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Soil pH dominated Cd sorption, explaining &gt;92% of the variation in <jats:italic>K<\/jats:italic><jats:sub>d<\/jats:sub> values in both treatments. At any pH, Cd sorption was apparently slightly but significantly (<jats:italic>p<\/jats:italic> &lt; 0.05) smaller in the sludge\u2010amended soil compared to the control, even though the organic carbon content was 70% larger and the ammonium oxalate\u2013extractable iron content was roughly doubled. Correction for dissolved organic carbon (DOC) complexation with the speciation model WHAM reduced the difference in sorption between treatments, but the sludged soil still had significantly smaller <jats:italic>K<\/jats:italic><jats:sub>d<\/jats:sub> values (<jats:italic>p<\/jats:italic> &lt; 0.01). Batch equilibrations without addition of Cd showed that there was no significant difference in the solubility of \u201cnative\u201d cadmium (defined as EDTA\u2010extractable Cd) in sludged and control soils. The reason for the lack of increase in Cd sorption in the sludge\u2010amended soil has not been established, but it may be due to competition for sorption sites on humic compounds with sludge\u2010derived Fe and trace metals such as zinc. The fact that the pyrophosphate\u2010extractable (i.e., organically associated) iron content was seven times larger in the sludged soil provides some supporting evidence for this hypothesis.<\/jats:p>","DOI":"10.2134\/jeq2004.0385","type":"journal-article","created":{"date-parts":[[2005,8,9]],"date-time":"2005-08-09T22:53:54Z","timestamp":1123628034000},"page":"1530-1538","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Cadmium Solubility and Sorption in a Long\u2010Term Sludge\u2010Amended Arable Soil"],"prefix":"10.1002","volume":"34","author":[{"given":"Petra","family":"Bergkvist","sequence":"first","affiliation":[{"name":"Department of Soil Sciences SLU Box 7014 750 07 Uppsala Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dan","family":"Berggren","sequence":"additional","affiliation":[{"name":"Department of Soil Sciences SLU Box 7014 750 07 Uppsala Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nicholas","family":"Jarvis","sequence":"additional","affiliation":[{"name":"Department of Soil Sciences SLU Box 7014 750 07 Uppsala Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2005,9]]},"reference":[{"key":"e_1_2_7_2_1","first-page":"404","volume-title":"Processing and use of sewage sludge","author":"Alloway B.J.","year":"1984"},{"doi-asserted-by":"publisher","key":"e_1_2_7_3_1","DOI":"10.1016\/0021-9797(81)90063-1"},{"doi-asserted-by":"publisher","key":"e_1_2_7_4_1","DOI":"10.2134\/jeq2004.1810"},{"doi-asserted-by":"publisher","key":"e_1_2_7_5_1","DOI":"10.1016\/S0167-8809(03)00121-X"},{"doi-asserted-by":"publisher","key":"e_1_2_7_6_1","DOI":"10.4141\/cjss96-025"},{"key":"e_1_2_7_7_1","first-page":"203","volume-title":"Humic substances in soil and crop sciences, selected readings","author":"Boyd S.A.","year":"1990"},{"doi-asserted-by":"publisher","key":"e_1_2_7_8_1","DOI":"10.1002\/jpln.19861490404"},{"key":"e_1_2_7_9_1","first-page":"451","volume-title":"Science and engineering of composting: Design, environmental, microbiological and utilization aspects","author":"Chaney R.L.","year":"1993"},{"doi-asserted-by":"publisher","key":"e_1_2_7_10_1","DOI":"10.2136\/sssaj1972.03615995003600050024x"},{"doi-asserted-by":"publisher","key":"e_1_2_7_11_1","DOI":"10.1007\/BF00163616"},{"doi-asserted-by":"publisher","key":"e_1_2_7_12_1","DOI":"10.1007\/BF00294136"},{"doi-asserted-by":"publisher","key":"e_1_2_7_13_1","DOI":"10.1007\/BF00193777"},{"doi-asserted-by":"publisher","key":"e_1_2_7_14_1","DOI":"10.1007\/BF00228779"},{"doi-asserted-by":"publisher","key":"e_1_2_7_15_1","DOI":"10.1097\/00010694-198409000-00009"},{"volume-title":"World reference base for soil resources","year":"1998","author":"FAO","key":"e_1_2_7_16_1"},{"doi-asserted-by":"publisher","key":"e_1_2_7_17_1","DOI":"10.2134\/jeq1998.00472425002700010003x"},{"doi-asserted-by":"publisher","key":"e_1_2_7_18_1","DOI":"10.1097\/00010694-199108000-00002"},{"key":"e_1_2_7_19_1","series-title":"SSSA Book Ser. 5","first-page":"665","volume-title":"Methods of soil analysis. 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