{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,12]],"date-time":"2026-04-12T14:15:48Z","timestamp":1776003348463,"version":"3.50.1"},"reference-count":40,"publisher":"IWA Publishing","issue":"10","license":[{"start":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T00:00:00Z","timestamp":1731369600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["42077186"],"award-info":[{"award-number":["42077186"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003819","name":"Natural Science Foundation of Hubei Province","doi-asserted-by":"publisher","award":["2023AFD222"],"award-info":[{"award-number":["2023AFD222"]}],"id":[{"id":"10.13039\/501100003819","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iwaponline.com"],"crossmark-restriction":true},"short-container-title":[],"published-print":{"date-parts":[[2024,11,15]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n               <jats:p\/>\n               <jats:p>Due to rapid urbanization and industrialization, combined pollution caused by BTEX (benzene, toluene, ethylbenzene, and xylene) and heavy metals has become ubiquitous in soils, which would pose serious health risks to humans. However, the effects of heavy metals on the sorption and desorption behaviors of BTEX have not been fully elucidated. In this study, the effects of Cu2+ and Pb2+ ions on the sorption and desorption of benzene onto humic acids and black carbons were investigated. The results showed that Cu2+ and Pb2+ ions significantly reduced the sorption capacity, slowed down the sorption rate, and made the desorption less hysteretic of benzene on both humic acids and black carbons. Furthermore, the inhibitory effects by Pb2+ were significantly stronger than those of Cu2+. By combining the results of Fourier transform infrared spectroscopy and the site energy distribution model, it can be speculated that the hydration shells of Cu2+ and Pb2+ ions partially cover the surface of humic acids and black carbons, blocking their micropores and shielding sorption sites, consequently inhibiting the sorption of benzene. This study highlights that coexisting metal cations can significantly influence the fate of BTEX in soils.<\/jats:p>","DOI":"10.2166\/wst.2024.372","type":"journal-article","created":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T16:35:19Z","timestamp":1731429319000},"page":"2947-2960","update-policy":"https:\/\/doi.org\/10.2166\/iwapcrossmarkpolicypage","source":"Crossref","is-referenced-by-count":1,"title":["Effects of copper and lead on the sorption and desorption behaviors of benzene onto humic acids and black carbons"],"prefix":"10.2166","volume":"90","author":[{"given":"Zhi","family":"Tang","sequence":"first","affiliation":[{"name":"a Six Geological Team of Hubei Geological Bureau, Xiaogan 432000, China"},{"name":"b School of Environmental Studies, China University of Geosciences, Wuhan 430074, China"},{"name":"c Hubei Key Laboratory of Resources and Eco-Environment Geology, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sen","family":"Yang","sequence":"additional","affiliation":[{"name":"b School of Environmental Studies, China University of Geosciences, Wuhan 430074, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-8951-4992","authenticated-orcid":false,"given":"Yilian","family":"Li","sequence":"additional","affiliation":[{"name":"b School of Environmental Studies, China University of Geosciences, Wuhan 430074, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Juan","family":"Du","sequence":"additional","affiliation":[{"name":"a Six Geological Team of Hubei Geological Bureau, Xiaogan 432000, China"},{"name":"c Hubei Key Laboratory of Resources and Eco-Environment Geology, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yangfu","family":"Xiong","sequence":"additional","affiliation":[{"name":"a Six Geological Team of Hubei Geological Bureau, Xiaogan 432000, China"},{"name":"c Hubei Key Laboratory of Resources and Eco-Environment Geology, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shengbo","family":"Fu","sequence":"additional","affiliation":[{"name":"a Six Geological Team of Hubei Geological Bureau, Xiaogan 432000, China"},{"name":"c Hubei Key Laboratory of Resources and Eco-Environment Geology, Xiaogan 