{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,13]],"date-time":"2026-04-13T13:07:09Z","timestamp":1776085629958,"version":"3.50.1"},"reference-count":154,"publisher":"Frontiers Media SA","license":[{"start":{"date-parts":[[2022,11,18]],"date-time":"2022-11-18T00:00:00Z","timestamp":1668729600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100018694","name":"HORIZON EUROPE Marie Sklodowska-Curie Actions","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100018694","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["frontiersin.org"],"crossmark-restriction":true},"short-container-title":["Front. Chem."],"abstract":"<jats:p>This work describes the main advances carried out in the field of corrosion protection using layered double hydroxides (LDH), both as additive\/pigment-based systems in organic coatings and as conversion films\/pre-treatments. In the context of the research topic \u201cCelebrating 20\u00a0years of CICECO\u201d, the main works reported herein are based on SECOP\u2019s group (CICECO) main advances over the years. More specifically, this review describes structure and properties of LDH, delving into the corrosion field with description of pioneering works, use of LDH as additives to organic coatings, conversion layers, application in reinforced concrete and corrosion detection, and environmental impact of these materials. Moreover, the use of computational tools for the design of LDH materials and understanding of ion-exchange reactions is also presented. The review ends with a critical analysis of the field and future perspectives on the use of LDH for corrosion protection. From the work carried out LDH seem very tenable, versatile, and advantageous for corrosion protection applications, although several obstacles will have to be overcome before their use become commonplace.<\/jats:p>","DOI":"10.3389\/fchem.2022.1048313","type":"journal-article","created":{"date-parts":[[2022,11,18]],"date-time":"2022-11-18T04:54:00Z","timestamp":1668747240000},"update-policy":"https:\/\/doi.org\/10.3389\/crossmark-policy","source":"Crossref","is-referenced-by-count":19,"title":["Layered double hydroxides for corrosion-related applications\u2014Main developments from 20\u00a0years of research at CICECO"],"prefix":"10.3389","volume":"10","author":[{"given":"Jo\u00e3o","family":"Tedim","sequence":"first","affiliation":[]},{"given":"Tiago L. P.","family":"Galv\u00e3o","sequence":"additional","affiliation":[]},{"given":"Kiryl A.","family":"Yasakau","sequence":"additional","affiliation":[]},{"given":"Alexandre","family":"Bastos","sequence":"additional","affiliation":[]},{"given":"Jos\u00e9 R. B.","family":"Gomes","sequence":"additional","affiliation":[]},{"given":"Mario G. S.","family":"Ferreira","sequence":"additional","affiliation":[]}],"member":"1965","published-online":{"date-parts":[[2022,11,18]]},"reference":[{"key":"B1","doi-asserted-by":"publisher","first-page":"35","DOI":"10.1016\/J.CORSCI.2018.02.018","article-title":"Synergetic active corrosion protection of AA2024-T3 by 2D- anionic and 3D-cationic nanocontainers loaded with Ce and mercaptobenzothiazole","volume":"135","author":"Abdolah Zadeh","year":"2018","journal-title":"Corros. Sci."},{"key":"B2","doi-asserted-by":"publisher","first-page":"7451","DOI":"10.1039\/c0jm01447h","article-title":"Hexagonal nanosheets from the exfoliation of Ni2+-Fe3+ LDHs: A route towards layered multifunctional materials","volume":"20","author":"Abell\u00e1n","year":"2010","journal-title":"J. Mat. Chem."},{"key":"B3","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1016\/j.softx.2015.06.001","article-title":"Gromacs: High performance molecular simulations through multi-level parallelism from laptops to supercomputers","author":"Abraham","year":"2015","journal-title":"SoftwareX"},{"key":"B4","doi-asserted-by":"publisher","first-page":"12","DOI":"10.1016\/J.POWTEC.2020.08.013","article-title":"Evolution of layered yttrium hydroxide nitrate particles during controlled double-jet precipitation","volume":"376","author":"Aleshin","year":"2020","journal-title":"Powder Technol."},{"key":"B154","doi-asserted-by":"publisher","first-page":"164","DOI":"10.1007\/s10126-017-9740-1","article-title":"Efficacy and ecotoxicity of novel anti-fouling nanomaterials in target and non-target marine species","volume":"19","author":"Avelelas","year":"","journal-title":"Mar. Biotechnol."},{"key":"B5","doi-asserted-by":"crossref","DOI":"10.1002\/9783527651696","volume-title":"Corrosion of steel in concrete: Prevention, diagnosis, repair","author":"Bertolini","year":"2013"},{"key":"B6","doi-asserted-by":"publisher","first-page":"144027","DOI":"10.1016\/J.APSUSC.2019.144027","article-title":"Zn-Al LDH growth on AA2024 and zinc and their intercalation with chloride: Comparison of crystal structure and kinetics","volume":"501","author":"Bouali","year":"","journal-title":"Appl. Surf. Sci."},{"key":"B7","doi-asserted-by":"publisher","first-page":"100857","DOI":"10.1016\/j.apmt.2020.100857","article-title":"Layered double hydroxides (LDHs) as functional materials for the corrosion protection of aluminum alloys: A review","volume":"21","author":"Bouali","year":"","journal-title":"Appl. Mat. Today"},{"key":"B8","doi-asserted-by":"publisher","first-page":"277","DOI":"10.1007\/S11998-004-0030-2","article-title":"Formation and characteristics of Al\u2212Zn hydrotalcite coatings on galvanized steel","volume":"1","author":"Buchheit","year":"2004","journal-title":"J. Coat. Technol. Res."},{"key":"B9","doi-asserted-by":"publisher","first-page":"205","DOI":"10.5006\/1.3293512","article-title":"Corrosion-resistant, chromate-free talc coatings for aluminum","volume":"50","author":"Buchheit","year":"1994","journal-title":"Corrosion"},{"key":"B10","doi-asserted-by":"publisher","first-page":"3","DOI":"10.5006\/1.3277303","article-title":"Active corrosion protection in Ce-modified hydrotalcite conversion coatings","volume":"58","author":"Buchheit","year":"2002","journal-title":"Corrosion"},{"key":"B11","doi-asserted-by":"publisher","first-page":"174","DOI":"10.1016\/J.PORGCOAT.2003.08.003","article-title":"Active corrosion protection and corrosion sensing in chromate-free organic coatings","volume":"47","author":"Buchheit","year":"2003","journal-title":"Prog. Org. Coat."