{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,8]],"date-time":"2026-04-08T20:21:30Z","timestamp":1775679690861,"version":"3.50.1"},"reference-count":72,"publisher":"Frontiers Media SA","license":[{"start":{"date-parts":[[2023,4,25]],"date-time":"2023-04-25T00:00:00Z","timestamp":1682380800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["MARTERA\/0004\/2017 2021.07744.BD UIDB\/50011\/2020 UIDP\/50011\/2020 LA\/P\/0006\/2020"],"award-info":[{"award-number":["MARTERA\/0004\/2017 2021.07744.BD UIDB\/50011\/2020 UIDP\/50011\/2020 LA\/P\/0006\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010665","name":"H2020 Marie Sk\u0142odowska-Curie Actions","doi-asserted-by":"publisher","award":["101007430"],"award-info":[{"award-number":["101007430"]}],"id":[{"id":"10.13039\/100010665","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["frontiersin.org"],"crossmark-restriction":true},"short-container-title":["Front. Chem. Eng."],"abstract":"<jats:p>The detection of corrosion at early stages could increase the service life of metal-based infrastructures in a cost-effective manner. Despite the recent progress in \u201csmart\u201d self-reporting corrosion sensing coatings, the development of environmentally friendly systems appropriate for steel substrate used in offshore applications remains a relevant challenge. In this study, a novel smart corrosion sensing coating, based on hexacyanoferrate intercalated Mg-Al LDH nanoadditive, was developed, aiming at the detection of early-stage corrosion of carbon steel. The detection mechanism is based on the ability of hexacyanoferrate ions to react with iron cations generated during the corrosion process, giving rise to a colorimetric signal, while LDH carriers provide a controlled release of active ions under corrosion conditions. The sensing nanoadditive was embedded into a commercial pigment-free water-based acrylic polyurethane coating. The nanomaterial was characterized structurally (XRD) and morphologically (STEM). The compatibility of the additive with the polymer formulation and its influence on the resulting coating performance was investigated in terms of rheological behavior, structure (FTIR), morphology (SEM\/EDS), thermal (TGA, DSC) and mechanical (adhesion, hardness) properties. The corrosion protection ability of the coating was evaluated via EIS, while the sensing functionality was analyzed by visual analysis of the surface. The developed coating successfully detects early-stage corrosion of steel substrate at a lab scale, in conditions relevant to the use of metallic structures in offshore applications, demonstrating a correlation between the level of material degradation and the spectroscopic signal associated with the presence of the LDH functional nanoadditive. Furthermore, the observed decrease in coating barrier properties, caused by the presence of LDH, was overcome by the subsequent development of a multilayer coating system. Two different topcoats (epoxy- and polyurethane-based) were surveyed for this purpose, showing an improvement in the coating barrier properties without influencing the corrosion detection functionality of the sensing layer. The results were successfully validated by standard salt spray tests. The multilayer approach opens up the possibility to model coatings with different characteristics for various operating conditions.