{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,5]],"date-time":"2025-11-05T14:17:24Z","timestamp":1762352244514,"version":"3.37.3"},"reference-count":27,"publisher":"Springer Science and Business Media LLC","issue":"12","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2013,1,1]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Solvent formulation is important in the optimization of the mass-transfer through supported liquid membranes (SLM) in pertraction and membrane extraction. Oleyl alcohol (OA) is frequently used as the solvent or diluent in the extraction of carboxylic acids. A disadvantage of OA is its relatively high viscosity of 28.32 mPa s at 25\u00b0C. This can be decreased by the application of a less viscous OA diluent, e.g. dodecane. The relationship between the ratio of the distribution coefficient of butyric acid (BA), D F, and the viscosity of OA-dodecane solvents, \u00b5, as extraction and transport characteristics, and the overall mass-transfer coefficient, K p, through SLMs was analyzed. Dependence of the D F\/\u00b5 ratio on the OA concentration showed a maximum at the OA concentration of 15 mass % to 30 mass %. The OA concentration dependence of K p for SLMs exhibited also a maximum at about 30 mass % and 20 mass % of OA at the BA concentration driving force of 0.12 kmol m\u22123 and 0.3 kmol m\u22123, respectively. Shifting of the maximum in K p dependences towards lower OA concentrations by increasing the BA concentration driving force is in agreement with the D F\/\u00b5 ratio dependence. Using pure OA as the solvent or diluent is not preferable and a mixture of a low viscosity diluent with the OA concentration below 40 mass % should be used. The presented results show the potential of the D F\/\u00b5 ratio in the screening and formulation of solvents in extraction and SLM optimization.<\/jats:p>","DOI":"10.2478\/s11696-013-0370-4","type":"journal-article","created":{"date-parts":[[2013,4,4]],"date-time":"2013-04-04T09:07:55Z","timestamp":1365066475000},"source":"Crossref","is-referenced-by-count":12,"title":["Effect of viscosity of a liquid membrane containing oleyl alcohol on the pertraction of butyric acid"],"prefix":"10.1007","volume":"67","author":[{"given":"Marek","family":"Blahu\u0161iak","sequence":"first","affiliation":[]},{"given":"J\u00e1n","family":"Mart\u00e1k","sequence":"additional","affiliation":[]},{"given":"Fernando","family":"Miranda","sequence":"additional","affiliation":[]},{"given":"\u0160tefan","family":"Schlosser","sequence":"additional","affiliation":[]},{"given":"Jos\u00e9","family":"Teixeira","sequence":"additional","affiliation":[]}],"member":"297","reference":[{"key":"ref41","doi-asserted-by":"crossref","first-page":"1662","DOI":"10.1128\/AEM.54.7.1662-1667.1988","article-title":"Enhancement of butanol formation by Clostridium acetobutylicum in the presence of decanol - oleyl alcohol mixed extractants","volume":"5","author":"Evans","year":"1988","journal-title":"Applied and Environmental Microbiology"},{"key":"ref11","doi-asserted-by":"publisher","first-page":"1546","DOI":"10.1021\/je060025z.http:\/\/dx.doi.org\/10.1021\/je060025z","article-title":"Distribution of butyric acid between water and several solvents Journal of Chemical","volume":"2","author":"Bilgin","year":"2006","journal-title":"Engineering Data"},{"key":"ref111","doi-asserted-by":"publisher","first-page":"163","DOI":"10.1016\/s0011-9164(04)90182-8.http:\/\/dx.doi.org\/10.1016\/S0011-9164(04)90182-8","article-title":"Mass - transfer characteristics of a spiral - channel SLM module in pertraction of phenylalanine","volume":"12","author":"Kert\u00e9sz","year":"2004","journal-title":"Desalination"},{"key":"ref181","doi-asserted-by":"publisher","first-page":"608","DOI":"10.2478\/s11696-011-0069-3.http:\/\/dx.doi.org\/10.2478\/s11696-011-0069-3","article-title":"Mass - transfer in pertraction of butyric acid by phosphonium ionic liquids and dodecane","volume":"19","author":"Mart\u00e1k","year":"2011","journal-title":"Chemical Papers"},{"key":"ref71","doi-asserted-by":"publisher","first-page":"166","DOI":"10.1007\/s12010-011-9442-5.http:\/\/dx.doi.org\/10.1007\/s12010-011-9442-5","article-title":"Fermentation of reactive - membrane - extracted and ammonium - hydroxide - conditioned dilute - acid - pretreated corn stover","volume":"8","author":"Grzenia","year":"2012","journal-title":"Applied Biochemistry and Biotechnology"},{"key":"ref161","doi-asserted-by":"publisher","first-page":"42","DOI":"10.2478\/s11696-007-0077-5.http:\/\/dx.doi.org\/10.2478\/s11696-007-0077-5","article-title":"Liquid - liquid equilibria of butyric acid for solvents containing a phosphonium ionic liquid","volume":"17","author":"Mart\u00e1k","year":"2008","journal-title":"Chemical Papers"},{"key":"ref81","doi-asserted-by":"publisher","first-page":"543","DOI":"10.1002\/cjce.5450700318.http:\/\/dx.doi.org\/10.1002\/cjce.5450700318","article-title":"Extractive fermentation systems for organic acids production","volume":"9","author":"Hatzinikolaou","year":"1992","journal-title":"The Canadian Journal of Chemical Engineering"},{"key":"ref221","doi-asserted-by":"publisher","first-page":"245","DOI":"10.1016\/s0032-9592(96)00084-2.http:\/\/dx.doi.org\/10.1016\/S0032-9592(96)00084-2","article-title":"Evaluation of solvent and pH for extractive fermentation of butyric acid","volume":"23","author":"Vand\u00e1k","year":"1997","journal-title":"Process Biochemistry"},{"key":"ref201","doi-asserted-by":"publisher","first-page":"735","DOI":"10.1021\/je000323a.http:\/\/dx.doi.org\/10.1021\/je000323a","article-title":"Liquid - liquid equilibria of butyric acid in water + solvent systems with trioctylamine as extractant Journal of Chemical","volume":"21","author":"Sabolov\u00e1","year":"2001","journal-title":"Engineering Data"},{"key":"ref171","doi-asserted-by":"publisher","first-page":"318","DOI":"10.1016\/j.memsci.2008.02.064.http:\/\/dx.doi.org\/10.1016\/j.memsci.2008.02.064","article-title":"Pertraction of lactic acid through supported liquid membranes containing phosphonium ionic liquid","volume":"18","author":"Mart\u00e1k","year":"2008","journal-title":"Journal of Membrane Science"},{"key":"ref61","doi-asserted-by":"publisher","first-page":"111","DOI":"10.1016\/j.biortech.2012.01.169.http:\/\/dx.doi.org\/10.1016\/j.biortech.2012.01.169","article-title":"Membrane extraction for detoxification of biomass hydrolysates","volume":"7","author":"Grzenia","year":"2012","journal-title":"Bioresource Technology"},{"key":"ref211","doi-asserted-by":"publisher","first-page":"2574","DOI":"10.1016\/j.ces.2005.11.026.http:\/\/dx.doi.org\/10.1016\/j.ces.2005.11.026","article-title":"Dependence of extraction equilibrium of monocarboxylic acid from aqueous solutions on the relative basicity of extractant","volume":"22","author":"Shan","year":"2006","journal-title":"Chemical Engineering Science"},{"key":"ref101","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/0956-9618(95)00132-8.http:\/\/dx.doi.org\/10.1016\/0956-9618(95)00132-8","article-title":"Recovery of carboxylic acids from an aqueous waste stream using tributylphosphate Effect of presence of inorganic acids and their sodium salts","volume":"11","author":"Ingale","year":"1996","journal-title":"Separations Technology"},{"key":"ref01","doi-asserted-by":"publisher","first-page":"1634","DOI":"10.1016\/j.jct.2006.03.017.http:\/\/dx.doi.org\/10.1016\/j.jct.2006.03.017","article-title":"Phase equilibria of liquid ( water + butyric acid + oleyl alcohol ) ternary system","volume":"1","author":"Bilgin","year":"2006","journal-title":"The