},{"key":"B12","doi-asserted-by":"publisher","first-page":"232","DOI":"10.1016\/j.jmst.2021.05.078","article-title":"Layered double hydroxide (LDH) for multi-functionalized corrosion protection of metals: A review","volume":"102","author":"Cao","year":"2022","journal-title":"J. Mat. Sci. Technol."},{"key":"B13","doi-asserted-by":"publisher","first-page":"39916","DOI":"10.1039\/C5RA03741G","article-title":"Polyelectrolyte-modified layered double hydroxide nanocontainers as vehicles for combined inhibitors","volume":"5","author":"Carneiro","year":"2015","journal-title":"RSC Adv."},{"key":"B14","doi-asserted-by":"publisher","first-page":"148","DOI":"10.1016\/J.CORSCI.2012.05.022","article-title":"Study of the in situ growth mechanism of Mg\u2013Al hydrotalcite conversion film on AZ31 magnesium alloy","volume":"63","author":"Chen","year":"2012","journal-title":"Corros. Sci."},{"key":"B15","doi-asserted-by":"publisher","first-page":"36","DOI":"10.1016\/J.ICA.2017.08.007","article-title":"Facile preparation methods of hydrotalcite layered materials and their structural characterization by combined techniques","volume":"470","author":"Conterosito","year":"2018","journal-title":"Inorganica Chim. Acta"},{"key":"B16","doi-asserted-by":"publisher","first-page":"10681","DOI":"10.1021\/jp8016453","article-title":"Structural and energetic analysis of MgxM1\u2212x(OH)2 (M = Zn, Cu or Ca) brucite-like compounds by DFT calculations","volume":"112","author":"Costa","year":"2008","journal-title":"J. Phys. Chem. C"},{"key":"B17","doi-asserted-by":"publisher","first-page":"14133","DOI":"10.1021\/jp1033646","article-title":"Structural model proposition and thermodynamic and vibrational analysis of hydrotalcite-like compounds by DFT calculations","volume":"114","author":"Costa","year":"2010","journal-title":"J. Phys. Chem. C"},{"key":"B18","doi-asserted-by":"publisher","first-page":"16","DOI":"10.1016\/J.CLAY.2011.11.014","article-title":"Comparative Structural, thermodynamic and electronic analyses of ZnAlAn\u2212 hydrotalcite-like compounds (An\u2212=Cl\u2212, F\u2212, Br\u2212, OH\u2212, CO32\u2212 or NO3\u2212): An ab initio study","volume":"56","author":"Costa","year":"2012","journal-title":"Appl. Clay Sci."},{"key":"B19","doi-asserted-by":"publisher","first-page":"419","DOI":"10.1016\/J.IJADHADH.2005.07.001","article-title":"Strategies for the replacement of chromic acid anodising for the structural bonding of aluminium alloys","volume":"26","author":"Critchlow","year":"2006","journal-title":"Int. J. Adhes. Adhes."},{"key":"B20","doi-asserted-by":"publisher","first-page":"2470","DOI":"10.1039\/b819076c","article-title":"Molecular models and simulations of layered materials","volume":"19","author":"Cygan","year":"2009","journal-title":"J. Mat. Chem."},{"key":"B21","doi-asserted-by":"publisher","first-page":"1255","DOI":"10.1021\/jp0363287","article-title":"Molecular models of hydroxide, oxyhydroxide, and clay phases and the development of a general force field","volume":"108","author":"Cygan","year":"2004","journal-title":"J. Phys. Chem. B"},{"key":"B22","doi-asserted-by":"publisher","first-page":"48","DOI":"10.1038\/s41529-022-00259-9","article-title":"Cordata: An open data management web application to select corrosion inhibitors","volume":"6","author":"Galv\u00e3o","year":"2022","journal-title":"npj Mat. Degrad."},{"key":"B23","doi-asserted-by":"publisher","first-page":"78","DOI":"10.1007\/s00214-016-1839-3","article-title":"A computational UV\u2013Vis spectroscopic study of the chemical speciation of 2-mercaptobenzothiazole corrosion inhibitor in aqueous solution","volume":"135","author":"Galv\u00e3o","year":"","journal-title":"Theor. Chem. Acc."},{"key":"B24","doi-asserted-by":"publisher","first-page":"86","DOI":"10.1016\/j.jcis.2016.01.038","article-title":"Control of crystallite and particle size in the synthesis of layered double hydroxides: Macromolecular insights and a complementary modeling tool","volume":"468","author":"Galv\u00e3o","year":"","journal-title":"J. Colloid Interface Sci."},{"key":"B25","doi-asserted-by":"publisher","first-page":"2211","DOI":"10.1021\/acs.jpcc.6b10860","article-title":"How density functional theory surface energies may explain the morphology of particles, nanosheets, and conversion films based on layered double hydroxides","volume":"121","author":"Galv\u00e3o","year":"2017","journal-title":"J. Phys. Chem. C"},{"key":"B26","doi-asserted-by":"publisher","first-page":"526","DOI":"10.1016\/j.cej.2018.02.061","article-title":"Improving the functionality and performance of AA2024 corrosion sensing coatings with nanocontainers","volume":"341","author":"Galv\u00e3o","year":"2018","journal-title":"Chem. Eng. J."},{"key":"B27","doi-asserted-by":"publisher","first-page":"5624","DOI":"10.1021\/acs.jpcc.9b09538","article-title":"Elucidating structure-property relationships in aluminum alloy corrosion inhibitors by machine learning","volume":"124","author":"Galv\u00e3o","year":"","journal-title":"J. Phys. Chem. C"},{"key":"B28","doi-asserted-by":"publisher","first-page":"385","DOI":"10.1016\/B978-0-12-816770-0.00022-8","article-title":"Emerging trends in smart nanocontainers for corrosion applications","author":"Galv\u00e3o","year":"","journal-title":"Smart Nanocontainers"},{"key":"B29","doi-asserted-by":"publisher","first-page":"1769","DOI":"10.3390\/MA13071769","article-title":"Use of ZnAl-layered double hydroxide (LDH) to extend the service life of reinforced concrete","volume":"13","author":"Gomes","year":"2020","journal-title":"Mater. (Basel)"},{"key":"B30","doi-asserted-by":"publisher","first-page":"708","DOI":"10.1039\/B506932G","article-title":"On the application of computer simulation techniques to anionic and cationic clays: A materials chemistry perspective","volume":"16","author":"Greenwell","year":"2006","journal-title":"J. Mat. Chem."},{"key":"B31","doi-asserted-by":"publisher","first-page":"1455","DOI":"10.1016\/j.jmst.2018.03.003","article-title":"Layered double hydroxide coatings on magnesium alloys: A review","volume":"34","author":"Guo","year":"2018","journal-title":"J. Mat. Sci. Technol."