{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,27]],"date-time":"2025-12-27T11:44:49Z","timestamp":1766835889657,"version":"3.48.0"},"reference-count":0,"publisher":"Swiss Chemical Society","issue":"11","license":[{"start":{"date-parts":[[2025,11,26]],"date-time":"2025-11-26T00:00:00Z","timestamp":1764115200000},"content-version":"unspecified","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chimia"],"abstract":"<jats:p>Because the biological activity of a molecule is directly linked to its three-dimensional configuration, the preparation of chiral compounds is a central discipline in synthetic organic chemistry. With the exploitation of photoredox catalysis that gives access to open-shell (radical) intermediates under mild and sustainable conditions, unprecedented molecular architectures can now be synthesized. However, the parent enantioselective transformations have been developed at a slower pace because suppressing non-catalyzed background reactivities has presented a major hurdle. Designer bifunctional photocatalysts containing a H-bonding motif for substrate recognition and a diaryl ketone as the photosensitizer embedded in a chiral scaffold are useful catalysts in asymmetric radical transformations. Herein, an overview of enantioselective transformations in which this class of catalysts has been successful and future directions are discussed.<\/jats:p>","DOI":"10.2533\/chimia.2025.803","type":"journal-article","created":{"date-parts":[[2025,11,26]],"date-time":"2025-11-26T00:09:54Z","timestamp":1764115794000},"page":"803-808","source":"Crossref","is-referenced-by-count":0,"title":["Chiral Bifunctional Photocatalysts with Aromatic Ketones as Photosensitizers"],"prefix":"10.2533","volume":"79","author":[{"given":"Giuseppe","family":"Zuccarello","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1442","published-online":{"date-parts":[[2025,11,26]]},"container-title":["CHIMIA"],"original-title":[],"link":[{"URL":"https:\/\/www.chimia.ch\/chimia\/article\/download\/2025_803\/2025_803","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.chimia.ch\/chimia\/article\/download\/2025_803\/2025_803","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,27]],"date-time":"2025-12-27T11:43:10Z","timestamp":1766835790000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.chimia.ch\/chimia\/article\/view\/2025_803"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,26]]},"references-count":0,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2025,11,26]]}},"URL":"https:\/\/doi.org\/10.2533\/chimia.2025.803","relation":{},"ISSN":["2673-2424","0009-4293"],"issn-type":[{"type":"electronic","value":"2673-2424"},{"type":"print","value":"0009-4293"}],"subject":[],"published":{"date-parts":[[2025,11,26]]}}}