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These synthesized compounds may have antioxidant ability.<\/jats:p><\/jats:sec><jats:sec><jats:title>Materials and Methods:<\/jats:title><jats:p>ZnO-NRs in these reactions were prepared according to reported article. 2,4-dihydroxyacetophenone 1 (2 mmol) and isopropenylacetylene 2 (2 mmol) were mixed and stirred for 30 min in the presence of ZnO-NR (10 mol%) under solvent-free conditions at room temperature. After 30 min, primary amine 3 (2 mmol) was added to the mixture gently and the mixture was stirred for 15 min. After this time TMSCN 4 (2 mmol) was added to the mixture and stirred for 15 min. After completion of the reaction, as indicated by TLC, isocyanides 5 was added to mixture in the presence of catalyst.<\/jats:p><\/jats:sec><jats:sec><jats:title>Results:<\/jats:title><jats:p>In the first step of this research, the reaction of 2,4-dihydroxyacetophenone 1, isopropenylacetylene 2, methyl amine 3a, trimethylsilyle cyanide 4 and tert-butyl isocyanides 5a was used as a sample reaction to attain the best reaction conditions. The results showed this reaction performed with catalyst and did not have any product without catalyst after 12 h.<\/jats:p><\/jats:sec><jats:sec><jats:title>Conclusion:<\/jats:title><jats:p>In conclusion, we investigate multicomponent reaction of 2,4-dihydroxyacetophenone 1, isopropenylacetylene 2, primary amines 3, trimethylsilyl cyanide 4 and isocyanides along with ZnO-NRs as reusable catalyst at room temperature under solvent-free conditions which generates \u03b1-amino nitrile benzofuran derivatives in high yields. The advantages of our method are high atom economy, green reaction conditions, higher yield, shorter reaction times, and easy work-up, which are in good agreement with some principles of green chemistry. The compounds 8c exhibit excellent DPPH radical scavenging activity and FRAP compared to synthetic antioxidants BHT and TBHQ.<\/jats:p><\/jats:sec>","DOI":"10.2174\/1386207323666200219124625","type":"journal-article","created":{"date-parts":[[2020,2,19]],"date-time":"2020-02-19T13:16:45Z","timestamp":1582118205000},"page":"345-355","update-policy":"https:\/\/doi.org\/10.2174\/bsp_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["ZnO-nanorods Promoted Synthesis of \u03b1-amino Nitrile Benzofuran Derivatives using One-pot Multicomponent Reaction of Isocyanides"],"prefix":"10.2174","volume":"23","author":[{"given":"Asef H.","family":"Najar","sequence":"first","affiliation":[{"name":"Department of Chemistry, Qaemshahr Branch, Islamic Azad University, \u200eQaemshahr, Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zinatossadat","family":"Hossaini","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Qaemshahr Branch, Islamic Azad University, \u200eQaemshahr, Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shahrzad","family":"Abdolmohammadi","sequence":"additional","affiliation":[{"name":"Department of Chemistry, East Tehran Branch, Islamic Azad University, Tehran, Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daryoush","family":"Zareyee","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Qaemshahr Branch, Islamic Azad University, \u200eQaemshahr, Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"965","reference":[{"key":"ref=1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470131442","author":"Li C.J.","year":"2007","unstructured":"Li C.J.; Chan T.H.; Comprehensive Organic Reactions in Aqueous Media 2007","journal-title":"Comprehensive Organic Reactions in Aqueous Media"},{"key":"ref=2","doi-asserted-by":"publisher","first-page":"725","DOI":"10.1021\/cr800448q","volume":"109","author":"Chanda A.","year":"2009","unstructured":"Chanda A.; Fokin V.V.; Organic synthesis \u201con water\u201d. 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