{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T09:18:09Z","timestamp":1778750289960,"version":"3.51.4"},"posted":{"date-parts":[[2023,8,3]]},"reference-count":0,"publisher":"American Chemical Society (ACS)","license":[{"start":{"date-parts":[[2023,8,3]],"date-time":"2023-08-03T00:00:00Z","timestamp":1691020800000},"content-version":"unspecified","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"abstract":"<jats:p>Understanding the impact of MOF synthesis conditions on the production cost is vital in order to have a competitive product in a view of industrial applications. Here, considering the benchmark mesoporous iron(III) trimesate MIL-100(Fe) as a prototypical example, we show that the production cost can reach &lt;30 $\/kg if a careful selection of the synthetic route is made. Two routes were considered in the analysis, using sulfate and nitrate as iron sources. A new optimized synthesis protocol in a laboratory pilot-scale reactor of 5 liters based on iron sulfate was developed using optimized sustainable ambient pressure conditions, leading to larger particles and a higher STY. Based on reliable pilot-scale data and established chemical engineering estimation methods, this leads to a significantly low production cost of high quality MIL-100(Fe) achieving a potential competitive product.<\/jats:p>","DOI":"10.26434\/chemrxiv-2023-lck31","type":"posted-content","created":{"date-parts":[[2023,8,3]],"date-time":"2023-08-03T08:59:42Z","timestamp":1691053182000},"source":"Crossref","is-referenced-by-count":0,"title":["Cost Estimation of the Sustainable Production of MIL-100(Fe) at Industrial Scale from two upscaled synthesis routes"],"prefix":"10.26434","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2542-6943","authenticated-orcid":false,"given":"farid","family":"Nouar","sequence":"first","affiliation":[]},{"given":"christian","family":"Serre","sequence":"additional","affiliation":[]},{"given":"Mois\u00e9s L.","family":"Pinto","sequence":"additional","affiliation":[]},{"given":"Maria In\u00eas","family":"Severino","sequence":"additional","affiliation":[]},{"given":"Vanessa","family":"Pimenta","sequence":"additional","affiliation":[]},{"given":"Catia","family":"Freitas","sequence":"additional","affiliation":[]}],"member":"316","container-title":[],"original-title":[],"link":[{"URL":"https:\/\/chemrxiv.org\/doi\/pdf\/10.26434\/chemrxiv-2023-lck31","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T08:48:58Z","timestamp":1778748538000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemrxiv.org\/doi\/full\/10.26434\/chemrxiv-2023-lck31"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,8,3]]},"references-count":0,"URL":"https:\/\/doi.org\/10.26434\/chemrxiv-2023-lck31","relation":{"has-version":[{"id-type":"doi","id":"10.26434\/chemrxiv-2023-lck31-v2","asserted-by":"object"}]},"subject":[],"published":{"date-parts":[[2023,8,3]]},"subtype":"preprint"}}