{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:12:06Z","timestamp":1788394326579,"version":"build-2803163510"},"reference-count":44,"publisher":"Frontiers Media SA","license":[{"start":{"date-parts":[[2019,4,5]],"date-time":"2019-04-05T00:00:00Z","timestamp":1554422400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["frontiersin.org"],"crossmark-restriction":true},"short-container-title":["Front. Chem."],"DOI":"10.3389\/fchem.2019.00204","type":"journal-article","created":{"date-parts":[[2019,4,5]],"date-time":"2019-04-05T03:47:30Z","timestamp":1554436050000},"update-policy":"https:\/\/doi.org\/10.3389\/crossmark-policy","source":"Crossref","is-referenced-by-count":3,"title":["Gas-Phase Conversion of 1,3-Dithiolane-2-Thione Into 1,3-Dithiolan-2-One Over Molybdenum Trioxide"],"prefix":"10.3389","volume":"7","author":[{"given":"R. Alan","family":"Aitken","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomasine E.","family":"Curzon","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthew J.","family":"Andrews","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1965","published-online":{"date-parts":[[2019,4,5]]},"reference":[{"key":"B1","doi-asserted-by":"publisher","first-page":"93","DOI":"10.1016\/bs.aihch.2015.03.002","article-title":"Recent advances in the synthesis of heterocyclic compounds using flash vacuum pyrolysis","volume":"115","author":"Aitken","year":"2015","journal-title":"Adv. Heterocycl. Chem."},{"key":"B2","doi-asserted-by":"publisher","first-page":"5271","DOI":"10.1016\/S0040-4039(99)00999-5","article-title":"Generation and Reactivity of a 3H-Phosphaindene: the first 3H-Phosphole","volume":"40","author":"Aitken","year":"1999","journal-title":"Tetrahedron Lett."},{"key":"B3","doi-asserted-by":"publisher","first-page":"402","DOI":"10.1039\/B108663D","article-title":"Flash vacuum pyrolysis over magnesium. Part 1. Pyrolysis of benzylic, other aryl\/alkyl and aliphatic halides","volume":"1","author":"Aitken","year":"2002","journal-title":"J. Chem. Soc. Perkin Trans."},{"key":"B4","doi-asserted-by":"publisher","first-page":"618","DOI":"10.1016\/j.jaap.2016.12.028","article-title":"Flash vacuum pyrolysis of benzylidene halides, benzotrihalides and aryl halides over magnesium","volume":"124","author":"Aitken","year":"2017","journal-title":"J. Anal. Appl. Pyrol."},{"key":"B5","doi-asserted-by":"publisher","first-page":"1163","DOI":"10.1039\/A702652H","article-title":"Dehalogenation of organic halides by flash vacuum pyrolysis over magnesium: a versatile synthetic method","author":"Aitken","year":"","journal-title":"Chem. Commun"},{"key":"B6","doi-asserted-by":"publisher","first-page":"8417","DOI":"10.1016\/S0040-4039(97)10236-2","article-title":"Flash vacuum pyrolysis of dichlorophosphines over magnesium: generation and reactivity of simple phosphinidenes","volume":"38","author":"Aitken","year":"","journal-title":"Tetrahedron Lett."},{"key":"B7","doi-asserted-by":"publisher","first-page":"787","DOI":"10.1055\/s-1997-1414","article-title":"Effect of added benzoic acid on the phase-transfer catalysed permanganate oxidation of organosulfur compounds","author":"Aitken","year":"","journal-title":"Synthesis"},{"key":"B8","doi-asserted-by":"publisher","first-page":"19379","DOI":"10.1039\/c4ra15004j","article-title":"Unexpected rearrangement during the gas-phase dehalogenation approach to benzodithiophenes","volume":"5","author":"Aitken","year":"2015","journal-title":"RSC Adv."