<\/jats:p>","DOI":"10.3389\/fceng.2023.1145049","type":"journal-article","created":{"date-parts":[[2023,4,25]],"date-time":"2023-04-25T04:45:51Z","timestamp":1682397951000},"update-policy":"https:\/\/doi.org\/10.3389\/crossmark-policy","source":"Crossref","is-referenced-by-count":9,"title":["A novel smart coating with hexacyanoferrate intercalated layered double hydroxides nanoadditive for early detection of carbon steel corrosion"],"prefix":"10.3389","volume":"5","author":[{"given":"Alesia","family":"Sushkova","sequence":"first","affiliation":[]},{"given":"Rodrigo","family":"Montes","sequence":"additional","affiliation":[]},{"given":"Tiago","family":"Paulino","sequence":"additional","affiliation":[]},{"given":"Isabel","family":"Sousa","sequence":"additional","affiliation":[]},{"given":"Cristina","family":"Neves","sequence":"additional","affiliation":[]},{"given":"M\u00e1rio G. S.","family":"Ferreira","sequence":"additional","affiliation":[]},{"given":"Jo\u00e3o","family":"Tedim","sequence":"additional","affiliation":[]}],"member":"1965","published-online":{"date-parts":[[2023,4,25]]},"reference":[{"key":"B1","volume-title":"Standard test methods for rating adhesion by tape test, D3359-22","year":"2022"},{"key":"B2","doi-asserted-by":"publisher","first-page":"2618","DOI":"10.1021\/am900527s","article-title":"Early detection of steel corrosion via \u201cTurn-On\u201d fluorescence in smart epoxy coatings","volume":"1","author":"Augustyniak","year":"2009","journal-title":"ACS Appl. Mat. Interfaces"},{"key":"B3","doi-asserted-by":"publisher","first-page":"463","DOI":"10.1515\/epoly-2016-0154","article-title":"FT-IR spectroscopic and thermal study of waterborne polyurethane-acrylate leather coatings using tartaric acid as an ionomer","volume":"16","author":"Bahadur","year":"2016","journal-title":"e-Polymers"},{"key":"B4","doi-asserted-by":"publisher","first-page":"2009","DOI":"10.1002\/elan.201000076","article-title":"Localised measurements of pH and dissolved oxygen as complements to SVET in the investigation of corrosion at defects in coated aluminum alloy","volume":"22","author":"Bastos","year":"2010","journal-title":"Electroanalysis"},{"key":"B5","doi-asserted-by":"publisher","first-page":"594","DOI":"10.1016\/j.progpolymsci.2013.07.011","article-title":"Advances in layered double hydroxide (LDH)-based elastomer composites","volume":"39","author":"Basu","year":"2014","journal-title":"Prog. Polym. Sci."},{"key":"B6","doi-asserted-by":"publisher","first-page":"100857","DOI":"10.1016\/j.apmt.2020.100857","article-title":"Layered double hydroxides (LDHs) as functional materials for the corrosion protection of aluminum alloys: A review","volume":"21","author":"Bouali","year":"2020","journal-title":"Appl. Mat. Today"},{"key":"B7","doi-asserted-by":"publisher","first-page":"1217","DOI":"10.1016\/0025-5408(94)90144-9","article-title":"Orientational effects in the infrared spectrum of the double layer material, magnesium aluminum hydroxide ferrocyanide","volume":"29","author":"Braterman","year":"1994","journal-title":"Mat. Res. Bull."},{"key":"B8","doi-asserted-by":"publisher","first-page":"27168","DOI":"10.1021\/acsami.2c05048","article-title":"Synthesis of smart nanofiber coatings with autonomous self-warning and self-healing functions","volume":"14","author":"Cao","year":"2022","journal-title":"ACS Appl. Mat. Interfaces"},{"key":"B9","doi-asserted-by":"publisher","first-page":"173","DOI":"10.1016\/0920-5861(91)80068-K","article-title":"Hydrotalcite-type anionic clays: Preparation, properties and applications","volume":"11","author":"Cavani","year":"1991","journal-title":"Catal. Today."},{"key":"B10","doi-asserted-by":"publisher","first-page":"138582","DOI":"10.1016\/j.cej.2022.138582","article-title":"Micro\/nanocontainer-based intelligent coatings: Synthesis, performance and applications \u2013 a review","volume":"451","author":"Chen","year":"2023","journal-title":"J. Chem. Eng."