{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,24]],"date-time":"2026-03-24T14:07:26Z","timestamp":1774361246536,"version":"3.50.1"},"reference-count":0,"publisher":"IWA Publishing","issue":"11","content-domain":{"domain":["iwaponline.com"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2010,12,1]]},"abstract":"<jats:p>A highly electroactive material Mo2[(OAc)2(H2-calix[4]arene)] is used as a neutral carrier for Cd2\u2009+\u2009 ions in this paper. The membrane is fabricated by using ionophore [Mo2(OAc)2(H2-calix[4]arene)]:poly(vinyl chloride) (PVC): dibutylphthalate(DBP):sodium tetraphenyl borate (NaTPB) in the ratio of 40:300:470:5 respectively and tetrahydrofuran (THF) used as a solvent. The membrane electrode performed in the concentration range of 9.9\u2009\u00d7\u200910\u22128\u20131.0\u2009\u00d7\u200910\u22121\u2009M (2.34\u2009\u00d7\u200910\u22125\u201323.64\u2009mg\/mL) having the Nernstian slope of 30.0\u00b11.0\u2009mV and the best detection limit was observed at 9.8\u2009\u00d7\u200910\u22128\u2009M (2.31\u2009\u00d7\u200910\u22125\u2009mg\/mL). The proposed membrane electrode has the response time of 12\u2009s and a useful working pH range of 1.0\u20137.0, and used over a period of 10 months and work satisfactorily in the test solution having 30% (v\/v) non-aqueous content. Electrode sensor has distinguishable ability for Cd2\u2009+\u2009 ion with regard to several alkali, alkaline earth, transition and heavy metal ions. It was used in direct potentiometry as an indicator electrode, in the potentiometric titration of 10\u22123\u2009M Cd2\u2009+\u2009 solution against 10\u22122\u2009M of ethylenediaminetetraacetic acid (EDTA).<\/jats:p>","DOI":"10.2166\/wst.2010.774","type":"journal-article","created":{"date-parts":[[2010,11,23]],"date-time":"2010-11-23T16:18:56Z","timestamp":1290529136000},"page":"2510-2518","update-policy":"https:\/\/doi.org\/10.2166\/iwapcrossmarkpolicypage","source":"Crossref","is-referenced-by-count":4,"title":["A polyvinylchloride-based cadmium ion-selective electrode using [Mo2(OAc)2(H2-calix[4]arene)] as an electroactive material"],"prefix":"10.2166","volume":"62","author":[{"given":"Sonika","family":"Tyagi","sequence":"first","affiliation":[{"name":"Department of Chemistry, Faculty of Natural Sciences, Jamia Millia Islamia (Central University), New Delhi 110 025, India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Himanshu","family":"Agarwal","sequence":"first","affiliation":[{"name":"Department of Chemistry, L.R. (P.G.) College, Sahibabad 201 005, India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Saiqa","family":"Ikram","sequence":"first","affiliation":[{"name":"Department of Chemistry, Faculty of Natural Sciences, Jamia Millia Islamia (Central University), New Delhi 110 025, India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"945","container-title":["Water Science and Technology"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/iwaponline.com\/wst\/article-pdf\/62\/11\/2510\/445789\/2510.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/iwaponline.com\/wst\/article-pdf\/62\/11\/2510\/445789\/2510.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2020,3,28]],"date-time":"2020-03-28T00:40:09Z","timestamp":1585356009000},"score":1,"resource":{"primary":{"URL":"https:\/\/iwaponline.com\/wst\/article\/62\/11\/2510\/14990\/A-polyvinylchloridebased-cadmium-ionselective"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,12,1]]},"references-count":0,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2010,12,1]]}},"URL":"https:\/\/doi.org\/10.2166\/wst.2010.774","relation":{},"ISSN":["0273-1223","1996-9732"],"issn-type":[{"value":"0273-1223","type":"print"},{"value":"1996-9732","type":"electronic"}],"subject":[],"published-other":{"date-parts":[[2010,12,1]]},"published":{"date-parts":[[2010,12,1]]}}}