},{"key":"B9","doi-asserted-by":"publisher","first-page":"219","DOI":"10.3390\/catal8050219","article-title":"Catalytic ozonation of iron coated pumice for the degradation of natural organic matters","volume":"8","author":"Alver","year":"2018","journal-title":"Catalysts"},{"key":"B10","doi-asserted-by":"publisher","first-page":"289","DOI":"10.1039\/P19960000289","article-title":"Convenient procedure for converting 1,3-dithiolane-2-thiones into 1,3-dithiolan-2-ones","volume":"1","author":"Barbero","year":"1996","journal-title":"J. Chem. Soc. Perkin Trans."},{"key":"B11","doi-asserted-by":"publisher","first-page":"731","DOI":"10.1002\/anie.198407311","article-title":"O = P\u2013Cl and S = P\u2013Cl: Gas-phase ionization","volume":"23","author":"Binnewies","year":"1984","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"B12","doi-asserted-by":"publisher","first-page":"1659","DOI":"10.1021\/ie020442e","article-title":"High surface area support\/catalyst derived from natural pumice. Study of pretreatment variables","volume":"43","author":"Brito","year":"2004","journal-title":"Ind. Eng. Chem. Res."},{"key":"B13","doi-asserted-by":"publisher","first-page":"336","DOI":"10.1002\/prac.19000610129","article-title":"Ueber Hydrazone der Dithiokohlens\u00e4ureester","volume":"61","author":"Busch","year":"1900","journal-title":"J. Prakt. Chem."},{"key":"B14","doi-asserted-by":"publisher","first-page":"292","DOI":"10.1039\/JR9530000292","article-title":"The isomeric dithiacyclopentenethiones","author":"Challenger","year":"1953","journal-title":"J. Chem. Soc."},{"key":"B15","doi-asserted-by":"publisher","first-page":"261","DOI":"10.1021\/ja00417a056","article-title":"Benzocyclobutene","volume":"98","author":"Chapman","year":"1976","journal-title":"J. Am. Chem. Soc."},{"key":"B16","doi-asserted-by":"publisher","first-page":"283","DOI":"10.1016\/j.cat.2004.04.028","article-title":"Structure and catalytic properties of molybdenum oxide catalysts supported on zirconia","volume":"226","author":"Chary","year":"2004","journal-title":"J. Catal."},{"key":"B17","volume-title":"Process for the Preparation of Cyclic Organo Trithiocarbonates. US Patent 2,193,415","author":"Coltof","year":"1940"},{"key":"B18","unstructured":"Reactions of ethylene oxides. Part 1. Preparation of ethylene sulphides and trithiocarbonates10501052\n            CulvenorC. C. J.\n            DaviesW.\n            PausackerK. H.\n          10.1039\/JR9460001050J. Chem. Soc.1946"},{"key":"B19","volume-title":"Process to Prepare Dithiocarbonates from Trithiocarbonates. European Patent 582,183","author":"Degani","year":"1994"},{"key":"B20","doi-asserted-by":"publisher","first-page":"894","DOI":"10.1055\/s-1986-31819","article-title":"Phase-transfer synthesis of symmetrical and unsymmetrical dialkyl trithiocarbonates","author":"Degani","year":"1986","journal-title":"Synthesis"},{"key":"B21","first-page":"195","article-title":"Vacuum gas solid reactions (VGSR): application to the synthesis of unstable species","volume-title":"Gas Phase Reactions in Organic Synthesis","author":"Denis","year":"1997"},{"key":"B22","doi-asserted-by":"publisher","first-page":"4431","DOI":"10.1016\/S0040-4020(01)86145-7","article-title":"Synthese d'imines lineaires non-stabilisees par reactions gaz-solide sous vide","volume":"44","author":"Guillemin","year":"1988","journal-title":"Tetrahedron"},{"key":"B23","doi-asserted-by":"publisher","first-page":"4447","DOI":"10.1016\/S0040-4020(01)86146-9","article-title":"Synthese d'imines cycliques non-stabilisees par reactions gaz-solide sous vide et thermolyse-eclair","volume":"44","author":"Guillemin","year":"1988","journal-title":"Tetrahedron"},{"key":"B24","doi-asserted-by":"publisher","first-page":"579","DOI":"10.1021\/acs.joc.6b02586","article-title":"Synthesis of Combretastatins D-1, D-2, and D-4 via ring contraction by flash vacuum pyrolysis","volume":"82","author":"Harras","year":"2017","journal-title":"J. Org. Chem."