432000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"945","published-online":{"date-parts":[[2024,11,12]]},"reference":[{"key":"key-10.2166\/wst.2024.372-1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2021.118686"},{"key":"key-10.2166\/wst.2024.372-2","doi-asserted-by":"publisher","DOI":"10.1021\/es00007a013"},{"key":"key-10.2166\/wst.2024.372-3","doi-asserted-by":"publisher","DOI":"10.1016\/0040-6090(74)90235-1"},{"key":"key-10.2166\/wst.2024.372-4","doi-asserted-by":"publisher","DOI":"10.1021\/es960903l"},{"key":"key-10.2166\/wst.2024.372-5","doi-asserted-by":"publisher","DOI":"10.1021\/es062113+"},{"key":"key-10.2166\/wst.2024.372-6","doi-asserted-by":"publisher","DOI":"10.1021\/es801376w"},{"key":"key-10.2166\/wst.2024.372-7","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2010.01.029"},{"key":"key-10.2166\/wst.2024.372-8","doi-asserted-by":"publisher","DOI":"10.1007\/s11368-018-1976-5"},{"key":"key-10.2166\/wst.2024.372-9","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-018-1536-y"},{"key":"key-10.2166\/wst.2024.372-10","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2022.116435"},{"key":"key-10.2166\/wst.2024.372-11","doi-asserted-by":"publisher","DOI":"10.1016\/j.orggeochem.2009.07.003"},{"key":"key-10.2166\/wst.2024.372-12","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.7b04999"},{"key":"key-10.2166\/wst.2024.372-13","doi-asserted-by":"publisher","DOI":"10.1021\/es010920x"},{"key":"key-10.2166\/wst.2024.372-14","doi-asserted-by":"publisher","DOI":"10.1007\/s10086-016-1606-z"},{"key":"key-10.2166\/wst.2024.372-15","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2010.01.103"},{"key":"key-10.2166\/wst.2024.372-16","doi-asserted-by":"publisher","DOI":"10.1016\/S1001-0742(11)60778-X"},{"key":"key-10.2166\/wst.2024.372-17","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2013.05.056"},{"key":"key-10.2166\/wst.2024.372-18","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2019.124072"},{"key":"key-10.2166\/wst.2024.372-19","doi-asserted-by":"publisher","DOI":"10.1016\/j.geoderma.2018.02.028"},{"key":"key-10.2166\/wst.2024.372-20","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-019-07029-2"},{"key":"key-10.2166\/wst.2024.372-21","doi-asserted-by":"publisher","DOI":"10.1021\/j150579a011"},{"key":"key-10.2166\/wst.2024.372-22","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2021.125255"},{"key":"key-10.2166\/wst.2024.372-23","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-022-20398-5"},{"key":"key-10.2166\/wst.2024.372-24","doi-asserted-by":"publisher","DOI":"10.1021\/es980970a"},{"key":"key-10.2166\/wst.2024.372-25","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2019.125281"},{"key":"key-10.2166\/wst.2024.372-26","doi-asserted-by":"publisher","DOI":"10.2134\/jeq2002.9700"},{"key":"key-10.2166\/wst.2024.372-27","doi-asserted-by":"publisher","DOI":"10.1093\/carcin\/21.8.1485"},{"key":"key-10.2166\/wst.2024.372-28","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-019-05095-0"},{"key":"key-10.2166\/wst.2024.372-29","doi-asserted-by":"publisher","DOI":"10.1021\/es050107s"},{"key":"key-10.2166\/wst.2024.372-30","doi-asserted-by":"publisher","DOI":"10.1021\/es803357b"},{"key":"key-10.2166\/wst.2024.372-31","doi-asserted-by":"publisher","DOI":"10.1016\/S1001-0742(10)60381-6"},{"key":"key-10.2166\/wst.2024.372-32","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-017-0038-7"},{"key":"key-10.2166\/wst.2024.372-33","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2022.114467"},{"key":"key-10.2166\/wst.2024.372-34","doi-asserted-by":"publisher","DOI":"10.1016\/S0927-7757(98)00820-6"},{"key":"key-10.2166\/wst.2024.372-35","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2020.141891"},{"key":"key-10.2166\/wst.2024.372-36","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2017.10.035"},{"key":"key-10.2166\/wst.2024.372-37","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2008.11.121"},{"key":"key-10.2166\/wst.2024.372-38","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-014-2493-8"},{"key":"key-10.2166\/wst.2024.372-39","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-019-04515-5"},{"key":"key-10.2166\/wst.2024.372-40","doi-asserted-by":"publisher","DOI":"10.1021\/es051079g"}],"container-title":["Water Science &amp; Technology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/iwaponline.com\/wst\/article-pdf\/90\/10\/2947\/1511054\/wst2024372.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/iwaponline.com\/wst\/article-pdf\/90\/10\/2947\/1511054\/wst2024372.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,11,29]],"date-time":"2024-11-29T16:02:04Z","timestamp":1732896124000},"score":1,"resource":{"primary":{"URL":"https:\/\/iwaponline.com\/wst\/article\/90\/10\/2947\/105794\/Effects-of-copper-and-lead-on-the-sorption-and"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,12]]},"references-count":40,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2024,11,12]]},"published-print":{"date-parts":[[2024,11,15]]}},"URL":"https:\/\/doi.org\/10.2166\/wst.2024.372","relation":{},"ISSN":["0273-1223","1996-9732"],"issn-type":[{"value":"0273-1223","type":"print"},{"value":"1996-9732","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,12]]}}}