{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T09:23:02Z","timestamp":1768814582242,"version":"3.49.0"},"reference-count":36,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2022,5,16]],"date-time":"2022-05-16T00:00:00Z","timestamp":1652659200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"European Structural and Investment Funds","award":["#KK.01.1.1.01.0010"],"award-info":[{"award-number":["#KK.01.1.1.01.0010"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Sensors"],"abstract":"<jats:p>Direct potentiometric measurements using solid-state sensors have a great potential for thiabendazole (TBZ) determination, considering simplicity, accuracy, and low cost. Modifying the sensing material of the sensor with multi-walled carbon nanotubes (MWCNTs) leads to improved analytical properties of the sensor. In this study, a new potentiometric solid-state sensor for TBZ determination, based on MWCNTs modified with a sulfate group, and TBZ ion as sensing material was developed. The sensor exhibited a Nernstian response for TBZ (60.4 mV\/decade of activity) in a working range between 8.6 \u00d7 10\u22127 and 1.0 \u00d7 10\u22123 M. The detection limit for TBZ was 6.2 \u00d7 10\u22127 M. The response time of the sensor for TBZ was 8 s, and its signal drift was only 1.7 mV\/h. The new sensor is applicable for direct potentiometric determination of TBZ in complex real samples, such as fruit peel. The accuracy of TBZ determination is confirmed using the standard addition method.<\/jats:p>","DOI":"10.3390\/s22103785","type":"journal-article","created":{"date-parts":[[2022,5,16]],"date-time":"2022-05-16T21:36:06Z","timestamp":1652736966000},"page":"3785","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["A New, MWCNT-Based, Solid-State Thiabendazole-Selective Sensor"],"prefix":"10.3390","volume":"22","author":[{"given":"Andrea","family":"Dandi\u0107","sequence":"first","affiliation":[{"name":"Department of Chemistry, Josip Juraj Strossmayer University of Osijek, Cara Hadrijana 8\/A, 31000 Osijek, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ivana","family":"Novak","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Josip Juraj Strossmayer University of Osijek, Cara Hadrijana 8\/A, 31000 Osijek, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9509-8105","authenticated-orcid":false,"given":"Marija","family":"Jozanovi\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Josip Juraj Strossmayer University of Osijek, Cara Hadrijana 8\/A, 31000 Osijek, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Iva","family":"Pukle\u0161","sequence":"additional","affiliation":[{"name":"Doctoral School of Chemistry, University of P\u00e9cs, Ifj\u00fas\u00e1g \u00fatja, 7624 P\u00e9cs, Hungary"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9207-2551","authenticated-orcid":false,"given":"Aleksandar","family":"Sz\u00e9chenyi","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Josip Juraj Strossmayer University of Osijek, Cara Hadrijana 8\/A, 31000 Osijek, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mateja","family":"Budeti\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Josip Juraj Strossmayer University of Osijek, Cara Hadrijana 8\/A, 31000 Osijek, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mirela","family":"Samard\u017ei\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Josip Juraj Strossmayer University of Osijek, Cara Hadrijana 8\/A, 31000 Osijek, Croatia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,5,16]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"5659","DOI":"10.1039\/c2an36094b","article-title":"Indirect Competitive Immunoassay for the Detection of Fungicide Thiabendazole in Whole Orange Samples by Surface Plasmon Resonance","volume":"137","author":"Estevez","year":"2012","journal-title":"Analyst"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/j.foodchem.2018.03.105","article-title":"Rapid Determination of Thiabendazole in Juice by SERS Coupled with Novel Gold Nanosubstrates","volume":"259","author":"Alsammarraie","year":"2018","journal-title":"Food Chem."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"814","DOI":"10.1016\/j.foodchem.2013.08.136","article-title":"Detection of Thiabendazole Applied on Citrus Fruits and Bananas Using Surface Enhanced Raman Scattering","volume":"145","author":"David","year":"2014","journal-title":"Food Chem."},{"key":"ref_4","first-page":"e06586","article-title":"Modification of the Existing Maximum Residue Levels and Setting of Import Tolerances for Thiabendazole in Various Crops","volume":"19","author":"Anastassiadou","year":"2021","journal-title":"EFSA J."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"232","DOI":"10.1016\/j.tiv.2015.12.018","article-title":"The Fungicide Thiabendazole Causes Apoptosis in Rat Hepatocytes","volume":"32","author":"Marion","year":"2016","journal-title":"Toxicol. Vitr."