},{"key":"B25","doi-asserted-by":"publisher","first-page":"2959","DOI":"10.1002\/app.12936","article-title":"Viable utilization of polycarbonate as a phosgene equivalent illustrated by reactions with alkanedithiols. mercaptoethanol, aminoethanethiol and aminoethanol: A solution for the issue of carbon resource conservation","volume":"90","author":"Hata","year":"2003","journal-title":"J. Appl. Polym. Sci."},{"key":"B26","doi-asserted-by":"publisher","first-page":"4357","DOI":"10.1021\/jo900224t","article-title":"Efficient method for the preparation of peracetylated Neu5Ac2en by flash vacuum pyrolysis","volume":"74","author":"Horn","year":"2009","journal-title":"J. Org. Chem."},{"key":"B27","doi-asserted-by":"publisher","first-page":"10911","DOI":"10.1021\/j100027a035","article-title":"Catalytic properties of supported molybdenum oxide catalysts: In situ Raman and methanol oxidation studies","volume":"99","author":"Hu","year":"1995","journal-title":"J. Phys. Chem."},{"key":"B28","doi-asserted-by":"publisher","first-page":"879","DOI":"10.1246\/bcsj.59.879","article-title":"Polymer-supported diaryl selenoxide and telluroxide as mild and selective oxidizing agents","volume":"59","author":"Hu","year":"1986","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"B29","first-page":"83","article-title":"Ueber den Sulfokohlens\u00e4ure-Aethylglycol\u00e4ther (Aethylensulfocarbonat)","volume":"123","author":"Husemann","year":"1862","journal-title":"Liebigs Ann. Chem."},{"key":"B30","doi-asserted-by":"publisher","first-page":"269","DOI":"10.1002\/jlac.18631260304","article-title":"Ueber schwefelhaltige Abk\u00f6mmlinge der Kohlenwasserstoffe aus der Reihe CnH2n","volume":"126","author":"Husemann","year":"1863","journal-title":"Liebigs Ann. Chem."},{"key":"B31","volume-title":"Electrolyte and Battery Using the Same. US Patent","author":"Ihara","year":"2008"},{"key":"B32","doi-asserted-by":"publisher","first-page":"381","DOI":"10.1016\/0022-328X(87)87010-9","article-title":"D\u00e9carbonylation des dithiocarbonates: Une voie d'acc\u00e8s g\u00e9n\u00e9rale aux complexes binucl\u00e9aires bis-m-(S-alkyl)-hexacarbonyldifer","volume":"326","author":"Lagadec","year":"1987","journal-title":"J. Organomet. Chem."},{"key":"B33","doi-asserted-by":"publisher","first-page":"1020","DOI":"10.1021\/cs3008335","article-title":"Mixed oxides as highly selective catalysts for the flash pyrolysis of phenacyl benzotriazole: one-pot synthesis of dibenzazepin-7-one","volume":"3","author":"Lener","year":"2013","journal-title":"ACS Catal."},{"key":"B34","doi-asserted-by":"publisher","first-page":"1298","DOI":"10.1002\/cber.19640970513","article-title":"Schwefel-Heterocyclen und Vorstufen, XXXIII. Pr\u00e4parative Synthese und Folgereaktionen des Isotrithions (1.3-Dithiol-thions-(2)) und Isodithions (1.3-Dithiol-ons-(2))","volume":"97","author":"Mayer","year":"1964","journal-title":"Chem. Ber."},{"key":"B35","unstructured":"unpublished results described in McDougald\n            McDougaldG.\n            McNabH.