{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T14:16:37Z","timestamp":1761488197563},"reference-count":20,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2009,1,1]],"date-time":"2009-01-01T00:00:00Z","timestamp":1230768000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Water Environment Research"],"published-print":{"date-parts":[[2009,1]]},"abstract":"<jats:p>An aqueous reaction mixture containing perchloroethylene (PCE), a photosensitizer, and an electron donor was irradiated by visible lamps to facilitate a sunlight\u2010sensitized dechlorination reaction. Various types of lamps, electron donors, and photosensitizers were examined, to compare the rates of dechlorination. Of the six photosensitizers evaluated, methylene blue was the most effective. Electron donors varied in effectiveness, as follows: trimethylamine &gt; triethylamine &gt; tributylamine. The intermediates and reaction products were identified by a purge\u2010and\u2010trap gas chromatography mass spectrometer system. The photosensitized dechlorination method degraded PCE via an electron\u2010transfer\u2010relay mechanism. Degradation products identified were trichloroethylene, dichloroethylenes, and chloroethylene. It seems a sequential dechlorination pathway was followed. The PCE dechlorination in a natural sunlight irradiation test was shown to be more effective than any of the simulated visible light sources. The result supports the feasibility of future development of solar\u2010powered dechlorination remediation systems with the use of sunlight, nontoxic dyes, and electron donors.<\/jats:p>","DOI":"10.2175\/106143008x304802","type":"journal-article","created":{"date-parts":[[2009,2,11]],"date-time":"2009-02-11T16:23:13Z","timestamp":1234369393000},"page":"76-81","source":"Crossref","is-referenced-by-count":3,"title":["Visible\u2010Light\u2010Sensitized Dechlorination of Perchloroethylene"],"prefix":"10.1002","volume":"81","author":[{"given":"Chitsan","family":"Lin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chih\u2010Ju G.","family":"Jou","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chih\u2010Lung","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2009,1]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/etc.5620060506"},{"key":"e_1_2_7_3_1","doi-asserted-by":"crossref","first-page":"1255","DOI":"10.2166\/wst.1987.0026","article-title":"Sensitized Photooxidation for Wastewater Disinfection and Detoxification","volume":"19","author":"Eisenberg T. N.","year":"1987","journal-title":"Water Sci. Technol."},{"key":"e_1_2_7_4_1","doi-asserted-by":"crossref","first-page":"2978","DOI":"10.1128\/aem.53.12.2978-2982.1987","article-title":"Factors Affecting the Methanogenic Activity of Methanothrix soehngenii VNBF","volume":"53","author":"Fathepure B. Z.","year":"1987","journal-title":"Appl. Environ. Microbiol."},{"key":"e_1_2_7_5_1","doi-asserted-by":"crossref","first-page":"2976","DOI":"10.1128\/aem.54.12.2976-2980.1988","article-title":"Dependence of Tetrachloroethylene Dechlorination on Methanogenic Substrate Consumption by Methanosarcina sp. Strain DCM","volume":"54","author":"Fathepure B. Z.","year":"1988","journal-title":"Appl. Environ. Microbiol."},{"key":"e_1_2_7_6_1","first-page":"301","article-title":"Mutagenic and Oncogenic Effects of Chloromethanes, Chloroethanes, and Halogenated Analogs of Vinyl Chloride","volume":"25","author":"Infante P. F.","year":"1982","journal-title":"Environ. Sci. Res."},{"key":"e_1_2_7_7_1","doi-asserted-by":"crossref","first-page":"1165","DOI":"10.1002\/etc.5620081209","article-title":"Flavin\u2010Sensitized Photodecomposition of Anilines and Phenols","volume":"8","author":"Larson R. A.","year":"1989","journal-title":"Environ. Toxicol. Chem."},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/es00033a013"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2006.07.049"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s001289900081"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/0045-6535(95)00177-A"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2003.11.059"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/es00061a012"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/0045-6535(81)90045-X"},{"key":"e_1_2_7_15_1","first-page":"366","volume-title":"Environmental Organic Chemistry;","author":"Schwarzenbach R. P.","year":"1993"},{"key":"e_1_2_7_16_1","volume-title":"Test Methods for Evaluating Solid Waste, Physical\/Chemical Methods,","author":"U.S. Environmental Protection Agency","year":"1996"},{"key":"e_1_2_7_17_1","doi-asserted-by":"crossref","first-page":"1703","DOI":"10.1128\/aem.54.7.1703-1708.1988","article-title":"Degradation of Trichloroethylene by Toluene Dioxygenase in Whole\u2010Cell Studies with Pseudomonas putida F1","volume":"54","author":"Wackett L. P.","year":"1988","journal-title":"Appl. Environ. Microbiol."},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/0045-6535(81)90174-0"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/es00159a010"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/es60127a013"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/es00131a008"}],"container-title":["Water Environment Research"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.2175%2F106143008X304802","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.2175\/106143008X304802","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,15]],"date-time":"2023-09-15T21:36:11Z","timestamp":1694813771000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.2175\/106143008X304802"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,1]]},"references-count":20,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2009,1]]}},"alternative-id":["10.2175\/106143008X304802"],"URL":"https:\/\/doi.org\/10.2175\/106143008x304802","archive":["Portico"],"relation":{},"ISSN":["1061-4303","1554-7531"],"issn-type":[{"value":"1061-4303","type":"print"},{"value":"1554-7531","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,1]]}}}