{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T15:48:10Z","timestamp":1753890490639,"version":"3.41.2"},"reference-count":47,"publisher":"Frontiers Media SA","license":[{"start":{"date-parts":[[2024,12,17]],"date-time":"2024-12-17T00:00:00Z","timestamp":1734393600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["frontiersin.org"],"crossmark-restriction":true},"short-container-title":["Front. Chem."],"abstract":"<jats:p>Rhodium(III) catalysis has been used for C-H activation of <jats:italic>N<\/jats:italic>-nitrosoanilines with substituted allyl alcohols. This method provides an efficient synthesis of the functional <jats:italic>N<\/jats:italic>-nitroso <jats:italic>ortho<\/jats:italic> \u03b2-aryl aldehydes and ketones with low catalyst loading, high functional group tolerance, and superior reactivity of allyl alcohols toward <jats:italic>N<\/jats:italic>-nitrosoanilines. We demonstrated that reaction also proceeds through the one-pot synthesis of <jats:italic>N<\/jats:italic>-nitrosoaniline, followed by subsequent, C-H activation. The protocol was also feasible with acyrlaldehyde and methyl vinyl ketone which furnished the same oxidative <jats:italic>N<\/jats:italic>-nitroso coupling product.<\/jats:p>","DOI":"10.3389\/fchem.2024.1506493","type":"journal-article","created":{"date-parts":[[2024,12,17]],"date-time":"2024-12-17T04:20:05Z","timestamp":1734409205000},"update-policy":"https:\/\/doi.org\/10.3389\/crossmark-policy","source":"Crossref","is-referenced-by-count":0,"title":["Oxidative coupling of N-nitrosoanilines with substituted allyl alcohols under rhodium (III) catalysis"],"prefix":"10.3389","volume":"12","author":[{"given":"Priyanka","family":"Chaudhary","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1965","published-online":{"date-parts":[[2024,12,17]]},"reference":[{"key":"B1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-60328-0","article-title":"Application of transition metal catalysts in organic synthesis","author":"Brandsma","year":"1999","journal-title":"Springer Desktop Ed. 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