{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,5]],"date-time":"2026-05-05T05:53:38Z","timestamp":1777960418908,"version":"3.51.4"},"reference-count":26,"publisher":"Bentham Science Publishers Ltd.","issue":"6","content-domain":{"domain":["eurekaselect.com"],"crossmark-restriction":true},"short-container-title":["COS"],"published-print":{"date-parts":[[2020,9,25]]},"abstract":"<jats:sec>\n<jats:title>Background:<\/jats:title>\n<jats:p>The phthalocyanines a series of compounds involves four iso-indole units linked by\naza nitrogen atoms bonded with metal atoms that are normally located in the center a phthalocyanines ring.\nSome of the central metal-phthalocyanines can be excited by ultraviolet light and emit a fluorescence in far-red\nregion.<\/jats:p>\n<\/jats:sec>\n<jats:sec>\n<jats:title>Objective:<\/jats:title>\n<jats:p>To synthesize a derivative of phthalocyanines namely 4,4',4' '-tri-(dodecenyl succinic anhydride)-\n4' ' '-(5-amino salicylic acid) zinc phthalocyanine with a zinc central metal.<\/jats:p>\n<\/jats:sec>\n<jats:sec>\n<jats:title>Materials and Methods:<\/jats:title>\n<jats:p>The reaction of 4- nitro Phthalonitrile and 4- amino Phthalonitrile with ZnCl2 in the\npresence of dimethyl amino ethanol afforded 4,4',4' '-triamino-4' ' '-nitro zinc phthalocyanine. This product\nreacted with 5-amino salicylic acid to yield tetra-(5-amino salicylic acid) zinc phthalocyanine. A dodecenyl\nsuccinic anhydride was added on the amine group of benzoic rings to afford 4,4',4' '-tri-(dodecenyl succinic\nanhydride)-4' ' '-(5-amino salicylic acid) zinc phthalocyanine(I), the target compound.<\/jats:p>\n<\/jats:sec>\n<jats:sec>\n<jats:title>Results and Discussion:<\/jats:title>\n<jats:p>Compound I is successfully synthesized with a yield of 72% from tetra-(5-amino\nsalicylic acid) zinc phthalocyanine with dodecenyl succinic anhydride.<\/jats:p>\n<\/jats:sec>\n<jats:sec>\n<jats:title>Conclusion:<\/jats:title>\n<jats:p>The newly synthesized molecule of 4,4',4' '-tri-(dodecenyl succinic anhydride)-4' ' '-(5-amino\nsalicylic acid) zinc phthalocyanine (I), tetra-(5-amino salicylic acid) zinc phthalocyanine(E) and 4,4',4' '-\ntriamino-4' ' '-nitro zinc phthalocyanine (S). The reaction of 4- nitro Phthalonitrile and 4- amino and the\nstructure of compound I is confirmed and its formation was proven.<\/jats:p>\n<\/jats:sec>","DOI":"10.2174\/1570179417666200519091950","type":"journal-article","created":{"date-parts":[[2020,5,19]],"date-time":"2020-05-19T16:07:39Z","timestamp":1589904459000},"page":"488-495","update-policy":"https:\/\/doi.org\/10.2174\/bsp_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis and Characterization of New Zinc Phthalocyanine - Dodecenyl Succinic Anhydride Benzoic Groups"],"prefix":"10.2174","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9637-3359","authenticated-orcid":true,"given":"Hussein Ali","family":"Al-Bahrani","sequence":"first","affiliation":[{"name":"College of Nursing, University of Al-Ameed, Karbala, Iraq"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4931-5524","authenticated-orcid":true,"given":"Mohanad Mousa","family":"Kareem","sequence":"additional","affiliation":[{"name":"Departmemt of Chemistry, College of Science, University of Babylon, Hilla, Iraq"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4074-9123","authenticated-orcid":true,"given":"Abdul Amir","family":"Kadhum","sequence":"additional","affiliation":[{"name":"Faculty of Medicine, University of Al-Ameed, Karbala, Iraq"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0711-3211","authenticated-orcid":true,"given":"Nour A.","family":"Alrazzak","sequence":"additional","affiliation":[{"name":"Departmemt of Chemistry, College of Science for Women, University of Babylon, Hilla, Iraq"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"965","reference":[{"key":"ref=1","author":"Chakraborty J.N.","year":"2014","unstructured":"Chakraborty J.N.;  Dyeing with phthalocyanine dye, in Fundamentals and Practices in Colouration of Textiles 2014","journal-title":"Dyeing with phthalocyanine dye, in Fundamentals and Practices in Colouration of Textiles"},{"key":"ref=2","doi-asserted-by":"publisher","first-page":"119","DOI":"10.1016\/j.poly.2013.05.046","volume":"61","author":"Phindile K.","year":"2013","unstructured":"Phindile K.; Edith A.; Tebello N.; Synthesis and photophysicochemical properties of zinc phthalocyanine derivatized with benzothiazole or carbazole photosensitizers. 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