},{"key":"B11","doi-asserted-by":"publisher","first-page":"8","DOI":"10.1016\/j.porgcoat.2015.07.020","article-title":"Smart corrosion sensing phenanthroline modified alkyd coatings","volume":"89","author":"Dhole","year":"2015","journal-title":"Prog. Org. Coat."},{"key":"B12","doi-asserted-by":"publisher","first-page":"970","DOI":"10.3390\/coatings10100970","article-title":"Assessment of anti-corrosion performances of coating systems for corrosion prevention of offshore wind power steel structures","volume":"10","author":"Eom","year":"2020","journal-title":"Coatings"},{"key":"B13","doi-asserted-by":"publisher","first-page":"812","DOI":"10.1021\/acsanm.8b02045","article-title":"Nanosensors for monitoring early stages of metallic corrosion","volume":"2","author":"Exbrayat","year":"2019","journal-title":"ACS Appl. Nano Mat."},{"key":"B14","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/B978-0-323-85451-1.00002-0","article-title":"Chapter 2 - life cycle assessment in mining industries","volume-title":"Life cycle assessment for sustainable mining","author":"Farjana","year":"2021"},{"key":"B15","doi-asserted-by":"publisher","first-page":"425","DOI":"10.1002\/tox.20198","article-title":"Effects of N-heterocyclic polyaromatic hydrocarbons on survival, reproduction, and biochemical parameters in Daphnia magna","volume":"21","author":"Feldmannov\u00e1","year":"2006","journal-title":"Environ. Toxicol."},{"key":"B16","doi-asserted-by":"publisher","first-page":"957","DOI":"10.5006\/1.3283932","article-title":"Corrosion-sensing behavior of an acrylic-based coating system","volume":"55","author":"Frankel","year":"1999","journal-title":"Corrosion"},{"key":"B17","doi-asserted-by":"publisher","first-page":"526","DOI":"10.1016\/j.cej.2018.02.061","article-title":"Improving the functionality and performance of AA2024 corrosion sensing coatings with nanocontainers","volume":"341","author":"Galv\u00e3o","year":"2018","journal-title":"J. Chem. Eng."},{"key":"B18","doi-asserted-by":"publisher","first-page":"106218","DOI":"10.1016\/j.porgcoat.2021.106218","article-title":"A focused review on smart carriers tailored for corrosion protection: Developments, applications, and challenges","volume":"154","author":"Habib","year":"2021","journal-title":"Prog. Org. Coat."},{"key":"B19","doi-asserted-by":"publisher","first-page":"1069","DOI":"10.1126\/science.aal4151","article-title":"The geologic history of seawater pH","volume":"355","author":"Halevy","year":"2017","journal-title":"Science"},{"key":"B20","doi-asserted-by":"publisher","first-page":"170","DOI":"10.1346\/CCMN.1994.0420207","article-title":"Synthesis and properties of hexacyanoferrate interlayered in hydrotalcite. I. Hexacyanoferrate(II)","volume":"42","author":"Hansen","year":"1994","journal-title":"Clays Clay Min."},{"key":"B21","doi-asserted-by":"publisher","first-page":"194","DOI":"10.1016\/j.ndteint.2018.12.007","article-title":"Nonlinear resonant ultrasound spectroscopy of stress corrosion cracking in stainless steel rods","volume":"102","author":"Hogg","year":"2019","journal-title":"NDT E Int."},{"key":"B22","doi-asserted-by":"publisher","first-page":"273","DOI":"10.1016\/S0167-2738(96)00478-X","article-title":"Hexacyanoferrate-interlayered hydrotalcite","volume":"92","author":"Holgado","year":"1996","journal-title":"Solid State Ion."},{"key":"B23","doi-asserted-by":"publisher","first-page":"143","DOI":"10.4236\/jss.2015.32019","article-title":"Environmental impacts of corrosion on the physical properties of copper and aluminium: A case study of the surrounding water bodies in port harcourt","volume":"3","author":"Ikechukwu","year":"2015","journal-title":"Open J. Soc. Sci."