},{"key":"B32","doi-asserted-by":"publisher","first-page":"9894","DOI":"10.1021\/la901012w","article-title":"One-step hydrothermal crystallization of a layered double hydroxide\/alumina bilayer film on aluminum and its corrosion resistance properties","volume":"25","author":"Guo","year":"2009","journal-title":"Langmuir"},{"key":"B33","doi-asserted-by":"publisher","first-page":"5197","DOI":"10.1039\/c0cc00313a","article-title":"Layered double hydroxide films: Synthesis, properties and applications","volume":"46","author":"Guo","year":"2010","journal-title":"Chem. Commun."},{"key":"B34","doi-asserted-by":"publisher","first-page":"530","DOI":"10.1016\/J.ENVPOL.2019.05.031","article-title":"Toxicity of engineered micro- and nanomaterials with antifouling properties to the brine shrimp Artemia salina and embryonic stages of the sea urchin Paracentrotus lividus","volume":"251","author":"Gutner-Hoch","year":"2019","journal-title":"Environ. Pollut."},{"key":"B35","doi-asserted-by":"publisher","first-page":"6","DOI":"10.3390\/jmse6010006","article-title":"Antimacrofouling efficacy of innovative inorganic nanomaterials loaded with booster biocides","volume":"6","author":"Gutner-Hoch","year":"2018","journal-title":"J. Mar. Sci. Eng."},{"key":"B36","doi-asserted-by":"publisher","first-page":"5188","DOI":"10.1039\/b807479h","article-title":"Heterogeneous ultrathin films fabricated by alternate assembly of exfoliated layered double hydroxides and polyanion","volume":"41","author":"Han","year":"2008","journal-title":"Chem. Commun."},{"key":"B37","doi-asserted-by":"publisher","first-page":"136796","DOI":"10.1016\/J.ELECTACTA.2020.136796","article-title":"Electrodeposited Zn-Al layered double hydroxide films for corrosion protection of aluminum alloys","volume":"355","author":"He","year":"2020","journal-title":"Electrochim. Acta"},{"key":"B38","doi-asserted-by":"publisher","first-page":"123","DOI":"10.1016\/J.CLAY.2009.04.013","article-title":"Synthesis of crystalline layered double hydroxides: Precipitation by using urea hydrolysis and subsequent hydrothermal reactions in aqueous solutions","volume":"45","author":"Hibino","year":"2009","journal-title":"Appl. Clay Sci."},{"key":"B39","doi-asserted-by":"publisher","first-page":"C461","DOI":"10.1149\/2.0091809jes","article-title":"Effect of NO3\u2212 intercalation on corrosion resistance of conversion coated Zn-Al-CO3 LDHs on electrogalvanized steel","volume":"165","author":"Hoshino","year":"2018","journal-title":"J. Electrochem. Soc."},{"key":"B40","doi-asserted-by":"publisher","first-page":"1487","DOI":"10.1039\/JM9940401487","article-title":"Electrogeneration of base by cathodic reduction of anions: Novel one-step route to unary and layered double hydroxides (LDHs)","volume":"4","author":"Indira","year":"1994","journal-title":"J. Mat. Chem."},{"key":"B41","unstructured":"Innovation - Kisuma chemicals"},{"key":"B42","doi-asserted-by":"publisher","first-page":"8968","DOI":"10.1039\/C3TA11015J","article-title":"Corrosion resistance of Mg\u2013Al layered double hydroxide container-containing magnesium hydroxide films formed directly on magnesium alloy by chemical-free steam coating","volume":"1","author":"Ishizaki","year":"2013","journal-title":"J. Mat. Chem. A Mat."},{"key":"B43","doi-asserted-by":"publisher","first-page":"17574","DOI":"10.1039\/D0CP01765E","article-title":"In situ kinetics studies of Zn\u2013Al LDH intercalation with corrosion related species","volume":"22","author":"Iuzviuk","year":"2020","journal-title":"Phys. Chem. Chem. Phys."},{"key":"B44","volume-title":"Principles and prevention of corrosion","author":"Jones","year":"2014"},{"key":"B45","doi-asserted-by":"publisher","first-page":"100656","DOI":"10.1016\/J.NANOSO.2020.100656","article-title":"Kinetic and equilibrium analyses of lactate adsorption by Cu-Al and Mg-Al layered double hydroxides (Cu-Al LDH and Mg-Al LDH) and Cu-Al and Mg-Al layered double oxides (Cu-Al LDO and Mg-Al LDO)","volume":"25","author":"Kameda","year":"2021","journal-title":"Nano-Structures Nano-Objects"},{"key":"B46","doi-asserted-by":"publisher","first-page":"172","DOI":"10.1016\/J.SURFCOAT.2015.11.051","article-title":"Effect of treatment time in the Mg(OH)2\/Mg\u2013Al LDH composite film formed on Mg alloy AZ31 by steam coating on the corrosion resistance","volume":"286","author":"Kamiyama","year":"2016","journal-title":"Surf. Coat. Technol."},{"key":"B47","doi-asserted-by":"publisher","first-page":"214713","DOI":"10.1063\/1.1902945","article-title":"Atomistic simulation of nanoporous layered double hydroxide materials and their properties. I. Structural modeling","volume":"122","author":"Kim","year":"2005","journal-title":"J. Chem. Phys."},{"key":"B48","doi-asserted-by":"publisher","first-page":"224701","DOI":"10.1063\/1.2799985","article-title":"Atomistic simulation of nanoporous layered double hydroxide materials and their properties. II. Adsorption and diffusion","volume":"127","author":"Kim","year":"2007","journal-title":"J. Chem. Phys."},{"key":"B49","doi-asserted-by":"publisher","first-page":"309","DOI":"10.1080\/10408436.2021.1886046","article-title":"A critical review on the production and application of graphene and graphene-based materials in anti-corrosion coatings","volume":"47","author":"Kulyk","year":"2022","journal-title":"Crit. Rev. Solid State Mater. Sci."},{"key":"B50","doi-asserted-by":"publisher","first-page":"13942","DOI":"10.1039\/C5RA27286F","article-title":"Sealing of tartaric sulfuric (TSA) anodized AA2024 with nanostructured LDH layers","volume":"6","author":"Kuznetsov","year":"2016","journal-title":"RSC Adv."},{"key":"B51","doi-asserted-by":"publisher","first-page":"1207","DOI":"10.1111\/jam.13433","article-title":"Antimicrobial activity of 2-mercaptobenzothiazole released from environmentally friendly nanostructured layered double hydroxides","volume":"122","author":"Kuznetsova","year":"2017","journal-title":"J. Appl. Microbiol."},{"key":"B52","doi-asserted-by":"publisher","first-page":"106537","DOI":"10.1016\/j.clay.2022.106537","article-title":"Layered materials as nanocontainers for active corrosion protection: A brief review","volume":"225","author":"Leal","year":"2022","journal-title":"Appl. Clay Sci."