{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T22:14:51Z","timestamp":1788473691966,"version":"build-2803163510"},"reference-count":67,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2022,12,28]],"date-time":"2022-12-28T00:00:00Z","timestamp":1672185600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Institute for Energy and Fuel Processing Technology"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Entropy"],"abstract":"<jats:p>A thermodynamic the influence of temperature on the logarithm of the considered quantity is expressed by bifunctional functional terms (1\/T, lnT). For this purpose, the Apelblat &amp; Manzurola (A&amp;M) equation was used for extended model dissolution analysis of 12 aromatic hydrocarbons in tetralin and decalin vs. temperature for saturated solutions. The A&amp;M equation was found to be thermodynamically compensatory in the sense of Enthalpy-Entropy-Compensation (EEC) while limiting melting temperature Tm=\u2206mH\u2206mS. The coefficients for the functional terms A1 vs. A2 are a linear relationship, with a slope called the compensation temperature Tc, as ratio of average enthalpy to average entropy. From this dependence, it has been shown that the approximation of \u2206cp=\u2206mS\u00af is justified, also assuming the average entropy. Regarding the term representing the activity coefficients, modifications to the A&amp;M equation were proposed by replacing the intercept and it was shown that the new form correctly determines \u2206mH. However, the condition is that the molar fraction of the solute exceeds x &gt; 0.5 moles. It has been shown that the simplest equation referred to van \u2019t Hoff\u2019s isobar also allows the simultaneous determination of enthalpy and entropy, but these quantities do not always come down to melting temperature.<\/jats:p>","DOI":"10.3390\/e25010055","type":"journal-article","created":{"date-parts":[[2022,12,28]],"date-time":"2022-12-28T08:38:19Z","timestamp":1672216699000},"page":"55","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Enthalpy-Entropy Compensation Effect in Saturated Solutions on an Example of Polynuclear Aromatics According to Thermodynamics at Melting Temperature"],"prefix":"10.3390","volume":"25","author":[{"given":"Andrzej","family":"Mianowski","sequence":"first","affiliation":[{"name":"Institute for Energy and Fuel Processing Technology, Zamkowa Street 1, 41-803 Zabrze, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3466-0299","authenticated-orcid":false,"given":"Grzegorz","family":"\u0141abojko","sequence":"additional","affiliation":[{"name":"Institute for Energy and Fuel Processing Technology, Zamkowa Street 1, 41-803 Zabrze, Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,12,28]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"972","DOI":"10.1038\/127972a0","article-title":"Calculation of the Latent Heat of Fusion of Camphor from Vapour Pressure\u2013Temperature Data","volume":"127","author":"Tideman","year":"1931","journal-title":"Nature"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"3493","DOI":"10.1002\/qj.4154","article-title":"The Rankine-Kirchhoff approximations for moist thermodynamics","volume":"147","author":"Romps","year":"2021","journal-title":"Q. J. R. Met. Soc."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"1090","DOI":"10.2355\/isijinternational.47.1090","article-title":"Viscosity of Highly Basic Slags","volume":"47","author":"Seok","year":"2007","journal-title":"ISIJ Int."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1007\/BF01499664","article-title":"On the Hole Theory of Viscosity, Compressibility, and Expansivity of Liquids","volume":"181","author":"Weymann","year":"1961","journal-title":"Kolloid-Zeitschrifl Zeitschrifl F\u00fcr Polym."},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Augustijns, P., and Brewster, M.E. (2007). Solvent Systems and Their Selection in Pharmaceutics and Biopharmaceutics, Springer.","DOI":"10.1007\/978-0-387-69154-1"},{"key":"ref_6","unstructured":"Acree, W.E. (1995). Polycyclic Aromatic Hydrocarbons: Binary Non-Aqueous System, Oxford University Press."