},{"key":"B24","volume-title":"Corrosion tests in artificial atmospheres \u2013 salt spray tests ISO 9227: 2022","year":"2022"},{"key":"B25","volume-title":"Plastics \u2014 differential scanning calorimetry (DSC) \u2014 Part 2: Determination of glass transition temperature and step height ISO 11357-2: 2020","year":"2020"},{"key":"B26","doi-asserted-by":"publisher","first-page":"257","DOI":"10.1016\/j.marpolbul.2018.08.058","article-title":"Emissions from corrosion protection systems of offshore wind farms: Evaluation of the potential impact on the marine environment","volume":"136","author":"Kirchgeorg","year":"2018","journal-title":"Mar. Pollut. Bull."},{"key":"B27","doi-asserted-by":"publisher","first-page":"623","DOI":"10.2138\/am-2002-5-604","article-title":"Infrared and Raman study of interlayer anions CO32-, NO3-, SO42- and ClO4- in Mg\/Al-hydrotalcite","volume":"87","author":"Kloprogge","year":"2002","journal-title":"Am. Min."},{"key":"B28","volume-title":"International measures of prevention, application, and economics of corrosion technologies (IMPACT) study","author":"Koch","year":"2016"},{"key":"B29","doi-asserted-by":"publisher","first-page":"2367","DOI":"10.1016\/s0006-3495(94)80723-4","article-title":"Components of the carbonyl stretching band in the infrared spectra of hydrated 1,2-diacylglycerolipid bilayers: A reevaluation","volume":"67","author":"Lewis","year":"1994","journal-title":"Biophys. J."},{"key":"B30","first-page":"07228","article-title":"Controlled release microcapsules for smart coatings","volume-title":"Nace \u2013 int. Corros. Conf. 2007","author":"Li","year":"2007"},{"key":"B31","doi-asserted-by":"publisher","first-page":"3194","DOI":"10.1039\/C9NR09221H","article-title":"Synthesis of nanosensors for autonomous warning of damage and self-repairing in polymeric coatings","volume":"12","author":"Liu","year":"2020","journal-title":"Nanoscale"},{"key":"B32","doi-asserted-by":"publisher","first-page":"1181","DOI":"10.1023\/A:1006517005082","article-title":"Vickers indentation responses of epoxy polymers","volume":"17","author":"Low","year":"1998","journal-title":"J. Mat. Sci. Lett."},{"key":"B33","doi-asserted-by":"publisher","first-page":"169","DOI":"10.3390\/nano11010169","article-title":"Construction of zeolite-loaded fluorescent supramolecular on-off probes for corrosion detection based on a cation exchange mechanism","volume":"11","author":"Lv","year":"","journal-title":"Nanomaterials"},{"key":"B34","doi-asserted-by":"publisher","first-page":"309","DOI":"10.1016\/j.jtice.2020.12.032","article-title":"Intelligent anti-corrosion and corrosion detection coatings based on layered supramolecules intercalated by fluorescent off-on probes","volume":"118","author":"Lv","year":"","journal-title":"J. Taiwan Inst. Chem. Eng."},{"key":"B35","doi-asserted-by":"publisher","first-page":"127854","DOI":"10.1016\/j.cej.2020.127854","article-title":"Self-reporting coatings for autonomous detection of coating damage and metal corrosion: A review","volume":"421","author":"Ma","year":"2021","journal-title":"J. Chem. Eng."},{"key":"B36","doi-asserted-by":"publisher","first-page":"4014","DOI":"10.1021\/ma050453u","article-title":"Rheological behavior of aqueous polyurethane dispersions: Effects of solid content, degree of neutralization, chain extension, and temperature","volume":"38","author":"Madbouly","year":"2005","journal-title":"Macromolecules"},{"key":"B37","doi-asserted-by":"publisher","first-page":"1287","DOI":"10.1039\/c2nr11536k","article-title":"Silica nanocontainers for active corrosion protection","volume":"4","author":"Maia","year":"2012","journal-title":"Nanoscale"},{"key":"B38","doi-asserted-by":"publisher","first-page":"415502","DOI":"10.1088\/0957-4484\/24\/41\/415502","article-title":"Nanocontainer-based corrosion sensing coating","volume":"24","author":"Maia","year":"2013","journal-title":"Nanotechnology"},{"key":"B39","doi-asserted-by":"publisher","first-page":"118973","DOI":"10.1016\/j.envpol.2022.118973","article-title":"Smart\u201d nanosensors for early detection of corrosion: Environmental behavior and effects on marine organisms","volume":"302","author":"Martins","year":"2022","journal-title":"Environ. Pollut."