{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,11]],"date-time":"2025-12-11T20:18:00Z","timestamp":1765484280407,"version":"3.41.2"},"reference-count":43,"publisher":"Frontiers Media SA","license":[{"start":{"date-parts":[[2022,5,5]],"date-time":"2022-05-05T00:00:00Z","timestamp":1651708800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["frontiersin.org"],"crossmark-restriction":true},"short-container-title":["Front. Chem."],"abstract":"<jats:p>Four selenoarsenates with different transition-metal complexes [Co(tren)<jats:sub>2<\/jats:sub>H]AsSe<jats:sub>4<\/jats:sub> [tren = tris(2-aminoethyl)amine] (<jats:bold>1<\/jats:bold>); [Ni<jats:sub>2<\/jats:sub>(dien)<jats:sub>4<\/jats:sub>](As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>) (dien = diethylenetriamine) (<jats:bold>2<\/jats:bold>); [Zn(tren)]<jats:sub>2<\/jats:sub>(As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>) (<jats:bold>3<\/jats:bold>) and [Mn(tren)]<jats:sub>2<\/jats:sub>(As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>) (<jats:bold>4<\/jats:bold>) were solvothermally synthesized in a mixed solvent of organic amine and alcohol solution. The compounds <jats:bold>1-4<\/jats:bold> have pyramidal\/tetrahedral structures (AsSe<jats:sub>3<\/jats:sub>\/AsSe<jats:sub>4<\/jats:sub>), and contain transition metal (Co<jats:sup>2+<\/jats:sup>, Ni<jats:sup>2+<\/jats:sup>, Zn<jats:sup>2+<\/jats:sup> and Mn<jats:sup>2+<\/jats:sup>) complex that form distinct zero-dimensional (0-D) clusters. Arsenic atoms form a tetrahedron in compounds <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold>; <jats:bold>1<\/jats:bold> consists of discrete tetrahedral (AsSe<jats:sub>4<\/jats:sub>) and transition metal complex [Co(tren)<jats:sub>2<\/jats:sub>]<jats:sup>2+<\/jats:sup>; <jats:bold>2<\/jats:bold> is composed of an anion [As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>]<jats:sup>4-<\/jats:sup> cluster and transition metal complex [Ni(dien)<jats:sub>2<\/jats:sub>]<jats:sup>2+<\/jats:sup>. In compounds <jats:bold>3<\/jats:bold> and <jats:bold>4<\/jats:bold>, arsenic atom forms a pyramidal AsSe<jats:sub>3<\/jats:sub> and the two pyramidal AsSe<jats:sub>3<\/jats:sub> share a corner connection to form a dimer [As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>]<jats:sup>4-<\/jats:sup>; <jats:bold>3<\/jats:bold> is characterized as a cluster consisting of two unsaturated [Zn(tren)]<jats:sup>2+<\/jats:sup> caiton linked by a dimer (As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>)<jats:sup>4-<\/jats:sup> linkage; in <jats:bold>4<\/jats:bold>, unsaturated [Mn(tren)]<jats:sup>2+<\/jats:sup> caiton is linked to two trigonal-bipyramidal [Mn(tren)]Se via dimer (As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>)<jats:sup>4-<\/jats:sup> to form [Mn(tren)]<jats:sub>4<\/jats:sub>[As<jats:sub>4<\/jats:sub>Se<jats:sub>10<\/jats:sub>] cluster. To our knowledge, [Zn(tren)]<jats:sub>2<\/jats:sub>(As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>) (<jats:bold>3<\/jats:bold>) is the first zinc selenoarsenate containing the (As<jats:sub>2<\/jats:sub>Se<jats:sub>5<\/jats:sub>)<jats:sup>4-<\/jats:sup> anion type. Furthermore, the Mn<jats:sup>2+<\/jats:sup> ions adopt a trigonal-biyramidal (five-coordinate) and octahedral (six-coordinate) environment. Adding K<jats:sub>2<\/jats:sub>CO<jats:sub>3<\/jats:sub>\/Cs<jats:sub>2<\/jats:sub>CO<jats:sub>3<\/jats:sub> to the synthesis system is necessary and may act as a mineralizer. Several properties of compounds <jats:bold>1<\/jats:bold>-<jats:bold>4<\/jats:bold> have been characterized in our studies, in particular their strong photocurrent response characteristics under visible light irradiation.<\/jats:p>","DOI":"10.3389\/fchem.2022.890496","type":"journal-article","created":{"date-parts":[[2022,5,5]],"date-time":"2022-05-05T06:06:34Z","timestamp":1651730794000},"update-policy":"https:\/\/doi.org\/10.3389\/crossmark-policy","source":"Crossref","is-referenced-by-count":3,"title":["Strong Photocurrent Response of Selenoarsenates With Different Transition Metal Complexes as Structure-Directing Agents"],"prefix":"10.3389","volume":"10","author":[{"given":"Xinyu","family":"Tian","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gele","family":"Teri","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Muge","family":"Shele","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Namila","family":"E","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Liming","family":"Qi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Min","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Menghe","family":"Baiyin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1965","published-online":{"date-parts":[[2022,5,5]]},"reference":[{"key":"B1","doi-asserted-by":"publisher","first-page":"594","DOI":"10.1016\/j.jallcom.2017.01.284","article-title":"Syntheses, Structures and Properties of a Series of New Lanthanide Chalcoarsenates(III) Containing crown-shaped [As3Q6]3\u2212 (Q = S, Se) Clusters","volume":"702","author":"An","year":"2017","journal-title":"J. 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