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Here we define the set of super two-extendible states and prove that an arbitrary state in this set cannot be used for heralded exact one-way secret-key distillation. This broad class of states includes both erased states and all full-rank states. Comparing the heralded exact one-way distillable secret key with the more commonly studied approximate one-way distillable secret key, our results demonstrate an extreme gap between them for many states of interest, with the approximate one-way distillable secret key being much larger. Our findings naturally extend to heralded exact one-way entanglement distillation, with similar conclusions.<\/jats:p>","DOI":"10.22331\/q-2026-03-10-2020","type":"journal-article","created":{"date-parts":[[2026,3,10]],"date-time":"2026-03-10T14:24:24Z","timestamp":1773152664000},"page":"2020","update-policy":"https:\/\/doi.org\/10.22331\/q-crossmark-policy-page","source":"Crossref","is-referenced-by-count":0,"title":["No-go theorem for heralded exact one-way key distillation"],"prefix":"10.22331","volume":"10","author":[{"given":"Vishal","family":"Singh","sequence":"first","affiliation":[{"name":"School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14850, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mark M.","family":"Wilde","sequence":"additional","affiliation":[{"name":"School of Electrical and Computer Engineering, Cornell University, Ithaca, New York 14850, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"9598","published-online":{"date-parts":[[2026,3,10]]},"reference":[{"key":"0","doi-asserted-by":"publisher","unstructured":"Feihu Xu, Xiongfeng Ma, Qiang Zhang, Hoi-Kwong Lo, and Jian-Wei Pan. ``Secure quantum key distribution with realistic devices&apos;&apos;. 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