},{"key":"B53","doi-asserted-by":"publisher","first-page":"884","DOI":"10.1021\/cg5016737","article-title":"Kinetic analysis of secondary crystal growth for hydrotalcite film formation","volume":"15","author":"Lee","year":"2015","journal-title":"Cryst. Growth Des."},{"key":"B54","doi-asserted-by":"publisher","first-page":"322","DOI":"10.5006\/1.3287681","article-title":"Performance of hydrotalcite conversion treatments on AA2024-T3 when used in a coating system","volume":"58","author":"Leggat","year":"2002","journal-title":"Corrosion"},{"key":"B55","doi-asserted-by":"publisher","first-page":"17934","DOI":"10.1021\/IE403299U","article-title":"Oriented CuZnAl ternary layered double hydroxide films: In situ hydrothermal growth and anticorrosion properties","volume":"52","author":"Lei","year":"2013","journal-title":"Ind. Eng. Chem. Res."},{"key":"B56","doi-asserted-by":"publisher","first-page":"237","DOI":"10.1021\/BK-1996-0622.CH016","article-title":"Chimie douce synthesis of nanostructured layered materials","volume":"622","author":"Levin","year":"1996","journal-title":"ACS Symp. Ser. Am. Chem. Soc."},{"key":"B57","first-page":"08214","article-title":"Review of pH and electrochemical responsive materials for corrosion control applications","author":"Li","year":"2008"},{"key":"B58","doi-asserted-by":"publisher","first-page":"18","DOI":"10.1016\/J.COLCOM.2018.03.003","article-title":"Controlled release of nitrate and molybdate intercalated in Zn-Al-layered double hydroxide nanocontainers towards marine anticorrosion applications","volume":"24","author":"Li","year":"2018","journal-title":"Colloid Interface Sci. Commun."},{"key":"B59","doi-asserted-by":"publisher","first-page":"12412","DOI":"10.1021\/ACSOMEGA.2C01115","article-title":"Atomistic insight into the hydration states of layered double hydroxides","volume":"7","author":"Li","year":"2022","journal-title":"ACS Omega"},{"key":"B60","doi-asserted-by":"publisher","first-page":"4872","DOI":"10.1021\/ja0584471","article-title":"Synthesis, anion exchange, and delamination of Co-Al layered double hydroxide: Assembly of the exfoliated nanosheet\/polyanion composite films and magneto-optical studies","volume":"128","author":"Liu","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"B61","doi-asserted-by":"publisher","first-page":"C45","DOI":"10.1149\/2.0021603jes","article-title":"Protective film formation on AA2024-T3 aluminum alloy by leaching of lithium carbonate from an organic coating","volume":"163","author":"Liu","year":"2016","journal-title":"J. Electrochem. Soc."},{"key":"B62","doi-asserted-by":"publisher","first-page":"5026","DOI":"10.1002\/ejic.200500666","article-title":"A novel integrated X-ray powder diffraction (XRPD) and molecular dynamics (MD) approach for modelling mixed-metal (Zn, Al) layered double hydroxides (LDHs)","volume":"2005","author":"Lombardo","year":"2005","journal-title":"Eur. J. Inorg. Chem."},{"key":"B63","doi-asserted-by":"publisher","first-page":"415","DOI":"10.1016\/j.chemosphere.2016.03.015","article-title":"High performance NiFe layered double hydroxide for methyl orange dye and Cr(VI) adsorption","volume":"152","author":"Lu","year":"2016","journal-title":"Chemosphere"},{"key":"B64","doi-asserted-by":"publisher","first-page":"108","DOI":"10.1016\/j.colsurfa.2012.03.032","article-title":"Molecular simulation studies for intercalation of photoactive dyes into layered double hydroxide","volume":"402","author":"Lv","year":"2012","journal-title":"Colloids Surfaces A Physicochem. Eng. Aspects"},{"key":"B65","doi-asserted-by":"publisher","first-page":"3809","DOI":"10.1039\/b605422f","article-title":"Exfoliating layered double hydroxides in formamide: A method to obtain positively charged nanosheets","volume":"16","author":"Ma","year":"2006","journal-title":"J. Mat. Chem."},{"key":"B66","doi-asserted-by":"publisher","first-page":"15112","DOI":"10.1021\/acs.jpcc.5b01754","article-title":"Multiphase Monte Carlo and molecular dynamics simulations of water and CO2 intercalation in montmorillonite and beidellite","volume":"119","author":"Makaremi","year":"2015","journal-title":"J. Phys. Chem. C"},{"key":"B67","doi-asserted-by":"publisher","first-page":"1106","DOI":"10.3390\/COATINGS10111106","article-title":"A review on anodizing of aerospace aluminum alloys for corrosion protection","volume":"10","author":"Mart\u00ednez-Viademonte","year":"2020","journal-title":"Coatings"},{"key":"B68","doi-asserted-by":"publisher","first-page":"1064","DOI":"10.1039\/C6EN00630B","article-title":"Effects of a novel anticorrosion engineered nanomaterial on the bivalve Ruditapes philippinarum","volume":"4","author":"Martins","year":"","journal-title":"Environ. Sci. Nano"},{"key":"B69","doi-asserted-by":"publisher","first-page":"219","DOI":"10.5006\/1.3287724","article-title":"Inhibition of filiform corrosion on organic-coated aluminum alloy by hydrotalcite-like anion-exchange pigments","volume":"60","author":"McMurray","year":"2004","journal-title":"Corrosion"},{"key":"B70","doi-asserted-by":"publisher","first-page":"6878","DOI":"10.1039\/C9CC02571E","article-title":"One-step synthesis and growth mechanism of nitrate intercalated ZnAl LDH conversion coatings on zinc","volume":"55","author":"Mikhailau","year":"2019","journal-title":"Chem. Commun."},{"key":"B71","doi-asserted-by":"publisher","first-page":"1426","DOI":"10.3390\/ma13061426","article-title":"Recent advances on the application of layered double hydroxides in concrete\u2014a review","volume":"13","author":"Mir","year":"2020","journal-title":"Materials"},{"key":"B72","doi-asserted-by":"publisher","first-page":"78","DOI":"10.3390\/CMD2010005","article-title":"The stability and chloride entrapping capacity of ZnAl-NO2 LDH in high-alkaline\/cementitious environment","volume":"2","author":"Mir","year":"2021","journal-title":"Corros. Mater. Degrad."},{"key":"B73","doi-asserted-by":"publisher","first-page":"126882","DOI":"10.1016\/J.SURFCOAT.2021.126882","article-title":"Zn-Al layered double hydroxide as an inhibitive conversion coating developed on AA2024-T3 by one-step hydrothermal crystallization: Crystal structure evolution and corrosion protection performance","volume":"409","author":"Mohammadi","year":"2021","journal-title":"Surf. Coat. Technol."