{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,9]],"date-time":"2025-09-09T22:22:18Z","timestamp":1757456538644},"reference-count":0,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2003,9,1]],"date-time":"2003-09-01T00:00:00Z","timestamp":1062374400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Water Environment Research"],"published-print":{"date-parts":[[2003,9]]},"abstract":"<jats:p>Column experiments were used to measure the hydrodechlorination rate of relatively high concentrations of trichloroethene (TCE) (approximately 100 mg L<jats:sup>\u22121<\/jats:sup>). Trichloroethene in water was treated with a platinum on titania (Pt\u2013TiO<jats:sub>2<\/jats:sub>) catalyst and hydrazine. The influence of some experimental conditions (i.e., flowrate, temperature, and pH) on the catalytic conversion of TCE was studied. The pseudo\u2010first\u2010order rate constant of the overall hydrodechlorination of TCE was approximately 1 \u00d7 10<jats:sup>\u22123<\/jats:sup> to 1 \u00d7 10<jats:sup>\u22122<\/jats:sup> s<jats:sup>\u22121<\/jats:sup> in the temperature range of 283 to 328 K and was determined from the dependence of the TCE conversion on the contact time of the feed water with the catalyst by assuming first\u2010order kinetics. The activation energy of the catalytic hydrodechlorination of TCE was calculated as approximately 34 kJ\/mol from the temperature dependence of the rate constant. The TCE conversion increases with increasing pH, and probably correlates with the presence of un\u2010ionized hydrazine.<\/jats:p>","DOI":"10.2175\/106143003x141277","type":"journal-article","created":{"date-parts":[[2006,9,16]],"date-time":"2006-09-16T13:25:41Z","timestamp":1158413141000},"page":"472-477","source":"Crossref","is-referenced-by-count":4,"title":["Kinetic Study of the Hydrodechlorination of Trichloroethene in Water Using a Platinum Catalyst and Hydrazine"],"prefix":"10.1002","volume":"75","author":[{"given":"Kanji","family":"Miyabe","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Norie","family":"Taniguchi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aiko","family":"Imura","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yoshisato","family":"Tezuka","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2003,9]]},"container-title":["Water Environment Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.2175%2F106143003X141277","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.2175\/106143003X141277","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,15]],"date-time":"2023-09-15T18:38:28Z","timestamp":1694803108000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.2175\/106143003X141277"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2003,9]]},"references-count":0,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2003,9]]}},"alternative-id":["10.2175\/106143003X141277"],"URL":"https:\/\/doi.org\/10.2175\/106143003x141277","archive":["Portico"],"relation":{},"ISSN":["1061-4303","1554-7531"],"issn-type":[{"value":"1061-4303","type":"print"},{"value":"1554-7531","type":"electronic"}],"subject":[],"published":{"date-parts":[[2003,9]]}}}