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"709","DOI":"10.1124\/dmd.105.008094","article-title":"In Vitro Metabolic Activation of Thiabendazole via 5-Hydroxythiabendazole: Identification of a Glutathione Conjugate of 5-Hydroxythiabendazoles","volume":"34","author":"Dalvie","year":"2006","journal-title":"Drug Metab. Dispos."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"2616","DOI":"10.1016\/j.fct.2008.04.019","article-title":"Transcriptome Analysis Provides New Insights into Liver Changes Induced in the Rat upon Dietary Administration of the Food Additives Butylated Hydroxytoluene, Curcumin, Propyl Gallate and Thiabendazole","volume":"46","author":"Stierum","year":"2008","journal-title":"Food Chem. Toxicol."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1006\/rtph.1999.1356","article-title":"An Analysis of the Possibility for Health Implications of Joint Actions and Interactions between Food Additives","volume":"31","author":"Groten","year":"2000","journal-title":"Regul. Toxicol. Pharmacol."},{"key":"ref_9","doi-asserted-by":"crossref","unstructured":"Dumancas, G.G., Hikkaduwa Koralege, R.S., Mojica, E.R.E., Murdianti, B.S., and Pham, P.J. (2014). Thiabendazole. Encyclopedia of Toxicology, Elsevier. [3rd ed.].","DOI":"10.1016\/B978-0-12-386454-3.01173-8"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1299","DOI":"10.1080\/03067319.2015.1100727","article-title":"Development of an Indirect Enzyme Immunoassay for the Determination of Thiabendazole in White and Red Wines","volume":"95","author":"Tsialla","year":"2015","journal-title":"Int. J. Environ. Anal. Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"1285","DOI":"10.1016\/j.microc.2019.02.064","article-title":"Molecularly Imprinted Monolithic Column Based on Functionalized \u03b2-Cyclodextrin and Multi-Walled Carbon Nanotubes for Selective Recognition of Benzimidazole Residues in Citrus Samples","volume":"146","author":"Liang","year":"2019","journal-title":"Microchem. J."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"460847","DOI":"10.1016\/j.chroma.2019.460847","article-title":"Evaluation of Sulfonic Acid Functionalized Covalent Triazine Framework as a Hydrophilic-Lipophilic Balance\/Cation-Exchange Mixed-Mode Sorbent for Extraction of Benzimidazole Fungicides in Vegetables, Fruits and Juices","volume":"1618","author":"Zhao","year":"2020","journal-title":"J. Chromatogr. A"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"120746","DOI":"10.1016\/j.talanta.2020.120746","article-title":"Direct-Immersion SPME in Soy Milk for Pesticide Analysis at Trace Levels by Means of a Matrix-Compatible Coating","volume":"211","author":"Gionfriddo","year":"2020","journal-title":"Talanta"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"106376","DOI":"10.1016\/j.microc.2021.106376","article-title":"Determination of Fungicides\u2019 Residues and Their Degradation Kinetics in Orange Tree Fruits Using Liquid Chromatography\u2014Tandem Mass Spectrometry Coupled with QuEChERS Method","volume":"168","author":"Fares","year":"2021","journal-title":"Microchem. J."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"108311","DOI":"10.1016\/j.foodcont.2021.108311","article-title":"Assessment of a Specific Sample Cleanup for the Multiresidue Determination of Veterinary Drugs and Pesticides in Salmon Using Liquid Chromatography\/Tandem Mass Spectrometry","volume":"130","author":"Bouza","year":"2021","journal-title":"Food Control"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"583","DOI":"10.1016\/j.tifs.2021.08.006","article-title":"Application of Surface-Enhanced Raman Spectroscopy Using Silver and Gold Nanoparticles for the Detection of Pesticides in Fruit and Fruit Juice","volume":"116","author":"Wang","year":"2021","journal-title":"Trends Food Sci. Technol."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"131681","DOI":"10.1016\/j.foodchem.2021.131681","article-title":"Label-Free Au NRs-Based SERS Coupled with Chemometrics for Rapid Quantitative Detection of Thiabendazole Residues in Citrus","volume":"375","author":"Pan","year":"2022","journal-title":"Food Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"106488","DOI":"10.1016\/j.microc.2021.106488","article-title":"Experimental and Theoretical Investigation for the Spectrophotometric Determination of Thiabendazole in Fruit Samples","volume":"168","author":"Tuzen","year":"2021","journal-title":"Microchem. J."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"90","DOI":"10.1016\/j.aca.2009.05.033","article-title":"Flow Injection Analysis with On-Line Nylon Powder Extraction for Room-Temperature Phosphorescence Determination of Thiabendazole","volume":"646","author":"Piccirilli","year":"2009","journal-title":"Anal. Chim. Acta"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"125812","DOI":"10.1016\/j.foodchem.2019.125812","article-title":"Green Synthesized Carbon Dots Embedded in Silica Molecularly Imprinted Polymers, Characterization and Application as a Rapid and Selective Fluorimetric Sensor for Determination of Thiabendazole in Juices","volume":"310","author":"Kazemifard","year":"2020","journal-title":"Food Chem."