},{"key":"ref_7","first-page":"1","article-title":"IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 1. Binary Solvent Mixtures","volume":"42","author":"Acree","year":"2013","journal-title":"J. Phys. Chem. Ref. Data"},{"key":"ref_8","first-page":"1","article-title":"IUPAC-NIST Solubility Data Series. 98. Solubility of Polycyclic Aromatic Hydrocarbons in Pure and Organic Solvent Mixtures: Revised and Updated. Part 2. Ternary Solvent Mixtures","volume":"42","author":"Acree","year":"2013","journal-title":"J. Phys. Chem. Ref. Data"},{"key":"ref_9","doi-asserted-by":"crossref","unstructured":"Hefter, G.T., and Tomkins, R.P.T. (2003). The Experimental Determination of Solubilities, John Wiley & Sons. Chapter 1.1.","DOI":"10.1002\/0470867833"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"539","DOI":"10.1039\/tf9666200539","article-title":"Evaluation of thermodynamic functions from equilibrium constants","volume":"62","author":"Clarke","year":"1966","journal-title":"Trans. Faraday Soc."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/j.jct.2011.09.006","article-title":"Fluorene: An extended experimental thermodynamic study","volume":"45","author":"Monte","year":"2012","journal-title":"J. Chem. Thermodyn."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"2070","DOI":"10.1021\/je5002158","article-title":"Measurement and correlation of the solubility of enrofloxacin in different solvents from (303.15 to 321.05) K","volume":"59","author":"Liu","year":"2014","journal-title":"J. Chem. Eng. Data"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1016\/j.fluid.2015.05.026","article-title":"Vapor pressures and thermophysical properties of selected hexenols and recommended vapor for hexan-1-ol","volume":"402","author":"Fulem","year":"2015","journal-title":"Fluid Phase Equilibria"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1016\/j.jct.2016.05.007","article-title":"Thermodynamic properties of 2,7-di-tert-butylfluorene\u2014An experimental and computational study","volume":"101","author":"Oliveira","year":"2016","journal-title":"J. Chem. Thermodyn."},{"key":"ref_15","unstructured":"Elliot, J.R., and Lira, C.T. (2012). Introductory Chemical Engineering Thermodynamics, Chapter 11, An Introduction to Activity Models, Prentice-Hall. [2nd ed.]."},{"key":"ref_16","unstructured":"Szarawara, J. (1997). Termodynamika Chemiczna Stosowana, WNT. [3rd ed.]. (In Polish)."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1021\/ja01056a002","article-title":"Vapor-Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing","volume":"86","author":"Wilson","year":"1964","journal-title":"J. Am. Chem. Soc."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"519","DOI":"10.1007\/BF00651460","article-title":"Solubilities of families of heterocyclic polynuclear aromatics in organic solvents and their mixtures","volume":"17","author":"Coon","year":"1988","journal-title":"J. Sol. Chem."},{"key":"ref_19","first-page":"29","article-title":"Parameter\u2019s estimate in Wilson equation","volume":"9","author":"Hristova","year":"2015","journal-title":"Int. Electron. J. Pure Appl. Math."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"181","DOI":"10.1016\/j.fluid.2016.02.041","article-title":"Correlation of interaction parameters in Wilson, NRTL and UNIQUAC models using theoretical methods","volume":"417","author":"Farajnezhad","year":"2016","journal-title":"Fluid Phase Equilibria"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"305","DOI":"10.1016\/0378-3812(89)80060-3","article-title":"A comparison of solid-liquid equilibrium with vapor-liquid equilibrium for prediction of activity coefficients in systems containing polynuclear aromatics","volume":"44","author":"Coon","year":"1989","journal-title":"Fluid Phase Equilibria"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1","DOI":"10.4236\/ojsst.2017.71001","article-title":"The measurement and prediction of flash point for binary mixtures {C1~ C3 alcohols + p-xylene} at 101.3 kPa","volume":"7","author":"Han","year":"2017","journal-title":"Open J. Saf. Sci. Technol."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"116","DOI":"10.1002\/aic.690210115","article-title":"Statistical thermodynamics of liquid mixtures: A new expression for the excess Gibbs energy of partly or completely miscible systems","volume":"21","author":"Abrams","year":"1975","journal-title":"AIChE J."