},{"key":"B40","doi-asserted-by":"publisher","first-page":"154","DOI":"10.1061\/(asce)1076-0342(2006)12:3(154)","article-title":"Recent progress in the modeling of corrosion of structural steel immersed in seawaters","volume":"12","author":"Melchers","year":"2006","journal-title":"J. Infrastruct. Syst."},{"key":"B41","doi-asserted-by":"publisher","first-page":"17","DOI":"10.1016\/j.surfcoat.2014.06.031","article-title":"Functional and smart coatings for corrosion protection: A review of recent advances","volume":"258","author":"Montemor","year":"2014","journal-title":"Surf. Coat. Technol."},{"key":"B42","doi-asserted-by":"publisher","first-page":"096739112210791","DOI":"10.1177\/09673911221079126","article-title":"Preparation and characterization of polyurethane rubber\/polypropylene-based thermoplastics vulcanizates nanocomposites with succinic anhydride intercalated layered double hydroxide","volume":"30","author":"Moshkriz","year":"2022","journal-title":"Polym. Polym. Compos."},{"key":"B43","doi-asserted-by":"publisher","first-page":"105013","DOI":"10.1016\/j.engfailanal.2020.105013","article-title":"High pH stress corrosion cracking initiation and crack evolution in buried steel pipelines: A review","volume":"120","author":"Niazi","year":"2021","journal-title":"Eng. Fail. Anal."},{"key":"B44","doi-asserted-by":"publisher","first-page":"1178","DOI":"10.1002\/celc.201600196","article-title":"Prussian blue degradation during hydrogen peroxide reduction: A scanning electrochemical microscopy study on the role of the hydroxide ion and hydroxyl radical","volume":"3","author":"No\u00ebl","year":"2016","journal-title":"ChemElectroChem"},{"key":"B45","doi-asserted-by":"publisher","first-page":"572","DOI":"10.1016\/j.molliq.2018.08.053","article-title":"Recent advances on organic coating system technologies for corrosion protection of offshore metallic structures","volume":"269","author":"Olajire","year":"2018","journal-title":"J. Mol. Liq."},{"key":"B46","doi-asserted-by":"publisher","first-page":"2353","DOI":"10.1021\/am900495r","article-title":"Novel inorganic host layered double hydroxides intercalated with guest organic inhibitors for anticorrosion applications","volume":"1","author":"Poznyak","year":"2009","journal-title":"ACS Appl. Mat. Interfaces"},{"key":"B47","doi-asserted-by":"publisher","first-page":"035115","DOI":"10.1063\/1.3562893","article-title":"Intercomparison of gamma scattering, gammatography, and radiography techniques for mild steel nonuniform corrosion detection","volume":"82","author":"Priyada","year":"2011","journal-title":"Rev. Sci. Instrum."},{"key":"B48","first-page":"1","article-title":"Corrosion detection in mild steel using effective post processing technique for modulated thermal imaging: A numerical study","author":"Raverkar","year":"2021"},{"key":"B49","doi-asserted-by":"crossref","DOI":"10.1002\/9780470277270","volume-title":"Corrosion and corrosion control","author":"Revie","year":"2008"},{"key":"B50","doi-asserted-by":"publisher","first-page":"880","DOI":"10.1016\/j.apsusc.2018.01.188","article-title":"Monitoring underlying epoxy-coated St-37 corrosion via 8-hydroxyquinoline as a fluorescent indicator","volume":"440","author":"Roshan","year":"2018","journal-title":"Appl. Surf. Sci."