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Its surface terminations are confined by the adjacent MXene layers, and form the 2D planar space with symmetrical surfaces, which is similar to a 2D nanoreactor that can be utilized and determined MXene\u2019s function. Based on the working principle, surface and interface play critical roles in the ion intercalation, physical\/chemical adsorption, and chemical reaction process, and show significant effects on MXene\u2019s properties and functions. Although there have been some reviews on MXene, less attention has been paid to the underlying principle of the involved surface chemistry, controllable design, and resultant properties. Herein, the regulation methods, characterization techniques, and the effects on properties of MXene surface terminations were summarized to understand the surface effects, and the relationship between the terminations and properties. We expected this review can offer the route for a series of ongoing studies to address the MXene surface environment and the guidelines for MXene\u2019s application.<\/jats:p>","DOI":"10.3390\/sym14112232","type":"journal-article","created":{"date-parts":[[2022,10,24]],"date-time":"2022-10-24T11:53:55Z","timestamp":1666612435000},"page":"2232","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":236,"title":["Surface Terminations of MXene: Synthesis, Characterization, and Properties"],"prefix":"10.3390","volume":"14","author":[{"given":"Mengrao","family":"Tang","sequence":"first","affiliation":[{"name":"Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, The Joint Laboratory of MXene Materials, Jilin Normal University, Changchun 130103, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaming","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, The Joint Laboratory of MXene Materials, Jilin Normal University, Changchun 130103, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, The Joint Laboratory of MXene Materials, Jilin Normal University, Changchun 130103, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjuan","family":"Han","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, The Joint Laboratory of MXene Materials, Jilin Normal University, Changchun 130103, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shichong","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, The Joint Laboratory of MXene Materials, Jilin Normal University, Changchun 130103, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming","family":"Lu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, The Joint Laboratory of MXene Materials, Jilin Normal University, Changchun 130103, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6414-7015","authenticated-orcid":false,"given":"Wei","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials MOE, School of Materials Science & Engineering, Jilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy Materials, Electron Microscopy Center, and International Center of Future Science, Jilin University, Changchun 130012, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haibo","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, The Joint Laboratory of MXene Materials, Jilin Normal University, Changchun 130103, China"},{"name":"School of Optoelectronic Science, Changchun College of Electronic Technology, Changchun 130114, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2022,10,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"6666","DOI":"10.1039\/D0CS00175A","article-title":"Emerging 2D MXenes for Supercapacitors: Status, Challenges and Prospects","volume":"49","author":"Hu","year":"2020","journal-title":"Chem. 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