{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T17:18:20Z","timestamp":1760548700600},"reference-count":25,"publisher":"National Library of Serbia","issue":"7","license":[{"start":{"date-parts":[[2008,1,1]],"date-time":"2008-01-01T00:00:00Z","timestamp":1199145600000},"content-version":"unspecified","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J Serb Chem Soc","J SERB CHEM","J SERB CHEM SOC","JSCS"],"published-print":{"date-parts":[[2008]]},"abstract":"<jats:p>A series of four Zn(II) complexes with asymmetrical porphyrinic ligands were synthesized: [5-(4-hydroxyphenyl)-10,15,20-triphenyl-21H,23H-porphinato]Zn(II) (Zn(II)TPPOHP), [5-(3-hydroxyphenyl)-10,15,20-triphenyl-21H,23H- -porphinato]Zn(II) (Zn(II)TPPOHM), [5-(2-hydroxyphenyl)-10,15,20-triphenyl- -21H,23H-Zn(II)-porphinato]Zn(II) (Zn(II)TPPOHO) and the well-known (5,10,15,20- -tetraphenyl-21H,23H-porphinato]Zn(II) (Zn(II)TPP) as reference, in a 1:1 mole ratio. In all cases, the free-base porphyrin served as a tetradentate ligand through the four pyrrole nitrogen atoms. The complexes were characterized by elemental analysis, FTIR and UV-Vis spectroscopy, which fully confirmed the structure of the complexes. UV-Vis showed that the spectral absorption of the four complexes was blue-shifted by at least 50 nm compared to that of the free ligands. Also important structural data were obtained from several different NMR experiments (including 1H-NMR, 13C-NMR, DEPT, COSY, HMBC and HMQC). Influences of external substituents on the porphyrin ring were observed. .<\/jats:p>","DOI":"10.2298\/jsc0807713b","type":"journal-article","created":{"date-parts":[[2008,7,22]],"date-time":"2008-07-22T14:32:50Z","timestamp":1216737170000},"page":"713-726","source":"Crossref","is-referenced-by-count":19,"title":["Studies on Zn(II) monohydroxyphenyl mesoporphyrinic complexes: Synthesis and characterization"],"prefix":"10.2298","volume":"73","author":[{"given":"Rica","family":"Boscencu","sequence":"first","affiliation":[{"name":"Carol Davila' University of Medicine and Pharmacy, Faculty of Pharmacy, Inorganic Chemistry Department, Bucharest, Romania"}]},{"given":"Radu","family":"Socoteanu","sequence":"additional","affiliation":[{"name":"Romanian Academy, Institute of Physical Chemistry 'I.G. Murgulescu', Bucharest, Romania"}]},{"suffix":"S.","given":"Anabela","family":"Oliveira","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica-F\u00edsica Molecular, Complexo Interdisciplinar, Instituto Superior T\u00e9cnico, Universidade T\u00e9cnica de Lisboa, Lisbon, Portugal"}]},{"suffix":"Filipe","given":"Vieira","family":"Ferreira","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica-F\u00edsica Molecular, Complexo Interdisciplinar, Instituto Superior T\u00e9cnico, Universidade T\u00e9cnica de Lisboa, Lisbon, Portugal"}]}],"member":"1078","reference":[{"key":"1","doi-asserted-by":"publisher","DOI":"10.2165\/00002512-199915010-00005"},{"key":"2","doi-asserted-by":"publisher","DOI":"10.1007\/BF02594124"},{"key":"3","doi-asserted-by":"publisher","DOI":"10.1093\/jnci\/90.12.889"},{"key":"4","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1993.tb04990.x"},{"key":"5","doi-asserted-by":"publisher","DOI":"10.1097\/00001813-199404000-00003"},{"key":"6","doi-asserted-by":"publisher","DOI":"10.1021\/cr010371d"},{"key":"7","doi-asserted-by":"publisher","DOI":"10.1039\/cs9962500351"},{"key":"8","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1994.tb05114.x"},{"key":"9","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.200590084"},{"key":"10","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotochem.2003.12.007"},{"key":"11","doi-asserted-by":"publisher","DOI":"10.1016\/S1010-6030(03)00203-X"},{"key":"12","doi-asserted-by":"publisher","DOI":"10.1039\/b616224j"},{"key":"13","doi-asserted-by":"publisher","DOI":"10.1016\/S1572-1000(04)00007-9"},{"key":"14","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijpharm.2004.03.004"},{"key":"15","doi-asserted-by":"publisher","DOI":"10.1016\/S1010-6030(03)00317-4"},{"key":"16","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1996.tb03093.x"},{"key":"17","doi-asserted-by":"publisher","DOI":"10.1002\/jpp.328"},{"key":"18","doi-asserted-by":"publisher","DOI":"10.1016\/j.jphotobiol.2003.10.002"},{"key":"19","doi-asserted-by":"publisher","DOI":"10.1016\/0005-2736(91)90008-V"},{"key":"20","doi-asserted-by":"publisher","DOI":"10.1021\/ja00312a061"},{"key":"21","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2852(61)90236-3"},{"key":"22","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2852(63)90011-0"},{"key":"23","doi-asserted-by":"publisher","DOI":"10.1021\/ja00851a015"},{"key":"24","doi-asserted-by":"publisher","DOI":"10.1039\/f19817700369"},{"key":"25","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1999.tb03322.x"}],"container-title":["Journal of the Serbian Chemical Society"],"original-title":[],"language":"en","deposited":{"date-parts":[[2023,5,29]],"date-time":"2023-05-29T09:29:41Z","timestamp":1685352581000},"score":1,"resource":{"primary":{"URL":"https:\/\/doiserbia.nb.rs\/Article.aspx?ID=0352-51390807713B"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008]]},"references-count":25,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2008]]}},"URL":"https:\/\/doi.org\/10.2298\/jsc0807713b","relation":{},"ISSN":["0352-5139","1820-7421"],"issn-type":[{"value":"0352-5139","type":"print"},{"value":"1820-7421","type":"electronic"}],"subject":[],"published":{"date-parts":[[2008]]}}}