},{"key":"B74","doi-asserted-by":"publisher","first-page":"36","DOI":"10.1016\/J.MATDES.2017.01.097","article-title":"Active protective PEO coatings on AA2024: Role of voltage on in-situ LDH growth","volume":"120","author":"Mohedano","year":"2017","journal-title":"Mat. Des."},{"key":"B75","doi-asserted-by":"publisher","first-page":"1272","DOI":"10.1107\/S0021889811038970","article-title":"VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data","volume":"44","author":"Momma","year":"2011","journal-title":"J. Appl. Crystallogr."},{"key":"B76","doi-asserted-by":"publisher","first-page":"31","DOI":"10.1016\/j.electacta.2011.10.078","article-title":"Evaluation of self-healing ability in protective coatings modified with combinations of layered double hydroxides and cerium molibdate nanocontainers filled with corrosion inhibitors","volume":"60","author":"Montemor","year":"2012","journal-title":"Electrochim. Acta"},{"key":"B77","doi-asserted-by":"publisher","first-page":"328","DOI":"10.3390\/coatings9050328","article-title":"Layered double hydroxide clusters as precursors of novel multifunctional layers: A bottom-up approach","volume":"9","author":"Neves","year":"2019","journal-title":"Coatings"},{"key":"B78","doi-asserted-by":"publisher","first-page":"105842","DOI":"10.1016\/j.clay.2020.105842","article-title":"Unveiling the local structure of 2-mercaptobenzothiazole intercalated in (Zn2Al) layered double hydroxides","volume":"198","author":"Novell-Leruth","year":"2020","journal-title":"Appl. Clay Sci."},{"key":"B79","doi-asserted-by":"publisher","first-page":"497","DOI":"10.3133\/TM6A43","article-title":"Description of input and examples for PHREEQC version 3: A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations","volume":"6","author":"Parkhurst","year":"2013","journal-title":"Tech. Methods"},{"key":"B80","doi-asserted-by":"publisher","first-page":"164","DOI":"10.1016\/J.CLAY.2018.06.037","article-title":"A molecular dynamics framework to explore the structure and dynamics of layered double hydroxides","volume":"163","author":"P\u00e9rez-S\u00e1nchez","year":"2018","journal-title":"Appl. Clay Sci."},{"key":"B81","doi-asserted-by":"publisher","first-page":"7856","DOI":"10.1021\/JP800574D","article-title":"Molecular modeling of the structure and dynamics of the interlayer species of ZnAlCl layered double hydroxide","volume":"112","author":"Pisson","year":"2008","journal-title":"J. Phys. Chem. B"},{"key":"B82","doi-asserted-by":"publisher","first-page":"2353","DOI":"10.1021\/am900495r","article-title":"Novel inorganic host layered double hydroxides intercalated with guest organic inhibitors for anticorrosion applications","volume":"1","author":"Poznyak","year":"2009","journal-title":"ACS Appl. Mat. Interfaces"},{"key":"B83","doi-asserted-by":"publisher","first-page":"11498","DOI":"10.1038\/s41598-019-48012-8","article-title":"Emerging switchable ultraviolet photoluminescence in dehydrated Zn\/Al layered double hydroxide nanoplatelets","volume":"9","author":"Prestopino","year":"2019","journal-title":"Sci. Rep."},{"key":"B84","doi-asserted-by":"publisher","first-page":"229","DOI":"10.1016\/S1387-1811(00)00197-9","article-title":"Synthesis and characterization of sol\u2013gel Mg\/Al and Ni\/Al layered double hydroxides and comparison with co-precipitated samples","volume":"39","author":"Prinetto","year":"2000","journal-title":"Microporous Mesoporous Mater."},{"key":"B85","doi-asserted-by":"publisher","first-page":"105560","DOI":"10.1016\/J.CLAY.2020.105560","article-title":"Structural arrangement and properties of layered double hydroxide drug nanocarrier intercalated by sulindac and mefenamic acid solved by molecular simulation methods","volume":"189","author":"P\u0161eni\u010dka","year":"2020","journal-title":"Appl. Clay Sci."},{"key":"B86","doi-asserted-by":"publisher","first-page":"80","DOI":"10.3390\/NANO9010080","article-title":"Applications of mechanochemically prepared layered double hydroxides as adsorbents and catalysts: A mini-review","volume":"9","author":"Qu","year":"2019","journal-title":"Nanomaterials"},{"key":"B87","doi-asserted-by":"publisher","first-page":"11193","DOI":"10.1039\/C5RA19209A","article-title":"Molecular design confirmation for proposition of improved photophysical properties in a dye-intercalated layered double hydroxides","volume":"6","author":"Rad","year":"2016","journal-title":"RSC Adv."},{"key":"B88","doi-asserted-by":"publisher","first-page":"1717","DOI":"10.1016\/J.CEMCONRES.2004.05.012","article-title":"Layered double hydroxide-like materials: Nanocomposites for use in concrete","volume":"34","author":"Raki","year":"2004","journal-title":"Cem. Concr. Res."},{"key":"B89","doi-asserted-by":"crossref","DOI":"10.1002\/9780470277270","volume-title":"Corrosion and corrosion control: An introduction to corrosion science and engineering","author":"Revie","year":"2008"},{"key":"B90","doi-asserted-by":"publisher","first-page":"4845","DOI":"10.1021\/acs.jcim.0c00493","article-title":"A genetic algorithmic approach to determine the structure of Li-Al layered double hydroxides","volume":"60","author":"Roberts","year":"2020","journal-title":"J. Chem. Inf. Model."},{"key":"B91","doi-asserted-by":"publisher","first-page":"14287","DOI":"10.1039\/c4cp01373e","article-title":"A DFT study on carbon monoxide adsorption onto hydroxylated \u03b1-Al2O3(0001) surfaces","volume":"16","author":"Rohmann","year":"2014","journal-title":"Phys. Chem. Chem. Phys."},{"key":"B92","doi-asserted-by":"publisher","first-page":"102","DOI":"10.1016\/J.CHEMPHYS.2012.01.026","article-title":"Comparative X-ray diffraction and infrared spectroscopy study of Zn\u2013Al layered double hydroxides: Vanadate vs nitrate","volume":"397","author":"Salak","year":"2012","journal-title":"Chem. Phys."},{"key":"B93","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1016\/J.CPLETT.2010.06.041","article-title":"Anion exchange in Zn\u2013Al layered double hydroxides: In situ X-ray diffraction study","volume":"495","author":"Salak","year":"2010","journal-title":"Chem. Phys. Lett."