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"114179","DOI":"10.1016\/j.jelechem.2020.114179","article-title":"Electrochemical Sensing of Thiabendazole in Complex Samples Using Boron-Doped Diamond Electrode","volume":"866","author":"Ribeiro","year":"2020","journal-title":"J. Electroanal. Chem."},{"key":"ref_22","first-page":"1088","article-title":"The Potentiometric Sensor for Determination of Thiabendazole","volume":"15","author":"Volnyanska","year":"2020","journal-title":"J. Eng. Appl. Sci."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"122196","DOI":"10.1016\/j.talanta.2021.122196","article-title":"A New Solid-State Anionic Surfactant-Selective Sensor Based on Functionalized MWCNT","volume":"226","author":"Ravnjak","year":"2021","journal-title":"Talanta"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"S2934","DOI":"10.1016\/j.arabjc.2013.11.029","article-title":"Chemically Modified Multiwalled Carbon Nanotube Carbon Paste Electrode for Copper Determination","volume":"10","author":"Ghaedi","year":"2017","journal-title":"Arab. J. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"795","DOI":"10.1016\/j.snb.2017.05.067","article-title":"A Functionalized Nanomaterial Based, New, Solid State Cationic-Surfactant-Selective Sensor with Fast Response and Low Noise","volume":"251","year":"2017","journal-title":"Sens. Actuators B Chem."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1016\/j.msea.2007.02.091","article-title":"Study on Amino-Functionalized Multiwalled Carbon Nanotubes","volume":"464","author":"Shen","year":"2007","journal-title":"Mater. Sci. Eng. A"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"2438","DOI":"10.1039\/C0CC03639K","article-title":"An Effective Nanostructured Assembly for Ion-Selective Electrodes. An Ionophore Covalently Linked to Carbon Nanotubes for Pb2+ Determination","volume":"47","author":"Parra","year":"2011","journal-title":"Chem. Commun."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"1023","DOI":"10.1016\/j.jinorgbio.2004.02.020","article-title":"Synthesis, Antimicrobial Activity and Chemotherapeutic Potential of Inorganic Derivatives of 2-(4\u2032-Thiazolyl)Benzimidazole{thiabendazole}: X-Ray Crystal Structures of [Cu(TBZH)2Cl]Cl\u00b7H2O\u00b7EtOH and TBZH2NO3 (TBZH=thiabendazole)","volume":"98","author":"Devereux","year":"2004","journal-title":"J. Inorg. Biochem."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"2527","DOI":"10.1351\/pac199466122527","article-title":"Recomendations for Nomenclature of Ion-Selective Electrodes (IUPAC Recommendations 1994)","volume":"66","author":"Buck","year":"1994","journal-title":"Pure Appl. Chem."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"102","DOI":"10.1016\/j.trac.2015.11.004","article-title":"Rational Design of All-Solid-State Ion-Selective Electrodes and Reference Electrodes","volume":"76","author":"Hu","year":"2016","journal-title":"TrAC Trends Anal. Chem."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"141","DOI":"10.2533\/chimia.2011.141","article-title":"Advancing Membrane Electrodes and Optical Ion Sensors","volume":"65","author":"Bakker","year":"2011","journal-title":"Chimia"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"676","DOI":"10.1021\/ac802078z","article-title":"Transduction Mechanism of Carbon Nanotubes in Solid-Contact Ion-Selective Electrodes","volume":"81","author":"Crespo","year":"2009","journal-title":"Anal. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"1851","DOI":"10.1351\/pac200072101851","article-title":"Potentiometric Selectivity Coefficients of Ion-Selective Electrodes Part I. Inorganic Cations (Technical Report)","volume":"72","author":"Umezawa","year":"2000","journal-title":"Pure Appl. Chem."},{"key":"ref_34","first-page":"271","article-title":"Amperometric and Spectrophotometric Determination of Food Additive Thiabendazole (E-233) in Bananas","volume":"5","author":"Volnyanska","year":"2016","journal-title":"Int. J. Adv. Pharm. Biol. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1016\/j.aca.2004.03.010","article-title":"Response Time of Ion-Selective Electrodes: Current Usage versus IUPAC Recommendations","volume":"512","year":"2004","journal-title":"Anal. Chim. Acta"},{"key":"ref_36","unstructured":"Eggins, B.R. (2002). Chemical Sensors and Biosensors, Wiley."}],"container-title":["Sensors"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1424-8220\/22\/10\/3785\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T23:11:26Z","timestamp":1760137886000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1424-8220\/22\/10\/3785"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,5,16]]},"references-count":36,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2022,5]]}},"alternative-id":["s22103785"],"URL":"https:\/\/doi.org\/10.3390\/s22103785","relation":{},"ISSN":["1424-8220"],"issn-type":[{"value":"1424-8220","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,5,16]]}}}