{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T15:59:32Z","timestamp":1792598372715,"version":"4.5.0"},"reference-count":88,"publisher":"Frontiers Media SA","license":[{"start":{"date-parts":[[2022,10,7]],"date-time":"2022-10-07T00:00:00Z","timestamp":1665100800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["frontiersin.org"],"crossmark-restriction":true},"short-container-title":["Front. Chem."],"abstract":"<jats:p>\n                    In this study, controllable and optimal microwave irradiation has been used to synthesize the novel nanostructures of Bi\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    under environmental conditions. The final products had a thermal stability of 210\u00b0C, an average particle size distribution of 85\u00a0nm, and a surface area of 783\u00a0m\n                    <jats:sup>2<\/jats:sup>\n                    \/g. The high thermodynamic stability of Bi\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    nanostructures was confirmed by TG and differential scanning calorimetry (DSC) analyses. The nanostructure nature of compounds, and most importantly, the use of an effective, cost-effective, and rapid synthesis route of microwave have created significant physiochemical properties in the Bi\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    products. These unexpected properties have made the possibility of potential application of these products in various fields, especially in nano-catalyst applications. It is well-documented that, as Lewis acid, bismuth nano-catalyst exhibits a great catalytic activity for the green synthesis of some bio-active barbituric acid derivatives using precursors with electron-donating or electron-withdrawing nature in high yields (80%\u201398%). After incorporating this catalyst into the aqueous media, all the reactions were completed within 2\u20133\u00a0min at room temperature. The main advantages of this method are practical facility, the availability of starting materials, and low costs besides the catalyst reusability. Additionally, the catalyst synthesis process may be carried out in the aqueous media for a short period with medium to high yields. The obtained results have opened a new window for the development of a novel nano-catalyst with practical application.\n                  <\/jats:p>","DOI":"10.3389\/fchem.2022.951229","type":"journal-article","created":{"date-parts":[[2022,10,7]],"date-time":"2022-10-07T00:21:41Z","timestamp":1665102101000},"update-policy":"https:\/\/doi.org\/10.3389\/crossmark-policy","source":"Crossref","is-referenced-by-count":9,"title":["Microwave-assisted synthetic method of novel Bi2O3 nanostructure and its application as a high-performance nano-catalyst in preparing benzylidene barbituric acid derivatives"],"prefix":"10.3389","volume":"10","author":[{"given":"Mahdieh","family":"Yahyazadehfar","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Enayatollah","family":"Sheikhhosseini","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sayed Ali","family":"Ahmadi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dadkhoda","family":"Ghazanfari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1965","published-online":{"date-parts":[[2022,10,7]]},"reference":[{"key":"B1","doi-asserted-by":"publisher","first-page":"4443","DOI":"10.1007\/s11164-015-2289-6","article-title":"Succinimidinium N-sulfonic acid hydrogen sulfate as an efficient ionic liquid catalyst for the synthesis of 5-arylmethylene-pyrimidine-2, 4, 6-trione and pyrano [2, 3-d] pyrimidinone derivatives","volume":"42","author":"Abedini","year":"2016","journal-title":"Res. 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