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1016\/j.fluid.2014.04.014","article-title":"An algorithm for the regression of the UNIQUAC interaction parameters in liquid-liquid equilibrium for single- and multi-temperature experimental data","volume":"374","author":"Santori","year":"2014","journal-title":"Fluid Phase Equilibria"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"609","DOI":"10.1021\/ie00089a017","article-title":"New analytical solution of group\u2019s method parameters for the prediction of vapor-liquid equilibrium","volume":"28","author":"Correa","year":"1989","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.fluid.2012.10.020","article-title":"MOQUAC, a new expression for the excess Gibbs free energy based on molecular orientations","volume":"338","author":"Bronneberg","year":"2013","journal-title":"Fluid Phase Equilibria"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"958","DOI":"10.1023\/A:1015873521067","article-title":"Ideal solubility of a solid solute: Effect of heat capacity assumptions","volume":"9","author":"Mishra","year":"1992","journal-title":"Pharm. Res."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"85","DOI":"10.1006\/jcht.1998.0424","article-title":"Solubilities of o-acetylsalicylic, 4-aminosalicylic, 3,5-dinitrosalicylic, and p-toluic acid, and magnesium-DL-aspartate in water from T = (278 to 348) K","volume":"31","author":"Apelblat","year":"1999","journal-title":"J. Chem. Thermodyn."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"469","DOI":"10.2306\/scienceasia1513-1874.2007.33.469","article-title":"Solubility of stearic acid in various organic solvents and its prediction using non-ideal solution models","volume":"33","author":"Heryanto","year":"2007","journal-title":"Sci. Asia"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"170","DOI":"10.1016\/j.molliq.2011.01.004","article-title":"Thermodynamics of the solubility of sulfamethazine in methanol, ethanol, 1-propanol, acetone, and chloroform from 293.15 to 333.15 K","volume":"159","author":"Zhang","year":"2011","journal-title":"J. Mol. Liquids"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"100","DOI":"10.6000\/1929-5030.2012.01.02.4","article-title":"Solubility of fudosteine in some pure and mixed solvents from (278.15 to 308.15) K","volume":"1","author":"Yan","year":"2012","journal-title":"J. App. Sol. Chem. Mod."},{"key":"ref_32","first-page":"396","article-title":"Measurement and modeling of the solubility of vanillin constituent of olive mill wastewater in binary water + ethanol solvents mixtures between 278.15 K and 308.15 K","volume":"8","author":"Noubigh","year":"2014","journal-title":"Aust. J. Basic Appl. Sci."},{"key":"ref_33","first-page":"125","article-title":"Solution thermodynamics and solubility of indomethacin in ethanol-water mixtures in the temperature range from 293.15 to 318.15 K","volume":"47","author":"Shakeel","year":"2015","journal-title":"Bulg. Chem. Commun."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"975","DOI":"10.1021\/j100446a008","article-title":"Solvent activity along a saturation line and solubility of hydrogen-bonding solids","volume":"84","author":"Buchowski","year":"1980","journal-title":"J. Phys. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"638","DOI":"10.1021\/es00171a004","article-title":"Aqueous solubility of polychlorinated biphenyls related to molecular structure","volume":"22","author":"Opperhulzen","year":"1988","journal-title":"Environ. Sci. Technol."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"1157","DOI":"10.1023\/A:1015984310068","article-title":"Solid and liquid heat capacities of n-alkyl para-aminobenzoates near the melting point","volume":"7","author":"Neau","year":"1990","journal-title":"Pharm. Res."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"601","DOI":"10.1023\/A:1012148910975","article-title":"Differential molar heat capacities to test ideal solubility estimations","volume":"14","author":"Neau","year":"1997","journal-title":"Pharm. Res."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"708","DOI":"10.1016\/j.enbuild.2005.10.006","article-title":"Eutectic mixtures of capric acid and lauric acid applied in building wallboards for heat energy storage","volume":"38","author":"Shilei","year":"2006","journal-title":"Energy Build."