},{"key":"B94","doi-asserted-by":"publisher","first-page":"186","DOI":"10.1016\/j.jconrel.2016.01.016","article-title":"Layered double hydroxides as effective carrier for anticancer drugs and tailoring of release rate through interlayer anions","volume":"224","author":"Senapati","year":"2016","journal-title":"J. Control. Release"},{"key":"B95","doi-asserted-by":"publisher","first-page":"190","DOI":"10.3390\/coatings7110190","article-title":"Role of phase composition of PEO coatings on AA2024 for in-situ LDH growth","volume":"7","author":"Serdechnova","year":"2017","journal-title":"Coatings"},{"key":"B96","doi-asserted-by":"publisher","first-page":"158","DOI":"10.1016\/j.jssc.2015.10.023","article-title":"Interlayer intercalation and arrangement of 2-mercaptobenzothiazolate and 1, 2, 3-benzotriazolate anions in layered double hydroxides: In situ X-ray diffraction study","volume":"233","author":"Serdechnova","year":"2016","journal-title":"J. Solid State Chem."},{"key":"B97","doi-asserted-by":"publisher","first-page":"1672","DOI":"10.1002\/adma.200502053","article-title":"Layer-by-Layer assembled nanocontainers for self-healing corrosion protection","volume":"18","author":"Shchukin","year":"2006","journal-title":"Adv. Mat."},{"key":"B98","doi-asserted-by":"publisher","first-page":"16409","DOI":"10.1038\/s41598-018-34751-7","article-title":"Chelating agent-assisted in situ LDH growth on the surface of magnesium alloy","volume":"8","author":"Shulha","year":"2018","journal-title":"Sci. Rep."},{"key":"B99","unstructured":"Smallmatek \u2013 small materials and Technologies"},{"key":"B100","doi-asserted-by":"publisher","first-page":"10419","DOI":"10.1038\/s41598-019-46910-5","article-title":"Sonication accelerated formation of Mg-Al-phosphate layered double hydroxide via sol-gel prepared mixed metal oxides","volume":"9","author":"Sokol","year":"2019","journal-title":"Sci. Rep."},{"key":"B101","doi-asserted-by":"publisher","first-page":"4477","DOI":"10.1038\/ncomms5477","article-title":"Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis","volume":"5","author":"Song","year":"2014","journal-title":"Nat. Commun."},{"key":"B102","article-title":"Development of nanoadditives for detection of early-stage corrosion of carbon steel","author":"Sushkova","year":""},{"key":"B103","doi-asserted-by":"publisher","first-page":"390","DOI":"10.1016\/j.jmrt.2020.12.025","article-title":"Reviewing the current status of layered double hydroxide-based smart nanocontainers for corrosion inhibiting applications","volume":"10","author":"Tabish","year":"2021","journal-title":"J. Mater. Res. Technol."},{"key":"B104","doi-asserted-by":"crossref","first-page":"863","DOI":"10.1016\/B978-1-4377-3455-3.00028-6","article-title":"Corrosion prevention and control of chemical processing equipment","volume-title":"Handbook of environmental degradation of materials","author":"Tait","year":"2012"},{"key":"B105","doi-asserted-by":"publisher","first-page":"289","DOI":"10.1016\/J.JASCER.2014.06.002","article-title":"Soft-chemical synthesis and catalytic activity of Ni-Al and Co-Al layered double hydroxides (LDHs) intercalated with anions with different charge density","volume":"2","author":"Takei","year":"2014","journal-title":"J. Asian Ceram. Soc."},{"key":"B106","doi-asserted-by":"publisher","first-page":"123","DOI":"10.1016\/S0958-9465(01)00059-2","article-title":"Repair materials system for chloride-induced corrosion of reinforcing bars","volume":"25","author":"Tatematsu","year":"2003","journal-title":"Cem. Concr. Compos."},{"key":"B107","doi-asserted-by":"publisher","first-page":"145743","DOI":"10.1016\/J.APSUSC.2020.145743","article-title":"Computational exploration of the anion exchange on the basal surface of layered double hydroxides by molecular dynamics","volume":"513","author":"Tavares","year":"","journal-title":"Appl. Surf. Sci."},{"key":"B108","doi-asserted-by":"publisher","first-page":"147159","DOI":"10.1016\/J.APSUSC.2020.147159","article-title":"Computational investigation of two-dimensional LDHs and the modification of their electronic structure induced by defects","volume":"532","author":"Tavares","year":"","journal-title":"Appl. Surf. Sci."},{"key":"B109","doi-asserted-by":"publisher","first-page":"149450","DOI":"10.1016\/J.APSUSC.2021.149450","article-title":"DFT and force-field based MD simulations of formamide intercalation in LDH and its exfoliated form","volume":"552","author":"Tavares","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"B110","doi-asserted-by":"publisher","first-page":"1528","DOI":"10.1021\/am100174t","article-title":"Enhancement of active corrosion protection via combination of inhibitor-loaded nanocontainers","volume":"2","author":"Tedim","year":"2010","journal-title":"ACS Appl. Mat. Interfaces"},{"key":"B111","doi-asserted-by":"publisher","first-page":"15464","DOI":"10.1039\/c1jm12463c","article-title":"Nanostructured LDH-container layer with active protection functionality","volume":"21","author":"Tedim","year":"2011","journal-title":"J. Mat. Chem."},{"key":"B112","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.corsci.2011.10.003","article-title":"Zn\u2013Al layered double hydroxides as chloride nanotraps in active protective coatings","volume":"55","author":"Tedim","year":"2012","journal-title":"Corros. Sci."},{"key":"B113","doi-asserted-by":"publisher","first-page":"C4","DOI":"10.1149\/2.005401eel","article-title":"Effect of surface treatment on the performance of LDH conversion films","volume":"3","author":"Tedim","year":"2013","journal-title":"ECS Electrochem. Lett."},{"key":"B114","doi-asserted-by":"publisher","first-page":"164","DOI":"10.1016\/j.electacta.2013.11.111","article-title":"Influence of preparation conditions of Layered Double Hydroxide conversion films on corrosion protection","volume":"117","author":"Tedim","year":"2014","journal-title":"Electrochim. Acta"},{"key":"B115","doi-asserted-by":"publisher","first-page":"215","DOI":"10.1016\/j.electacta.2016.05.134","article-title":"Corrosion protection of AA2024-T3 by LDH conversion films. Analysis of SVET results","volume":"210","author":"Tedim","year":"2016","journal-title":"Electrochim. Acta"},{"key":"B116","doi-asserted-by":"publisher","first-page":"1123","DOI":"10.1007\/s10973-011-1369-0","article-title":"Sulfate intercalated layered double hydroxides prepared by the reformation effect","volume":"107","author":"Theiss","year":"2012","journal-title":"J. Therm. Anal. Calorim."