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This study aims to present a novel material, namely copper\u2013HAP (Cu\u2013HAP), which was synthesized via an ion exchange method. The resulting material underwent comprehensive characterization using scanning electron microscopy, X-ray diffraction, Fourier-transform infrared spectroscopy, and Brunauer\u2013Emmett\u2013Teller (BET) analysis. Subsequently, based on the principle of the Fenton-like oxidation reaction, the material was used for the degradation of phenol. The outcomes of the investigation revealed that the optimal preparation conditions for the catalyst were achieved at a temperature of 40 \u00b0C, a pH value of 5, and a relative dosage of Cu\u2013HAP at 100 mg\/g. Under the reaction conditions of a catalyst dosage of 2 g\/L, a 30% hydrogen peroxide concentration of 30 mM, a phenol concentration of 20 mg\/L, a pH value of 6, a temperature of 40 \u00b0C, and the degradation rate of phenol impressively reached 98.12%. Furthermore, the degradation rate remained at 42.31% even after five consecutive cycles, indicating the promising potential of Cu\u2013HAP in the treatment of recalcitrant organic compounds within this field.<\/jats:p>","DOI":"10.2166\/wst.2023.292","type":"journal-article","created":{"date-parts":[[2023,9,13]],"date-time":"2023-09-13T08:55:00Z","timestamp":1694595300000},"page":"2332-2343","update-policy":"https:\/\/doi.org\/10.2166\/iwapcrossmarkpolicypage","source":"Crossref","is-referenced-by-count":9,"title":["Ion exchange synthesis of copper-based hydroxyapatite for the catalytic degradation of phenol"],"prefix":"10.2166","volume":"88","author":[{"given":"Yu","family":"Peng","sequence":"first","affiliation":[{"name":"a College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, China"},{"name":"b Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan University of Science and 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