},{"key":"B51","doi-asserted-by":"publisher","first-page":"117109","DOI":"10.1016\/j.watres.2021.117109","article-title":"Assessing the aquatic toxicity and environmental safety of tracer compounds Rhodamine B and Rhodamine WT","volume":"197","author":"Skjolding","year":"2021","journal-title":"Water Res."},{"key":"B52","doi-asserted-by":"publisher","first-page":"1900662","DOI":"10.1002\/mame.201900662","article-title":"Chitosan microspheres as carriers for pH-indicating species in corrosion sensing","volume":"305","author":"Sousa","year":"2020","journal-title":"Macromol. Mat. Eng."},{"key":"B53","doi-asserted-by":"publisher","first-page":"7","DOI":"10.1080\/1478422X.2021.1976086","article-title":"Phosphate loaded layered double hydroxides for active corrosion protection of carbon steel","volume":"57","author":"Sui","year":"2022","journal-title":"Corros. Eng. Sci. Technol."},{"key":"B54","doi-asserted-by":"publisher","first-page":"107073","DOI":"10.1016\/j.porgcoat.2022.107073","article-title":"Investigation of intelligent protection and corrosion detection of epoxy-coated St-12 by redox-responsive microcapsules containing dual-functional 8-hydroxyquinoline","volume":"172","author":"Taheri","year":"2022","journal-title":"Prog. Org. Coat."},{"key":"B55","doi-asserted-by":"publisher","first-page":"103953","DOI":"10.1016\/j.autcon.2021.103953","article-title":"Detection, visualization, quantification, and warning of pipe corrosion using distributed fiber optic sensors","volume":"132","author":"Tan","year":"2021","journal-title":"Autom. Constr."},{"key":"B56","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.corsci.2011.10.003","article-title":"Zn\u2013Al layered double hydroxides as chloride nanotraps in active protective coatings","volume":"55","author":"Tedim","year":"2012","journal-title":"Corros. Sci."},{"key":"B57","doi-asserted-by":"publisher","first-page":"3604","DOI":"10.1021\/acs.nanolett.1c00620","article-title":"Halochromic polymer nanosensors for simple visual detection of local pH in coatings","volume":"21","author":"Theerasilp","year":"2021","journal-title":"Nano Lett."},{"key":"B58","doi-asserted-by":"publisher","first-page":"263","DOI":"10.1002\/app.31096","article-title":"Characterization of polyurethane resins by FTIR, TGA, and XRD","volume":"115","author":"Trovati","year":"2010","journal-title":"J. Appl. Polym. Sci."},{"key":"B59","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1109\/TMAG.2018.2833852","article-title":"Magnetic detection of steel corrosion at a buried position near the ground level using a magnetic resistance sensor","volume":"54","author":"Tsukada","year":"2018","journal-title":"IEEE Trans. Magn."},{"key":"B60","doi-asserted-by":"publisher","first-page":"91","DOI":"10.1016\/s0300-9440(98)00015-0","article-title":"Review of alternatives to chromate for corrosion protection of aluminum aerospace alloys","volume":"33","author":"Twite","year":"1998","journal-title":"Prog. Org. Coat."},{"key":"B61","doi-asserted-by":"publisher","first-page":"294","DOI":"10.1016\/j.porgcoat.2017.06.013","article-title":"Developments in smart anticorrosive coatings with multifunctional characteristics","volume":"111","author":"Ulaeto","year":"2017","journal-title":"Prog. Org. Coat."},{"key":"B62","doi-asserted-by":"publisher","first-page":"380","DOI":"10.1016\/j.pmatsci.2019.04.002","article-title":"Protective polymeric films for industrial substrates: A critical review on past and recent applications with conducting polymers and polymer composites\/nanocomposites","volume":"104","author":"Umoren","year":"2019","journal-title":"Prog. Mat. Sci."