},{"key":"B117","doi-asserted-by":"publisher","first-page":"127","DOI":"10.1007\/BF02708774","article-title":"Line broadening in the PXRD patterns of layered hydroxides: The relative effects of crystallite size and structural disorder","volume":"118","author":"Thomas","year":"2006","journal-title":"J. Chem. Sci. (Bangalore)."},{"key":"B118","doi-asserted-by":"publisher","first-page":"12485","DOI":"10.1021\/ja8037068","article-title":"Role of host layer flexibility in DNA guest intercalation revealed by computer simulation of layered nanomaterials","volume":"130","author":"Thyveetil","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"B119","doi-asserted-by":"publisher","first-page":"65","DOI":"10.1007\/430_2015_205","article-title":"Applications of layered double hydroxide materials: Recent advances and perspective","volume":"172","author":"Tian","year":"2016","journal-title":"Struct. Bond"},{"key":"B120","doi-asserted-by":"publisher","first-page":"1044","DOI":"10.1016\/J.JPCS.2007.10.063","article-title":"Molecular dynamic simulations of interactions between LDH and NO3\u2212 intercalates in aqueous solution","volume":"69","author":"Tran","year":"2008","journal-title":"J. Phys. Chem. Solids"},{"key":"B121","doi-asserted-by":"publisher","first-page":"12291","DOI":"10.1021\/JP026339K","article-title":"First principles study of the structure and chemistry of Mg-based hydrotalcite-like anionic clays","volume":"106","author":"Trave","year":"2002","journal-title":"J. Phys. Chem. B"},{"key":"B122","doi-asserted-by":"publisher","first-page":"19986","DOI":"10.1038\/srep19986","article-title":"Energy and structure of bonds in the interaction of organic anions with layered double hydroxide nanosheets: A molecular dynamics study","volume":"6","author":"Tsukanov","year":"2016","journal-title":"Sci. Rep."},{"key":"B123","doi-asserted-by":"publisher","first-page":"91","DOI":"10.1016\/S0300-9440(98)00015-0","article-title":"Review of alternatives to chromate for corrosion protection of aluminum aerospace alloys","volume":"33","author":"Twite","year":"1998","journal-title":"Prog. Org. Coat."},{"key":"B124","doi-asserted-by":"publisher","first-page":"158","DOI":"10.1016\/J.SURFCOAT.2019.07.028","article-title":"Cast iron corrosion protection with chemically modified MgAl layered double hydroxides synthesized using a novel approach","volume":"375","author":"Vieira","year":"2019","journal-title":"Surf. Coat. Technol."},{"key":"B125","doi-asserted-by":"publisher","first-page":"151527","DOI":"10.1016\/J.APSUSC.2021.151527","article-title":"Ce-substituted Mg-Al layered double hydroxides to prolong the corrosion protection lifetime of aluminium alloys","volume":"573","author":"Vieira","year":"2022","journal-title":"Appl. Surf. Sci."},{"key":"B126","doi-asserted-by":"publisher","first-page":"80","DOI":"10.1016\/J.PORGCOAT.2016.04.028","article-title":"Study of the formation of a protective layer in a defect from lithium-leaching organic coatings","volume":"99","author":"Visser","year":"2016","journal-title":"Prog. Org. Coat."},{"key":"B127","doi-asserted-by":"publisher","first-page":"271","DOI":"10.1016\/J.JALLCOM.2010.01.007","article-title":"Hydrotalcite conversion coating on Mg alloy and its corrosion resistance","volume":"494","author":"Wang","year":"2010","journal-title":"J. Alloys Compd."},{"key":"B128","doi-asserted-by":"publisher","first-page":"4124","DOI":"10.1021\/cr200434v","article-title":"Recent advances in the synthesis and application of layered double hydroxide (LDH) nanosheets","volume":"112","author":"Wang","year":"2012","journal-title":"Chem. Rev."},{"key":"B129","doi-asserted-by":"publisher","first-page":"794","DOI":"10.1038\/35057232","article-title":"Autonomic healing of polymer composites","volume":"409","author":"White","year":"2001","journal-title":"Nature"},{"key":"B130","doi-asserted-by":"publisher","first-page":"2063","DOI":"10.1002\/EJIC.202000144","article-title":"Hexacyanoferrate-intercalated layered double hydroxides as nanoadditives for the detection of early-stage corrosion of steel: The revival of prussian blue","volume":"2020","author":"Wilhelm","year":"2020","journal-title":"Eur. J. Inorg. Chem."},{"key":"B131","doi-asserted-by":"publisher","first-page":"B13","DOI":"10.1149\/1.1691529","article-title":"Inhibition of filiform corrosion on polymer coated AA2024-T3 by hydrotalcite-like pigments incorporating organic anions","volume":"7","author":"Williams","year":"2004","journal-title":"Electrochem. Solid-State Lett."},{"key":"B132","doi-asserted-by":"publisher","first-page":"834","DOI":"10.1016\/J.APSUSC.2014.06.083","article-title":"Electrochemical deposition and characterization of Zn-Al layered double hydroxides (LDHs) films on magnesium alloy","volume":"313","author":"Wu","year":"2014","journal-title":"Appl. Surf. Sci."},{"key":"B133","doi-asserted-by":"publisher","first-page":"426","DOI":"10.3390\/MA10040426","article-title":"In situ formation of decavanadate-intercalated layered double hydroxide films on AA2024 and their anti-corrosive properties when combined with hybrid sol gel films","volume":"10","author":"Wu","year":"2017","journal-title":"Materials"},{"key":"B134","doi-asserted-by":"publisher","first-page":"19665","DOI":"10.1007\/s11356-019-05161-7","article-title":"Formation of high crystalline LDH sludge for removing Cu and Zn from wastewater by controlled double-jet precipitation","volume":"26","author":"Wu","year":"2019","journal-title":"Environ. Sci. Pollut. Res."},{"key":"B135","doi-asserted-by":"publisher","first-page":"131627","DOI":"10.1016\/J.JCLEPRO.2022.131627","article-title":"Deciphering the CO2 emissions and emission intensity of cement sector in China through decomposition analysis","volume":"352","author":"Wu","year":"2022","journal-title":"J. Clean. Prod."