\n          University of Edinburgh\u201cDevelopment of New Catalytic Preparative Gas-Phase Processes,\u201d2000"},{"key":"B36","doi-asserted-by":"publisher","first-page":"61","DOI":"10.1002\/jlac.18912620104","article-title":"Ueber das sogenannte \u201dRhodan\u00e4thylsulfin\u201c","volume":"262","author":"Miolati","year":"1891","journal-title":"Liebigs Ann. Chem."},{"key":"B37","doi-asserted-by":"publisher","first-page":"98","DOI":"10.1016\/j.apcata.2009.11.003","article-title":"Catalytic flash vacuum pyrolysis (CFVP): A new way to afford 7H-dibenzo[b,d]azepin-7-one","volume":"373","author":"Moyano","year":"2010","journal-title":"Appl. Catal. A"},{"key":"B38","doi-asserted-by":"publisher","first-page":"2179","DOI":"10.1021\/ol070690c","article-title":"One-Pot Synthesis of 7H-Dibenzo[b,d]azepin-7-one by Heterogeneous Flash Vacuum Pyrolysis with MCM-41 Catalysts","volume":"9","author":"Moyano","year":"2007","journal-title":"Org. Lett."},{"key":"B39","doi-asserted-by":"publisher","first-page":"5427","DOI":"10.1021\/ja01553a027","article-title":"Synthesis of compounds related to segments of synthetic sulfhydryl polymers","volume":"80","author":"Overberger","year":"1958","journal-title":"J. Am. Chem. Soc."},{"key":"B40","doi-asserted-by":"publisher","first-page":"737","DOI":"10.1002\/prac.19813230506","article-title":"1H- und 13C-NMR-chemische Verschiebungen von 5-Ring-Schwefel- und Selenheterocyclen. Ein Betrag zum Zusammenhang zwischen Elektronenstruktur und 13C-chemischer Verschiebung von C = O, C = S und C = Se Gruppierungen","volume":"323","author":"Poleschner","year":"1981","journal-title":"J. Prakt. Chem."},{"key":"B41","doi-asserted-by":"publisher","first-page":"253","DOI":"10.1016\/j.arabjc.2010.10.027","article-title":"Preparation, characterization and catalytic activity of MoO3\/CeO2-ZrO2 solid heterogeneous catalyt for the synthesis of \u03b2-enaminones","volume":"7","author":"Rathod","year":"2014","journal-title":"Arabian J. Chem."},{"key":"B42","doi-asserted-by":"publisher","first-page":"2845","DOI":"10.1021\/ja00190a017","article-title":"Molecular structures of unstable dichloroketene and its precursor, trichloroacetyl chloride, from electron diffraction","volume":"111","author":"Rozsondai","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"B43","doi-asserted-by":"publisher","first-page":"521","DOI":"10.1002\/14356007.a16_655","article-title":"Molybdenum and molybdenum compounds","volume":"23","author":"Sebenik","year":"2012","journal-title":"Ullmann's Encyclopedia Indust. Chem."},{"key":"B44","doi-asserted-by":"publisher","first-page":"1595","DOI":"10.1007\/s12039-017-1372-5","article-title":"Reaction of three cyclic thioester ligands with triiron dodecacarbonyl and possible reaction mechanisms","volume":"129","author":"Xiao","year":"2017","journal-title":"J. Chem. Sci."}],"container-title":["Frontiers in Chemistry"],"original-title":[],"link":[{"URL":"https:\/\/www.frontiersin.org\/article\/10.3389\/fchem.2019.00204\/full","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2019,4,5]],"date-time":"2019-04-05T03:48:09Z","timestamp":1554436089000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.frontiersin.org\/article\/10.3389\/fchem.2019.00204\/full"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,4,5]]},"references-count":44,"alternative-id":["10.3389\/fchem.2019.00204"],"URL":"https:\/\/doi.org\/10.3389\/fchem.2019.00204","relation":{},"ISSN":["2296-2646"],"issn-type":[{"value":"2296-2646","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,4,5]]},"article-number":"204"}}