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"1100","DOI":"10.1002\/jps.21897","article-title":"Estimation of the ideal solubility (Crystal-Liquid Fugacity Ratio) of organic compounds","volume":"99","author":"Yalkowsky","year":"2010","journal-title":"Pharm. Sci."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"48","DOI":"10.56431\/p-c5b9qj","article-title":"Solubility of butylated hydroxytoluene (BHT) in aqueous and alcohol solutions from 293","volume":"9","author":"Baluja","year":"2014","journal-title":"15 to 313.15 K. Int. Lett. Chem. Phys. Astron."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"312","DOI":"10.18433\/J3KS4P","article-title":"Crystal-liquid fugacity ration as a surrogate parameter for intestinal permeability","volume":"19","author":"Fasihi","year":"2016","journal-title":"J. Pharm. Pharm. Sci."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"176","DOI":"10.1080\/00319104.2017.1317779","article-title":"Extended Hildebrand solubility approach applied to some sulphapyrimidines in some {methanol (1) + water (2)} mixtures","volume":"56","author":"Delgado","year":"2017","journal-title":"Phys. Chem. Liquids"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"1371","DOI":"10.1007\/s10973-017-6473-3","article-title":"Thermodynamic approaches for the prediction of oral drug absorption","volume":"130","author":"Fasihi","year":"2017","journal-title":"J. Therm. Anal. Cal."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"2710","DOI":"10.1002\/jps.24033","article-title":"Unified physicochemical properly estimation relationships (UPPER)","volume":"103","author":"Yalkowsky","year":"2014","journal-title":"J. Pharm. Pharm. Sci."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"403","DOI":"10.1021\/je00042a011","article-title":"Solubility of aromatic hydrocarbon solids in mixtures of benzene and cyclohexane","volume":"30","author":"Choi","year":"1985","journal-title":"J. Chem. Eng. Data"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"125","DOI":"10.1016\/0378-5173(94)90187-2","article-title":"Prediction of carbazole solubility and its dependence upon the solvent nature","volume":"104","author":"Ruelle","year":"1994","journal-title":"Int. J. Pharm."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/S0045-6535(96)00377-3","article-title":"Aqueous solubility prediction of environmentally important chemicals from the mobile order thermodynamics","volume":"34","author":"Ruelle","year":"1997","journal-title":"Chemosphere"},{"key":"ref_48","unstructured":"(2022, October 30). Available online: https:\/\/pubchem.ncbi.nlm.nih.gov\/compound\/8404#section=Kovats-Retention-Index."},{"key":"ref_49","unstructured":"(2022, October 30). Available online: https:\/\/webbook.nist.gov\/cgi\/cbook.cgi?ID=C493027&Mask=2."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"360","DOI":"10.1007\/s10953-015-0317-1","article-title":"Solution Thermodynamics and Preferential Solvation of Sulfamerazine in Methanol + Water Mixtures","volume":"44","author":"Delgado","year":"2015","journal-title":"J. Solut. Chem."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1007\/s00706-012-0837-y","article-title":"\u2018Entropy is anthropomorphic\u2019: Does this lead to interpretational devalorisation of entropy-enthalpy compensation?","volume":"144","author":"Starikov","year":"2013","journal-title":"Monatsh. Chem."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"659","DOI":"10.1002\/jps.2600690613","article-title":"Extended Hildebrand approach: Solubility of caffeine in dioxane-water mixtures","volume":"69","author":"Adjei","year":"1980","journal-title":"J. Pharm. Sci."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1007\/s10973-006-7516-3","article-title":"Examination of polyolefins\u2014organic compounds interactions by inverse gas chromatography","volume":"89","author":"Siudyga","year":"2007","journal-title":"J. Therm. Anal. Cal."},{"key":"ref_54","first-page":"315","article-title":"Extended Hildebrand solubility approach: Satranidazole in mixtures of dioxane and water","volume":"73","author":"Rathi","year":"2011","journal-title":"Indian J. Pharm. Sci."