{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T11:05:07Z","timestamp":1791111907138,"version":"4.1.0"},"reference-count":41,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2006,3,1]],"date-time":"2006-03-01T00:00:00Z","timestamp":1141171200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Valorisation Recherche Qu\u00e9bec"}],"content-domain":{"domain":["acsess.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["J of Env Quality"],"published-print":{"date-parts":[[2006,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title><jats:p>Influence of soil properties and aging on Cu partitioning and toxicity was assessed on 10 artificial soils constituted using a statistical design considering pH (5.5 and 7.5), organic matter (1\u201330% [w\/w]), and clay content (5\u201335% [w\/w]). Total Cu as well as water\u2010, CaCl<jats:sub>2<\/jats:sub>\u2013, and diethylene triamine pentaacetic acid (DTPA)\u2013extracted Cu fractions were determined for each soil mixture. Ecotoxic effect was assessed by determining growth inhibition of barley (<jats:italic>Hordeum vulgare<\/jats:italic> L.) and compost worm (<jats:italic>Eisenia fetida<\/jats:italic>) mortality. Analyses were repeated after a 16\u2010wk aging period of the soils at pH 7.5 (8 \u00d7 2\u2010wk wetting and drying cycle). Results indicated that pH was the main factor controlling Cu partitioning, ahead of organic matter and clay content. Calcium chloride (0.5 <jats:italic>M<\/jats:italic>)\u2013extracted Cu fractions showed the best correlation with toxic responses (<jats:italic>r<\/jats:italic> = 0.55\u20130.66; <jats:italic>p<\/jats:italic> &lt; 0.05), while total and DTPA\u2010extracted Cu concentrations could not explain differences in toxicity. Direct regressions between toxicity and soil properties (pH, organic matter, and clay content) provided better explanation of variance: <jats:italic>r<\/jats:italic><jats:sup>2<\/jats:sup> = 0.50 (<jats:italic>p<\/jats:italic> = 0.00006) for compost worm mortality, <jats:italic>r<\/jats:italic><jats:sup>2<\/jats:sup> = 0.77 (<jats:italic>p<\/jats:italic> &lt; 0.00001) for barley shoot inhibition, and <jats:italic>r<\/jats:italic><jats:sup>2<\/jats:sup> = 0.92 (<jats:italic>p<\/jats:italic> &lt; 0.00001) for barley root inhibition. Copper toxicity was mainly influenced by pH and, to a lesser extent, by organic matter and clay content. Aging in organic soils revealed a slight reduction in ecotoxicity while an increase was observed in soils with low organic matter content. Further investigation using longer aging periods would be necessary to assess the significance of this observation.<\/jats:p>","DOI":"10.2134\/jeq2005.0107","type":"journal-article","created":{"date-parts":[[2006,3,1]],"date-time":"2006-03-01T20:45:34Z","timestamp":1141245934000},"page":"558-567","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Influence of Soil Properties and Aging on the Toxicity of Copper on Compost Worm and Barley"],"prefix":"10.1002","volume":"35","author":[{"given":"Catherine M.","family":"Daoust","sequence":"first","affiliation":[{"name":"CIRAIG: InterUniversity Reference Center for the Life Cycle Assessment Interpretation and Management of Products, Processes and Services 2500 ch. Polytechnique Montreal Quebec H3C 3A7 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Bastien","sequence":"additional","affiliation":[{"name":"CEAEQ: Centre d'Expertise en Analyse Environnementale du Qu\u00e9bec Minist\u00e8re de l'Environnement du Qu\u00e9bec 2700, EInstein Sainte\u2010Foy Quebec G1P 3W8 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Louise","family":"Desch\u00eanes","sequence":"additional","affiliation":[{"name":"CIRAIG: InterUniversity Reference Center for the Life Cycle Assessment Interpretation and Management of Products, Processes and Services 2500 ch. Polytechnique Montreal Quebec H3C 3A7 Canada"},{"name":"NSERC Industrial Chair in Site Remediation, Chemical Engineering Department \u00c9cole Polytechnique de Montr\u00e9al 2500 ch. 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