{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T04:42:43Z","timestamp":1760244163302,"version":"build-2065373602"},"reference-count":14,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2004,1,31]],"date-time":"2004-01-31T00:00:00Z","timestamp":1075507200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Heteroaryl substituted allyl and homoallyl alcohols were synthesised with two different method. Synthesis of bis-allyl ethers and homoallyl ethers were carried out via reaction of allyl bromide with allyl alcohols and homoallyl alcohols, respectively. [2.3]-Wittig Rearrangement reactions of heteroaryl substituted bis-allyl ethers were investigated using GC\/MS techniques. In these reactions two unexpected products were isolated in high yield.<\/jats:p>","DOI":"10.3390\/90100022","type":"journal-article","created":{"date-parts":[[2008,10,25]],"date-time":"2008-10-25T13:32:11Z","timestamp":1224941531000},"page":"22-28","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers"],"prefix":"10.3390","volume":"9","author":[{"given":"S.","family":"Servi","sequence":"first","affiliation":[{"name":"Department of Chemistry, Firat University, Faculty of Science and Arts, 23169, Elazig, Turkey"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"C.","family":"Topaloglu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Firat University, Faculty of Science and Arts, 23169, Elazig, Turkey"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2004,1,31]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3179","DOI":"10.1021\/ja00451a061","article-title":"Grignard-type carbonyl addition of allyl halides by means of chromous salt chemospecific synthesis of homoallyl alcohols","volume":"99","author":"Okude","year":"1977","journal-title":"J. Am. Chem. 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Rev."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1246\/cl.1982.1349","article-title":"Applications of the tandem [2,3]-Wittig oxy-Cope rearrangement to synthesis of exo-brevicomin and oxocrinol. The scope and limitation of the sigmatropic sequences as a synthetic method for delta, epsilon-unsaturated ketones","volume":"9","author":"Mikami","year":"1982","journal-title":"Chem. Lett."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"2911","DOI":"10.1016\/S0040-4020(01)90580-0","article-title":"New sigmatropic sequences based on the [2,3]-Wittig rearrangement of the bis-allylic ether system","volume":"42","author":"Mikami","year":"1986","journal-title":"Tetrahedron"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"6445","DOI":"10.1016\/S0040-4039(97)01473-1","article-title":"Stereoselective [2,3]-Wittig and tandem [2,3]-Wittig anionic oxy-cope rearrangement of bis allylic ethers: effect of substituents","volume":"38","author":"Nicholas","year":"1997","journal-title":"Tetrahedron Lett."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"3313","DOI":"10.1016\/S0040-4020(01)90160-7","article-title":"Palladium mediated cyclization of 1,5-hexadien-3-ols to 1-methyl-1,3-cyclopentadienes","volume":"49","author":"Zair","year":"1993","journal-title":"Tetrahedron"},{"key":"ref_12","first-page":"73","article-title":"Use of 2-alkenyl-3-(chloromethyl) oxiranes in the synthesis of 1, 5-dien-3-ols","volume":"53","author":"Servi","year":"2000","journal-title":"S. Afr. J. Chem."},{"key":"ref_13","first-page":"629","article-title":"Synthesis of allyl-cyclopropyl alcohols and allyl-1,5-hexadien-3-ols and investigation of their antibacterial and antifungal activities","volume":"39","author":"Servi","year":"2000","journal-title":"Ind. J. Chem."},{"key":"ref_14","unstructured":"Budzikiewicz, H., Djerassi, C., and Williams, H.D. (1967). Mass Spectrometry of Organic Compounds, Holden-Day Inc."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/9\/1\/22\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T22:26:02Z","timestamp":1760221562000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/9\/1\/22"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2004,1,31]]},"references-count":14,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2004,1]]}},"alternative-id":["90100022"],"URL":"https:\/\/doi.org\/10.3390\/90100022","relation":{},"ISSN":["1420-3049"],"issn-type":[{"type":"electronic","value":"1420-3049"}],"subject":[],"published":{"date-parts":[[2004,1,31]]}}}