{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,22]],"date-time":"2026-04-22T14:30:20Z","timestamp":1776868220424,"version":"3.51.2"},"reference-count":26,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2015,4,30]],"date-time":"2015-04-30T00:00:00Z","timestamp":1430352000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Entropy"],"abstract":"<jats:p>CaMoO4 nanocakes with uniform size and morphology were prepared on a large scale via a room temperature reverse-microemulsion method. The products were characterized in detail by X-ray powder diffraction, field-emission scanning electron microscopy, transmission electron microscopy, and high-resolution transmission electron microscopy. By establishing the relations between the thermodynamic functions of  nano-CaMoO4 and bulk-CaMoO4 reaction systems, the equations for calculating the surface thermodynamic functions of nano-CaMoO4 were derived. Then, combined with in-situ microcalorimetry, the molar surface enthalpy, molar surface Gibbs free energy, and molar surface entropy of the prepared CaMoO4 nanocakes at 298.15 K were successfully obtained as (19.674 \u00b1 0.017) kJ\u00b7mol\u22121, (619.704 \u00b1 0.016) J\u00b7mol\u22121, and (63.908 \u00b1 0.057) J\u00b7mol\u22121\u00b7K\u22121, respectively.<\/jats:p>","DOI":"10.3390\/e17052741","type":"journal-article","created":{"date-parts":[[2015,4,30]],"date-time":"2015-04-30T08:58:53Z","timestamp":1430384333000},"page":"2741-2748","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Synthesis and Surface Thermodynamic Functions of CaMoO4 Nanocakes"],"prefix":"10.3390","volume":"17","author":[{"given":"Xingxing","family":"Li","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gaochao","family":"Fan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zaiyin","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530008, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2015,4,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1021\/nl010010d","article-title":"Perspective: Nanothermodynamics","volume":"1","author":"Hill","year":"2001","journal-title":"Nano Lett."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1021\/nl010009e","article-title":"Extension of Nanothermodynamics to Include a One-dimensional Surface Excess","volume":"1","author":"Hill","year":"2001","journal-title":"Nano Lett."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1021\/nl010027w","article-title":"A Different Approach to Nanothermodynamics","volume":"1","author":"Hill","year":"2001","journal-title":"Nano Lett."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"761","DOI":"10.1038\/355761a0","article-title":"Science at the Atomic Scale","volume":"355","author":"Ball","year":"1992","journal-title":"Nature"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1006\/jcis.1997.4911","article-title":"The Theory of Thermodynamics for Chemical Reactions in Dispersed Heterogeneous Systems","volume":"191","author":"Xue","year":"1997","journal-title":"J. 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