{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,2]],"date-time":"2026-03-02T15:25:56Z","timestamp":1772465156913,"version":"3.50.1"},"reference-count":69,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2023,2,22]],"date-time":"2023-02-22T00:00:00Z","timestamp":1677024000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China","award":["2021ZR130"],"award-info":[{"award-number":["2021ZR130"]}]},{"name":"Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China","award":["2021J01513"],"award-info":[{"award-number":["2021J01513"]}]},{"name":"Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China","award":["22175178"],"award-info":[{"award-number":["22175178"]}]},{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2021ZR130"],"award-info":[{"award-number":["2021ZR130"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2021J01513"],"award-info":[{"award-number":["2021J01513"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["22175178"],"award-info":[{"award-number":["22175178"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["2021ZR130"],"award-info":[{"award-number":["2021ZR130"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["2021J01513"],"award-info":[{"award-number":["2021J01513"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22175178"],"award-info":[{"award-number":["22175178"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Sensors"],"abstract":"<jats:p>In this work, a copper iodine module bearing a coordination polymer (CP) with a formula of [(Cu2I2)2Ce2(INA)6(DMF)3]\u00b7DMF (1, HINA = isonicotinic acid, DMF = N,N\u2019-dimethyl formamide) is presented. The title compound features a three dimensional (3D) structure, in which the {Cu2I2} cluster and {Cu2I2}n chain modules are coordinated by N atoms from a pyridine ring in INA\u2212 ligands, while the Ce3+ ions are bridged by the carboxylic groups of INA\u2212 ligands. More importantly, compound 1 exhibits an uncommon red fluorescence (FL) with a single emission band maximized at 650 nm belonging to near infrared (NIR) luminescence. The temperature dependent FL measurement was applied to investigate the FL mechanism. Remarkably, 1 could be used as a FL sensor to cysteine and the nitro-bearing explosive molecule of trinitropheno (TNP) with high sensitivity, demonstrating its potential FL sensing applications for biothiol and explosive molecules.<\/jats:p>","DOI":"10.3390\/s23052420","type":"journal-article","created":{"date-parts":[[2023,2,22]],"date-time":"2023-02-22T04:33:56Z","timestamp":1677040436000},"page":"2420","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["A Cerium Organic Framework with {Cu2I2} Cluster and {Cu2I2}n Chain Modules: Structure and Fluorescence Sensing Properties"],"prefix":"10.3390","volume":"23","author":[{"given":"Bin","family":"Tan","sequence":"first","affiliation":[{"name":"Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou 350002, China"}]},{"given":"Zi-Wei","family":"Li","sequence":"additional","affiliation":[{"name":"Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou 350002, China"}]},{"given":"Zhao-Feng","family":"Wu","sequence":"additional","affiliation":[{"name":"Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou 350002, China"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3514-216X","authenticated-orcid":false,"given":"Xiao-Ying","family":"Huang","sequence":"additional","affiliation":[{"name":"Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China"},{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou 350002, China"}]}],"member":"1968","published-online":{"date-parts":[[2023,2,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1126","DOI":"10.1021\/cr200101d","article-title":"Luminescent Functional Metal-Organic Frameworks","volume":"112","author":"Cui","year":"2012","journal-title":"Chem. 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