},{"key":"B136","doi-asserted-by":"publisher","first-page":"122","DOI":"10.1016\/J.THEOCHEM.2009.08.033","article-title":"First principles study of microscopic structures and layer-anion interactions in layered double hydroxides intercalated various univalent anions","volume":"915","author":"Xu","year":"2009","journal-title":"J. Mol. Struct. THEOCHEM"},{"key":"B137","doi-asserted-by":"publisher","first-page":"1743","DOI":"10.1021\/JP0029257","article-title":"Abrupt structural transformation in hydrotalcite-like compounds Mg1-xAlx(OH)2(NO3)x\u00b7nH2O as a continuous function of nitrate anions","volume":"105","author":"Xu","year":"2001","journal-title":"J. Phys. Chem. B"},{"key":"B138","doi-asserted-by":"publisher","first-page":"34","DOI":"10.1016\/J.THEOCHEM.2008.06.031","article-title":"Theoretical study of the hexahydrated metal cations for the understanding of their template effects in the construction of layered double hydroxides","volume":"866","author":"Yan","year":"2008","journal-title":"J. Mol. Struct. THEOCHEM"},{"key":"B139","doi-asserted-by":"publisher","first-page":"1066","DOI":"10.1002\/maco.201206915","article-title":"Modified hydrotalcites as a new emerging class of smart additive of reinforced concrete for anticorrosion applications: A literature review","volume":"64","author":"Yang","year":"2013","journal-title":"Mater. Corros."},{"key":"B140","doi-asserted-by":"publisher","first-page":"124991","DOI":"10.1016\/j.conbuildmat.2021.124991","article-title":"Application of layered double hydroxides (LDHs) in corrosion resistance of reinforced concrete-state of the art","volume":"307","author":"Yang","year":"2021","journal-title":"Constr. Build. Mat."},{"key":"B141","doi-asserted-by":"publisher","first-page":"299","DOI":"10.1016\/J.CORSCI.2018.08.039","article-title":"A novel bilayer system comprising LDH conversion layer and sol-gel coating for active corrosion protection of AA2024","volume":"143","author":"Yasakau","year":"2018","journal-title":"Corros. Sci."},{"key":"B142","doi-asserted-by":"publisher","first-page":"411","DOI":"10.3390\/NANO8060411","article-title":"In-situ growth of NiAl-layered double hydroxide on AZ31 Mg alloy towards enhanced corrosion protection","volume":"8","author":"Ye","year":"2018","journal-title":"Nanomaterials"},{"key":"B143","doi-asserted-by":"publisher","first-page":"362","DOI":"10.1016\/J.CEJ.2008.03.016","article-title":"Fabrication of oriented layered double hydroxide films by spin coating and their use in corrosion protection","volume":"141","author":"Zhang","year":"2008","journal-title":"Chem. Eng. J."},{"key":"B144","doi-asserted-by":"publisher","first-page":"3498","DOI":"10.1016\/S1003-6326(15)63987-5","article-title":"Corrosion of in-situ grown MgAl-LDH coating on aluminum alloy","volume":"25","author":"Zhang","year":"2015","journal-title":"Trans. Nonferrous Metals Soc. China"},{"key":"B145","doi-asserted-by":"publisher","first-page":"74","DOI":"10.1016\/J.CORSCI.2018.08.005","article-title":"Self-healing mechanisms in smart protective coatings: A review","volume":"144","author":"Zhang","year":"2018","journal-title":"Corros. Sci."},{"key":"B146","doi-asserted-by":"publisher","first-page":"591","DOI":"10.5006\/1.3277650","article-title":"Hydrotalcite coating formation on Al-Cu-Mg alloys from oxidizing bath chemistries","volume":"58","author":"Zhang","year":"2002","journal-title":"Corrosion"},{"key":"B147","doi-asserted-by":"publisher","first-page":"602","DOI":"10.1016\/J.CORSCI.2009.10.020","article-title":"Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor","volume":"52","author":"Zheludkevich","year":"2010","journal-title":"Corros. Sci."},{"key":"B148","doi-asserted-by":"publisher","first-page":"314","DOI":"10.1016\/j.electacta.2012.04.095","article-title":"Smart\u201d coatings for active corrosion protection based on multi-functional micro and nanocontainers","volume":"82","author":"Zheludkevich","year":"2012","journal-title":"Electrochim. Acta"},{"key":"B149","first-page":"101","article-title":"Self-healing anticorrosion coatings","volume-title":"Self-healing materials: Fundamentals, design strategies, and applications","author":"Zheludkevich","year":"2009"},{"key":"B150","doi-asserted-by":"publisher","first-page":"1055","DOI":"10.1021\/cm048085g","article-title":"Hydrothermal synthesis of layered double hydroxides (LDHs) from mixed MgO and Al2O3: LDH formation mechanism","volume":"17","author":"Zhi","year":"2005","journal-title":"Chem. Mat."},{"key":"B151","doi-asserted-by":"publisher","first-page":"172","DOI":"10.1016\/J.APSUSC.2015.02.086","article-title":"Insitu grown superhydrophobic Zn\u2013Al layered double hydroxides films on magnesium alloy to improve corrosion properties","volume":"337","author":"Zhou","year":"2015","journal-title":"Appl. Surf. Sci."},{"key":"B152","doi-asserted-by":"publisher","first-page":"246","DOI":"10.1016\/J.APSUSC.2017.01.161","article-title":"Design and fabrication of enhanced corrosion resistance Zn-Al layered double hydroxides films based anion-exchange mechanism on magnesium alloys","volume":"404","author":"Zhou","year":"2017","journal-title":"Appl. Surf. Sci."},{"key":"B153","doi-asserted-by":"publisher","first-page":"128062","DOI":"10.1016\/J.JHAZMAT.2021.128062","article-title":"New insights into the capture performance and mechanism of hazardous metals Cr3+ and Cd2+ onto an effective layered double hydroxide based material","volume":"426","author":"Zhu","year":"2022","journal-title":"J. Hazard. Mat."}],"container-title":["Frontiers in Chemistry"],"original-title":[],"link":[{"URL":"https:\/\/www.frontiersin.org\/articles\/10.3389\/fchem.2022.1048313\/full","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,11,18]],"date-time":"2022-11-18T04:54:06Z","timestamp":1668747246000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.frontiersin.org\/articles\/10.3389\/fchem.2022.1048313\/full"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,18]]},"references-count":154,"alternative-id":["10.3389\/fchem.2022.1048313"],"URL":"https:\/\/doi.org\/10.3389\/fchem.2022.1048313","relation":{},"ISSN":["2296-2646"],"issn-type":[{"value":"2296-2646","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,11,18]]},"article-number":"1048313"}}