{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T05:57:24Z","timestamp":1790575044345,"version":"4.1.0"},"reference-count":60,"publisher":"Frontiers Media SA","license":[{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["frontiersin.org"],"crossmark-restriction":true},"short-container-title":["Front. Chem."],"abstract":"<jats:p>The radical-mediated 1,2-boron shift strategy has emerged as a promising and powerful approach for the construction of functionalized organoboron compounds. This review summarizes and categorizes the relevant studies based on the distinct mechanisms underlying the generation of \u03b2-boryl radicals, such as radical addition, oxidative cleavage, decarboxylation reactions, or hydrogen atom transfer (HAT). Furthermore, the reaction scopes, synthetic utilities, and underlying mechanistic pathways are thoroughly examined to provide a comprehensive overview of this evolving strategy.<\/jats:p>","DOI":"10.3389\/fchem.2026.1955064","type":"journal-article","created":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T05:45:41Z","timestamp":1790574341000},"update-policy":"https:\/\/doi.org\/10.3389\/crossmark-policy","source":"Crossref","is-referenced-by-count":0,"title":["Radical 1,2-boron shift in modern organoboron synthesis"],"prefix":"10.3389","volume":"14","author":[{"given":"Yunkai","family":"Zhang","sequence":"first","affiliation":[{"name":"College of Chemistry, Zhengzhou University","place":["Zhengzhou, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinduo","family":"Shen","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University","place":["Zhengzhou, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiuren","family":"Wei","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University","place":["Zhengzhou, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xi","family":"Li","sequence":"additional","affiliation":[{"name":"Hunan Provincial University Key Laboratory of the Fundamental and Clinical Research on Functional Nucleic Acid, Changsha Medical University","place":["Changsha, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongyan","family":"Cao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Henan University","place":["Kaifeng, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Sun","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University","place":["Zhengzhou, China"]},{"name":"International Innovation Center for Forest Chemicals and Materials, Nanjing Forestry University","place":["Nanjing, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingbo","family":"Qu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University","place":["Zhengzhou, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing","family":"Yu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Zhengzhou University","place":["Zhengzhou, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1965","published-online":{"date-parts":[[2026,9,28]]},"reference":[{"key":"B1","doi-asserted-by":"publisher","first-page":"1798","DOI":"10.1002\/(SICI)1521-3773(19990614)38:12<1798::AID-ANIE1798>3.0.CO;2-0","article-title":"The first boron-tethered radical cyclizations and intramolecular homolytic substitutions at boron","volume":"38","author":"Batey","year":"1999","journal-title":"Angew. 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