},{"key":"B63","doi-asserted-by":"publisher","first-page":"1700616","DOI":"10.1002\/mame.201700616","article-title":"Adaptive polymeric coatings with self-reporting and self-healing dual functions from porous core\u2013shell nanostructures","volume":"303","author":"Wang","year":"2018","journal-title":"Macromol. Mat. Eng."},{"key":"B64","doi-asserted-by":"publisher","first-page":"99","DOI":"10.1021\/j150415a013","article-title":"X-ray diffraction studies on heavy metal iron-cyanides","volume":"46","author":"Weiser","year":"1942","journal-title":"J. Phys. Chem."},{"key":"B65","doi-asserted-by":"publisher","first-page":"2512","DOI":"10.1021\/ic50093a027","article-title":"Prussian blues","volume":"9","author":"Wilde","year":"1970","journal-title":"Inorg. Chem."},{"key":"B66","doi-asserted-by":"publisher","first-page":"2063","DOI":"10.1002\/ejic.202000144","article-title":"Hexacyanoferrate-intercalated layered double hydroxides as nanoadditives for the detection of early-stage corrosion of steel: The revival of prussian blue","volume":"2020","author":"Wilhelm","year":"2020","journal-title":"Eur. J. Inorg. Chem."},{"key":"B67","doi-asserted-by":"publisher","first-page":"1804","DOI":"10.3390\/polym14091804","article-title":"On the application of Vickers micro hardness testing to isotactic polypropylene","volume":"14","author":"Wu","year":"2022","journal-title":"Polymers"},{"key":"B68","doi-asserted-by":"publisher","first-page":"151","DOI":"10.1016\/j.jmst.2021.11.004","article-title":"Electrochemical measurements used for assessment of corrosion and protection of metallic materials in the field: A critical review","volume":"112","author":"Xia","year":"2022","journal-title":"J. Mat. Sci. Technol."},{"key":"B69","doi-asserted-by":"publisher","first-page":"171","DOI":"10.1007\/s00128-015-1566-9","article-title":"Toxicity of 8-hydroxyquinoline in cryprinus carpio using the acute toxicity test, hepatase activity analysis and the comet assay","volume":"95","author":"Yan","year":"2015","journal-title":"Bull. Environ. Contam. Toxicol."},{"key":"B70","doi-asserted-by":"publisher","first-page":"138","DOI":"10.3390\/polym12010138","article-title":"A comprehensive review on water diffusion in polymers focusing on the polymer\u2013metal interface combination","volume":"12","author":"Yang","year":"2020","journal-title":"Polymers"},{"key":"B71","doi-asserted-by":"publisher","first-page":"2455","DOI":"10.1016\/j.polymer.2014.03.039","article-title":"Relaxation behavior of layered double hydroxides filled dangling chain-based polyurethane\/polymethyl methacrylate nanocomposites","volume":"55","author":"Yu","year":"2014","journal-title":"Polymer"},{"key":"B72","doi-asserted-by":"publisher","first-page":"139","DOI":"10.1016\/j.jmst.2022.04.032","article-title":"Graphene-like two-dimensional nanosheets-based anticorrosive coatings: A review","volume":"129","author":"Zhang","year":"2022","journal-title":"J. Mat. Sci. Technol."}],"container-title":["Frontiers in Chemical Engineering"],"original-title":[],"link":[{"URL":"https:\/\/www.frontiersin.org\/articles\/10.3389\/fceng.2023.1145049\/full","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,25]],"date-time":"2023-04-25T04:46:00Z","timestamp":1682397960000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.frontiersin.org\/articles\/10.3389\/fceng.2023.1145049\/full"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,4,25]]},"references-count":72,"alternative-id":["10.3389\/fceng.2023.1145049"],"URL":"https:\/\/doi.org\/10.3389\/fceng.2023.1145049","relation":{},"ISSN":["2673-2718"],"issn-type":[{"value":"2673-2718","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,4,25]]},"article-number":"1145049"}}