{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,13]],"date-time":"2026-02-13T13:30:04Z","timestamp":1770989404755,"version":"3.50.1"},"reference-count":29,"publisher":"IWA Publishing","issue":"8","content-domain":{"domain":["iwaponline.com"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2017,10,25]]},"abstract":"<jats:p>Taking cetyltrimethylammonium bromide (CTAB) as the template and using TiO2 as the substrate, coral-globular-like composite Ag\/TiO2-SnO2 (CTAB) was successfully synthesized by the sol\u2013gel combined with a temperature-programmed treatment method. X-ray diffraction, scanning electron microscopy (SEM), UV\u2013vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, SEM combined with X-ray energy dispersive spectroscopy, and N2 adsorption\u2013desorption tests were employed to characterize samples' crystalline phase, chemical composition, morphology and surface physicochemical properties. Results showed that composites not only had TiO2 anatase structure, but also had some generated SnTiO4, and the silver species was metallic Ag0. Ag\/TiO2-SnO2 (CTAB) possessed a coral-globular-like structure with nanosheets in large quantities. The photocatalytic activity of Ag\/TiO2-SnO2 (CTAB) had studied by degrading organic dyes under multi-modes, mainly using rhodamine B as the model molecule. Results showed that the coral-globular-like Ag\/TiO2-SnO2 (CTAB) was higher photocatalytic activity than that of commercial TiO2, Ag\/TiO2-SnO2, TiO2-SnO2 (CTAB), and TiO2-SnO2 under ultraviolet light irradiation. Moreover, Ag\/TiO2-SnO2 (CTAB) composite can significantly affect the photocatalytic degradation under multi-modes including UV light, visible light, simulated solar light and microwave-assisted irradiation. Meanwhile, the photocatalytic activity of Ag\/TiO2-SnO2 (CTAB) was maintained even after three cycles, indicating that the catalyst had good usability.<\/jats:p>","DOI":"10.2166\/wst.2017.323","type":"journal-article","created":{"date-parts":[[2017,6,30]],"date-time":"2017-06-30T00:20:29Z","timestamp":1498782029000},"page":"2120-2132","update-policy":"https:\/\/doi.org\/10.2166\/iwapcrossmarkpolicypage","source":"Crossref","is-referenced-by-count":7,"title":["Synthesis of coral-globular-like composite Ag\/TiO2-SnO2 and its photocatalytic degradation of rhodamine B under multiple modes"],"prefix":"10.2166","volume":"76","author":[{"given":"Q.","family":"Song","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, China"},{"name":"College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"L.","family":"Li","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, China"},{"name":"College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China"},{"name":"College of Heilongjiang Province Key Laboratory of Fine Chemicals, Qiqihar 161006, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"N.","family":"Zhuo","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"H. 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Technol."},{"issue":"13","key":"2020032801451165200_WST-EM17302R1C7","doi-asserted-by":"crossref","first-page":"2615","DOI":"10.1021\/cm049771i","article-title":"Room-temperature preparation of ZrO2 precursor thin film in an aqueous peroxozirconium-complex solution","volume":"16","author":"Gao","year":"2004","journal-title":"Chem. Mater."},{"issue":"3","key":"2020032801451165200_WST-EM17302R1C8","doi-asserted-by":"crossref","first-page":"900","DOI":"10.1021\/ie504304u","article-title":"Au\/MnOx\/3DOM La0.6Sr0.4MnO3: highly active nanocatalysts for the complete oxidation of toluene","volume":"54","author":"Jiang","year":"2015","journal-title":"Ind. Eng. Chem. Res."},{"issue":"21","key":"2020032801451165200_WST-EM17302R1C9","doi-asserted-by":"crossref","first-page":"11351","DOI":"10.1021\/acsami.5b01817","article-title":"Bifunctional sensing mechanism of SnO2\u2013ZnO composite nanofibers for drastically enhancing the sensing behavior in H2 gas","volume":"7","author":"Katoch","year":"2015","journal-title":"Appl. Mater. Interfaces"},{"issue":"2","key":"2020032801451165200_WST-EM17302R1C10","doi-asserted-by":"crossref","first-page":"381","DOI":"10.1007\/s10971-011-2515-7","article-title":"Preparation of Sn doped nanometric TiO2 powders by reflux and hydrothermal syntheses and their characterization","volume":"59","author":"Kiraz","year":"2011","journal-title":"J. Sol-Gel Sci. 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Soc."},{"key":"2020032801451165200_WST-EM17302R1C17","doi-asserted-by":"crossref","first-page":"134","DOI":"10.1016\/j.colsurfa.2014.05.060","article-title":"Microwave-assisted synthesis of nanocomposite Ag\/ZnO\u2013TiO2 and photocatalytic degradation rhodamine B with different modes","volume":"457","author":"Li","year":"2014","journal-title":"Colloids and Surfaces A"},{"key":"2020032801451165200_WST-EM17302R1C16","doi-asserted-by":"crossref","first-page":"2753","DOI":"10.1007\/s11051-014-2753-z","article-title":"Urchin-like CdS\/ZrO2 nanocomposite prepared by microwave-assisted hydrothermal combined with ion-exchange and its multimode photocatalytic activity","volume":"16","author":"Li","year":"2014","journal-title":"J. Nanopart. 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