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"40","DOI":"10.2174\/1874396X01105010040","article-title":"Analysis of predictive thermodynamic models for estimation of polycyclic aromatic solid solubility in hot pressurized water","volume":"5","author":"Fornari","year":"2011","journal-title":"Open Thermodyn. J."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"15876","DOI":"10.1021\/acs.jpcb.5b09925","article-title":"Enthalpy-Entropy compensation (EEC) effect: A revisit","volume":"119","author":"Pan","year":"2015","journal-title":"J. Phys. Chem. B"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"50","DOI":"10.1021\/i160073a009","article-title":"Detection of the Compensation Effect (\u03b8 Rule)","volume":"19","author":"Krug","year":"1980","journal-title":"Ind. Eng. Chem. Fundamen."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"1689","DOI":"10.1021\/jp1105696","article-title":"Entropy-enthalpy compensation in chemical reactions and adsorption: An exactly solvable model","volume":"115","author":"Freed","year":"2011","journal-title":"J. Phys. Chem. B"},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"126","DOI":"10.6000\/1929-5030.2013.02.02.7","article-title":"Entropy-Enthalpy Compensation and its Significance\u2014in Particular for Nanoscale Events","volume":"2","author":"Starikov","year":"2013","journal-title":"J. Appl. Sol. Chem. Model."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/0378-5173(84)90104-2","article-title":"Non-linear van\u2019t Hoff solubility-temperature plots and their pharmaceutical interpretation","volume":"18","author":"Grant","year":"1984","journal-title":"Int. J. Pharm."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"6819","DOI":"10.1021\/acs.jpca.8b04432","article-title":"Isoconversional methods in thermodynamic principles","volume":"122","author":"Mianowski","year":"2018","journal-title":"J. Phys. Chem. A"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"2341","DOI":"10.1021\/j100562a007","article-title":"Enthalpy-Entropy Compensation. 2. Separation of the Chemical from the Statistical Effect","volume":"80","author":"Krug","year":"1976","journal-title":"J. Phys. Chem."},{"key":"ref_63","doi-asserted-by":"crossref","unstructured":"Shakeel, F., Alshehri, S., Imran, M., Haq, N., Alanazi, A., and Anwer, M.K. (2020). Experimental and Computational Approaches for Solubility Measurement of Pyridazinone Derivative in Binary (DMSO + Water) Systems. Molecules, 25.","DOI":"10.3390\/molecules25010171"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"733","DOI":"10.1080\/00319104.2020.1808658","article-title":"Dissolution thermodynamics and preferential solvation of meloxicam in (acetonitrile + water) mixtures","volume":"59","author":"Martinez","year":"2021","journal-title":"Phys. Chem. Liquids"},{"key":"ref_65","doi-asserted-by":"crossref","unstructured":"Starikov, E.B., Nord\u00e9n, B., and Tanaka, S. (2021). Entropy-Enthalpy Compensation: An Attempt to Find a Methodological Common Denominator, Jenny Stanford Publishing Pte. Ltd.. Available online: www.jennystanford.com.","DOI":"10.1201\/9781003056256"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1016\/j.cplett.2012.04.028","article-title":"Entropy\u2013enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data","volume":"538","author":"Starikov","year":"2012","journal-title":"Chem. Phys. Let."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"88","DOI":"10.1016\/j.cplett.2013.02.016","article-title":"Valid entropy\u2013enthalpy compensation: Fine mechanisms at microscopic level","volume":"564","author":"Starikov","year":"2013","journal-title":"Chem. Phys. Let."}],"container-title":["Entropy"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1099-4300\/25\/1\/55\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:53:49Z","timestamp":1760147629000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1099-4300\/25\/1\/55"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,12,28]]},"references-count":67,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2023,1]]}},"alternative-id":["e25010055"],"URL":"https:\/\/doi.org\/10.3390\/e25010055","relation":{},"ISSN":["1099-4300"],"issn-type":[{"value":"1099-4300","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,12,28]]}}}