{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,20]],"date-time":"2025-12-20T21:52:23Z","timestamp":1766267543632,"version":"3.37.3"},"reference-count":51,"publisher":"Bentham Science Publishers Ltd.","issue":"4","funder":[{"DOI":"10.13039\/501100006011","name":"Babol Noshirvani University of Technology","doi-asserted-by":"publisher","award":["BNUT\/370152\/98"],"award-info":[{"award-number":["BNUT\/370152\/98"]}],"id":[{"id":"10.13039\/501100006011","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["eurekaselect.com"],"crossmark-restriction":true},"short-container-title":["CCHTS"],"published-print":{"date-parts":[[2021,4]]},"abstract":"<jats:sec>\n<jats:title>Background:<\/jats:title>\n<jats:p> Propylene is one of the main petrochemical building blocks applied as a\nfeedstock for various chemical and polymer intermediates. The methanol-to-propylene (MTP)\nprocesses are reliable options for propylene production from non-petroleum resources. The highsilica\nZSM-5 zeolite is found to be a reliable candidate for the methanol to propylene catalysis.<\/jats:p>\n<\/jats:sec>\n<jats:sec>\n<jats:title>Objective:<\/jats:title>\n<jats:p>In this study, the mesoporosity was first introduced into a high silica ZSM-5 zeolite via\nan alkaline treatment by NaOH solution with piperidine to decrease the diffusion limitation, and\nthen the structure of zeolite was stabilized by phosphorus modification to improve the acidic\nproperties and to enhance the catalyst stability.<\/jats:p>\n<\/jats:sec>\n<jats:sec>\n<jats:title>Methods:<\/jats:title>\n<jats:p> High-silica H-ZSM-5 catalysts (Si\/Al = 200) were successfully prepared through\nmicrowave-assisted hydrothermal technique in the presence of tetrapropyl ammonium hydroxide\n(TPAOH) structure-directing agent. The mesoporosity was efficiently introduced into the ZSM-5\ncrystals via desilication derived from alkaline NaOH\/piperidine solution. Then, the acidity of the\ndesilicated ZSM-5 samples was improved using phosphorus modification. The catalysts were\nsubjected to XRD, ICP-OES, FE-SEM, BET, TGA, FT-IR and NH<jats:sub>3<\/jats:sub>-TPD analysis.<\/jats:p>\n<\/jats:sec>\n<jats:sec>\n<jats:title>Results:<\/jats:title>\n<jats:p> The catalytic performance of the prepared catalysts in the methanol to propylene (MTP)\nreaction was examined in a fixed-bed reactor at 475 \u00b0C, atmospheric pressure and methanol WHSV\nof 0.9 h<jats:sup>-1<\/jats:sup>. The results showed that the alkaline treatment in NaOH\/piperidine solution created uniform\nmesoporosity with no severe damage in the crystal structure. Similarly, phosphorus modification\ndeveloped the acidic features and led to the optimal catalytic efficiency in terms of the maximum\npropylene selectivity (49.16%) and P\/E ratio (5.97) as well as the catalyst lifetime.<\/jats:p>\n<\/jats:sec>\n<jats:sec>\n<jats:title>Conclusion:<\/jats:title>\n<jats:p> The results showed an excellent catalytic activity in terms of 99.21% methanol\nconversion, good propylene selectivity up to 49.16%, a high ratio of P\/E of 5.97 and a low\nselectivity to C5 + hydrocarbons of 11.57% for ZS-D-PI-P sample.<\/jats:p>\n<\/jats:sec>","DOI":"10.2174\/1386207323666200714002844","type":"journal-article","created":{"date-parts":[[2020,7,15]],"date-time":"2020-07-15T05:27:28Z","timestamp":1594790848000},"page":"546-558","update-policy":"https:\/\/doi.org\/10.2174\/bsp_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Effects of Desilication in NaOH\/Piperidine Medium and Phosphorus Modification on the Catalytic Activity of HZSM-5 Catalyst in Methanol to Propylene Conversion"],"prefix":"10.2174","volume":"24","author":[{"given":"Ebrahim","family":"Safaei","sequence":"first","affiliation":[{"name":"Chemical Engineering Department, Babol Noshirvani University of Technology, P.O. 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