{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,18]],"date-time":"2026-05-18T14:24:31Z","timestamp":1779114271338,"version":"3.51.4"},"reference-count":11,"publisher":"MDPI AG","issue":"11","license":[{"start":{"date-parts":[[2004,11,30]],"date-time":"2004-11-30T00:00:00Z","timestamp":1101772800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Cadmium carbonate was found to be a useful promoter in the Koenigs-Knorrsynthesis of 2-(4-methoxybenzyl)cyclohexyl-\u03b2-D-glycopyranosides. Using this promotermodel glucoside and galactoside derivatives of cyclic (i.e., secondary) alcohols weresynthesized in 50\u201360 % overall yields. Diastereoisomeric mixtures of products wereobtained in these syntheses, which started from racemic isomers of 2-(4-methoxy-benzyl)cyclohexanol. The prepared compounds have been purified and characterized bytheir 1H- and 13C-NMR spectra, as well as by their IR and MS spectra, in order to usethem as reference compounds in planned subsequent research.<\/jats:p>","DOI":"10.3390\/91100902","type":"journal-article","created":{"date-parts":[[2008,10,25]],"date-time":"2008-10-25T13:32:11Z","timestamp":1224941531000},"page":"902-912","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Koenigs-Knorr Synthesis of Cycloalkyl Glycosides"],"prefix":"10.3390","volume":"9","author":[{"given":"Zdenek","family":"Wimmer","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry and Biochemistry AS CR, Flemingovo namesti 2, CZ-16610, Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lucie","family":"Pechova","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technology, Technicka 5, CZ-16028 Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"David","family":"Saman","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry and Biochemistry AS CR, Flemingovo namesti 2, CZ-16610, Prague 6, Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2004,11,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Igarashi, K. (1977). Adv. Carbohydr. Chem. Biochem., 34, 243\u2013283.","DOI":"10.1016\/S0065-2318(08)60326-1"},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Schmidt, R. R. (1986). Angew. Chem. Int. Ed. Engl., 25, 212\u2013235.","DOI":"10.1002\/anie.198602121"},{"key":"ref_3","doi-asserted-by":"crossref","unstructured":"Hanessian, S. (1997). \u2018Preparative Carbohydrate Chemistry\u2019, Dekker.","DOI":"10.1201\/9781482273588"},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Hanessian, S. (1997). \u2018Preparative Carbohydrate Chemistry\u2019, Dekker.","DOI":"10.1201\/9781482273588"},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Hanessian, S. (1997). \u2018Preparative Carbohydrate Chemistry\u2019, Dekker.","DOI":"10.1201\/9781482273588"},{"key":"ref_6","doi-asserted-by":"crossref","unstructured":"Wimmer, Z., and Roma\u0148uk, M. (1982). Coll. Czech. Chem. Commun., 47, 1878\u20131883.","DOI":"10.1135\/cccc19821878"},{"key":"ref_7","doi-asserted-by":"crossref","unstructured":"Wimmer, Z., Rejzek, M., Zarev\u00facka, M., Kuldov\u00e1, J., Hrd\u00fd, I., N\u011bmec, V., and Roma\u0148uk, M. (1997). J. Chem. Ecol., 23, 605\u2013628.","DOI":"10.1023\/B:JOEC.0000006399.07779.16"},{"key":"ref_8","doi-asserted-by":"crossref","unstructured":"Plattner, J. J., Gless, R. D., and Rapoport, H. (1972). J. Am. Chem. Soc., 94, 8613\u20138615.","DOI":"10.1021\/ja00779a072"},{"key":"ref_9","doi-asserted-by":"crossref","unstructured":"Bud\u011b\u0161\u00ednsk\u00fd, M., \u0160aman, D., and Wimmer, Z. (1982). Coll. Czech. Chem. Commun., 47, 2763\u20132767.","DOI":"10.1135\/cccc19822763"},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"von Kienlin, M., Moonen, C. T. W., van der Toorn, A., and van Zijl, C. M. (1991). J. Magn. Reson., 93, 423\u2013429.","DOI":"10.1016\/0022-2364(91)90020-T"},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Willker, W., Leibfritz, D., Kerssebaum, R., and Bermel, W. (1993). Magn. Reson. Chem., 31, 287\u2013292.","DOI":"10.1002\/mrc.1260310315"}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/9\/11\/902\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T22:26:08Z","timestamp":1760221568000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/9\/11\/902"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2004,11,30]]},"references-count":11,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2004,11]]}},"alternative-id":["91100902"],"URL":"https:\/\/doi.org\/10.3390\/91100902","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2004,11,30]]}}}