{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T01:25:31Z","timestamp":1760232331077,"version":"build-2065373602"},"reference-count":21,"publisher":"MDPI AG","issue":"11","license":[{"start":{"date-parts":[[2022,11,2]],"date-time":"2022-11-02T00:00:00Z","timestamp":1667347200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Symmetry"],"abstract":"<jats:p>Organic fluorescent materials are widely applied in different important fields, such as light-emitting display, explosive detection, molecular imprinting, and so on, because of their low cost, easy functionalization, and large-scale fabrication. In this work, we designed and synthesized a new kind of organic fluorescent polysulfate composite material through post-sulfonation sulfur-fluorine exchange polymerization (a new kind of click chemistry) by symmetric molecular. Sulfur-fluorine exchange polymerization: symmetrical structure SO2F\u2212R1\u2212SO2F molecular reacted with symmetrical OH\u2212R2\u2212OH molecular through nucleophilic reaction in the presence of inorganic base. The polysulfate material was further modified by ClSO3H to get PSE\u2212SO3H materials. Tb3+ was highly dispersed on PSE\u2212SO3H to afford organic-inorganic hybrid fluorescent materials through the conventional coordination chemistry method. The emission wavelength of the organic-inorganic hybrid fluorescent polymer PSE\u2212SO3H\u2212Tb3+ was between 475 and 685 nm, the quantum yield reached 1.18%, and fluorescence lifetime lasted for 730.168 us, with the pure green light emission and long light-emitting lifetime. The fluorescence film was prepared through phase transformation method by the fluorescent polymer material PSE\u2212SO3H\u2212Tb3+. The film has the strong stability property in different pH conditions (pH 1~13). Thus, this kind of organic fluorescent polysulfate composite material may have certain prospects application in terms of detection and luminescence in extreme chemical environments in the future.<\/jats:p>","DOI":"10.3390\/sym14112293","type":"journal-article","created":{"date-parts":[[2022,11,2]],"date-time":"2022-11-02T03:44:17Z","timestamp":1667360657000},"page":"2293","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Fluorescent Composites Prepared of Tb3+ and Sulfonated Sulfate Polymer Constructed through Post-Sulfonation Sulfur-Fluorine Exchange Polymerization by Symmetric Molecular"],"prefix":"10.3390","volume":"14","author":[{"given":"Fuchong","family":"Li","sequence":"first","affiliation":[{"name":"School of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Special Function Materials and Structure Design, Institute of National Nuclear Industry, Frontiers Science Center for Rare Isotope, School of Nuclear Science and Technology, Ministry of Education, Lanzhou University, Lanzhou 730000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yang","family":"Gao","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li","family":"Tian","sequence":"additional","affiliation":[{"name":"School of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Junhong","family":"Guo","sequence":"additional","affiliation":[{"name":"School of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jinfeng","family":"Cui","sequence":"additional","affiliation":[{"name":"School of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Baoping","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,2]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2004","DOI":"10.1002\/1521-3773(20010601)40:11<2004::AID-ANIE2004>3.0.CO;2-5","article-title":"Click Chemistry: Diverse Chemical Function from a Few Good Reactions","volume":"40","author":"Hartmuth","year":"2001","journal-title":"Angew. 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