{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T19:55:38Z","timestamp":1760298938975},"reference-count":0,"publisher":"Swiss Chemical Society","issue":"6","license":[{"start":{"date-parts":[[2012,6,27]],"date-time":"2012-06-27T00:00:00Z","timestamp":1340755200000},"content-version":"unspecified","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chimia"],"abstract":"<jats:p>\n        Esters are of widespread use for protecting carboxylic acids in organic synthesis. However, methods to cleave esters often employ harsh conditions. Herein, we report a new and mild method for the reductive cleavage of 2,2,2-trichloroethylesters (TCE esters). Our radical method employs\n Cp2TiCl as an electron transfer catalyst and Zn dust as stoichiometric reducing agent. It avoids the use of strong Br\u00f8nstedt-acids as well as aqueous conditions and can be carried out at room temperature.\n      <\/jats:p>","DOI":"10.2533\/chimia.2012.433","type":"journal-article","created":{"date-parts":[[2014,5,28]],"date-time":"2014-05-28T23:38:44Z","timestamp":1401320324000},"page":"433","source":"Crossref","is-referenced-by-count":4,"title":["Reductive Cleavage of 2,2,2-Trichloroethyl Esters by Titanocene Catalysis"],"prefix":"10.2533","volume":"66","author":[{"given":"Andreas","family":"Gans\u00e4uer","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tobias","family":"Dahmen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1442","published-online":{"date-parts":[[2012,6,27]]},"container-title":["CHIMIA"],"original-title":[],"link":[{"URL":"https:\/\/www.chimia.ch\/chimia\/article\/download\/5240\/4530","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.chimia.ch\/chimia\/article\/download\/5240\/4530","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,1,28]],"date-time":"2022-01-28T00:24:45Z","timestamp":1643329485000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.chimia.ch\/chimia\/article\/view\/5240"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,6,27]]},"references-count":0,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2012,6,1]]}},"URL":"https:\/\/doi.org\/10.2533\/chimia.2012.433","relation":{},"ISSN":["2673-2424","0009-4293"],"issn-type":[{"value":"2673-2424","type":"electronic"},{"value":"0009-4293","type":"print"}],"subject":[],"published":{"date-parts":[[2012,6,27]]}}}