Journal of Chemical Thermodynamics"},{"key":"ref241","doi-asserted-by":"publisher","first-page":"82","DOI":"10.1002\/bit.10542.http:\/\/dx.doi.org\/10.1002\/bit.10542","article-title":"Extractive fermentation for butyric acid production from glucose by Clostridium tyrobutyricum","volume":"25","author":"Wu","year":"2003","journal-title":"Biotechnology and Bioengineering"},{"key":"ref51","doi-asserted-by":"publisher","first-page":"393","DOI":"10.1007\/bf00903771.http:\/\/dx.doi.org\/10.1007\/BF00903771","article-title":"Effects of extractive fermentation on butyric acid production by Clostridium acetobutylicum","volume":"6","author":"Evans","year":"1990","journal-title":"Applied Microbiology and Biotechnology"},{"key":"ref261","doi-asserted-by":"publisher","first-page":"835","DOI":"10.1016\/s0032-9592(99)00007-2.http:\/\/dx.doi.org\/10.1016\/S0032-9592(99)00007-2","article-title":"Butyric acid production by Clostridium butyricum with integrated extraction and pertraction","volume":"27","author":"Zigov\u00e1","year":"1999","journal-title":"Process Biochemistry"},{"key":"ref231","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1002\/aic.690010222.http:\/\/dx.doi.org\/10.1002\/aic.690010222","article-title":"Correlation of diffusion coefficients in dilute solutions","volume":"24","author":"Wilke","year":"1955","journal-title":"AIChE Journal"},{"key":"ref91","doi-asserted-by":"publisher","first-page":"252","DOI":"10.1016\/0956-9618(94)80030-8.http:\/\/dx.doi.org\/10.1016\/0956-9618(94)80030-8","article-title":"Recovery of butyric acid , valeric acid , and caproic acid ( BVC acids ) from an aqueous waste stream using tributylphosphate as an extractant","volume":"10","author":"Ingale","year":"1994","journal-title":"Separations Technology"},{"key":"ref251","doi-asserted-by":"publisher","first-page":"2671","DOI":"10.1080\/01496399608000819.http:\/\/dx.doi.org\/10.1080\/01496399608000819","article-title":"Extraction equilibria of butyric acid with organic solvents","volume":"26","author":"Zigov\u00e1","year":"1996","journal-title":"Separation Science and Technology"},{"key":"ref21","doi-asserted-by":"publisher","first-page":"213","DOI":"10.2478\/s11696-009-0114-7.http:\/\/dx.doi.org\/10.2478\/s11696-009-0114-7","article-title":"Simulation of a hybrid fermentation - separation process for production of butyric acid","volume":"3","author":"Blahu\u0161iak","year":"2010","journal-title":"Chemical Papers"},{"key":"ref271","first-page":"95","article-title":"Possibilities of butyric acid production by butanol oxidation with Gluconobacter oxydans coupled with extraction Chemical","volume":"28","author":"Zigov\u00e1","year":"2000","journal-title":"Biochemical Engineering Quarterly"},{"key":"ref151","doi-asserted-by":"publisher","first-page":"483","DOI":"10.1016\/j.seppur.2006.09.013.http:\/\/dx.doi.org\/10.1016\/j.seppur.2006.09.013","article-title":"Extraction of lactic acid by phosphonium ionic liquids","volume":"16","author":"Mart\u00e1k","year":"2007","journal-title":"Separation and Purification Technology"},{"key":"ref191","article-title":"The properties of gases and liquids rd ed New York","volume":"20","author":"Reid","year":"1977","journal-title":"USA"},{"key":"ref121","doi-asserted-by":"publisher","first-page":"336","DOI":"10.1021\/ie8010337.http:\/\/dx.doi.org\/10.1021\/ie8010337","article-title":"Extraction of acrylic propionic and butyric acid using Aliquat in oleyl alcohol : Equilibria and effect of temperature Industrial","volume":"13","author":"Keshav","year":"2009","journal-title":"Engineering Chemistry Research"},{"key":"ref131","doi-asserted-by":"publisher","first-page":"843","DOI":"10.1021\/je015526t.http:\/\/dx.doi.org\/10.1021\/je015526t","article-title":"Liquid - 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