{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,5]],"date-time":"2026-03-05T02:06:30Z","timestamp":1772676390691,"version":"3.50.1"},"reference-count":16,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2020,3,24]],"date-time":"2020-03-24T00:00:00Z","timestamp":1585008000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Entropy"],"abstract":"<jats:p>This paper presents a review of our original results obtained during the last decade. These results have been found theoretically for classical mass-action-law models of chemical kinetics and justified experimentally. In contrast with the traditional invariances, they relate to a special battery of kinetic experiments, not a single experiment. Two types of invariances are distinguished and described in detail: thermodynamic invariants, i.e., special combinations of kinetic dependences that yield the equilibrium constants, or simple functions of the equilibrium constants; and \u201cmixed\u201d kinetico-thermodynamic invariances, functions both of equilibrium constants and non-thermodynamic ratios of kinetic coefficients.<\/jats:p>","DOI":"10.3390\/e22030373","type":"journal-article","created":{"date-parts":[[2020,3,24]],"date-time":"2020-03-24T13:04:04Z","timestamp":1585055044000},"page":"373","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["New Invariant Expressions in Chemical Kinetics"],"prefix":"10.3390","volume":"22","author":[{"given":"Gregory","family":"Yablonsky","sequence":"first","affiliation":[{"name":"McKelvey School of Engineering, Department of Energy, Environmental and Chemical Engineering, Washington University in St. Louis, 1 Brookings Dr., St. Louis, MO 63130, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daniel","family":"Branco","sequence":"additional","affiliation":[{"name":"Department of Separation and Conversion Technology, VITO (Flemish Institute for Technological Research), Boeretang 200, B-2400 Mol, Belgium"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guy","family":"Marin","sequence":"additional","affiliation":[{"name":"Laboratory for Chemical Technology, Ghent University, Technologiepark 914, B-9052 Ghent, Belgium"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Denis","family":"Constales","sequence":"additional","affiliation":[{"name":"Department of Electronics and Information Systems ELIS, Ghent University, Building S-8, Krijgslaan 281, B-9000 Ghent, Belgium"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2020,3,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Marin, G.B., Yablonsky, G.S., and Constales, D. 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