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Due to the dramatic change in electrical resistance and optical transmittance of VO2, it has attracted considerable attention towards the electronic and optical device applications, such as switching devices, memory devices, memristors, smart windows, sensors, actuators, etc. The present review provides an overview of several methods for the synthesis of nanostructured VO2, such as solution-based chemical approaches (sol-gel process and hydrothermal synthesis) and gas or vapor phase synthesis techniques (pulsed laser deposition, sputtering method, and chemical vapor deposition). This review also presents stoichiometry, strain, and doping engineering as modulation strategies of physical properties for nanostructured VO2. In particular, this review describes ultraviolet-visible-near infrared photodetectors, optical switches, and color modulators as optical sensing applications associated with nanostructured VO2 materials. Finally, current research trends and perspectives are also discussed.<\/jats:p>","DOI":"10.3390\/s23156715","type":"journal-article","created":{"date-parts":[[2023,7,28]],"date-time":"2023-07-28T02:10:45Z","timestamp":1690510245000},"page":"6715","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Nanostructured Vanadium Dioxide Materials for Optical Sensing Applications"],"prefix":"10.3390","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6425-6046","authenticated-orcid":false,"given":"Jongwon","family":"Yoon","sequence":"first","affiliation":[{"name":"Department of Energy & Electronic Materials, Surface & Nano Materials Division, Korea Institute of Materials Science, Changwon 51508, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8221-1028","authenticated-orcid":false,"given":"Woong-Ki","family":"Hong","sequence":"additional","affiliation":[{"name":"Center for Scientific Instrumentation, Korea Basic Science Institute, Daejeon 34133, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yonghun","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Energy & Electronic Materials, Surface & Nano Materials Division, Korea Institute of Materials Science, Changwon 51508, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seung-Young","family":"Park","sequence":"additional","affiliation":[{"name":"Center for Scientific Instrumentation, Korea Basic Science Institute, Daejeon 34133, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,7,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1557\/mrc.2017.2","article-title":"Opportunities in vanadium-based strongly correlated electron systems","volume":"7","author":"Brahlek","year":"2017","journal-title":"MRS Commun."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1701147","DOI":"10.1002\/smll.201701147","article-title":"Hydrothermal synthesis of VO2 polymorphs: Advantages, challenges and prospects for the application of energy efficient smart windows","volume":"13","author":"Li","year":"2017","journal-title":"Small"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"231101","DOI":"10.1063\/5.0027690","article-title":"Synthesis of vanadium dioxide thin films and nanostructures","volume":"128","author":"Devthade","year":"2020","journal-title":"J. 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