{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T02:43:11Z","timestamp":1778035391420,"version":"3.51.4"},"reference-count":60,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2024,1,24]],"date-time":"2024-01-24T00:00:00Z","timestamp":1706054400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Australian Research Council (ARC) Discovery Projects","award":["DP180103238"],"award-info":[{"award-number":["DP180103238"]}]},{"name":"Australian Research Council (ARC) Discovery Projects","award":["DP220102219"],"award-info":[{"award-number":["DP220102219"]}]},{"name":"Australian Research Council (ARC) Discovery Projects","award":["102018"],"award-info":[{"award-number":["102018"]}]},{"name":"Australian Research Council (ARC) Discovery Projects","award":["CE170100012"],"award-info":[{"award-number":["CE170100012"]}]},{"name":"National Heart Foundation Australia","award":["DP180103238"],"award-info":[{"award-number":["DP180103238"]}]},{"name":"National Heart Foundation Australia","award":["DP220102219"],"award-info":[{"award-number":["DP220102219"]}]},{"name":"National Heart Foundation Australia","award":["102018"],"award-info":[{"award-number":["102018"]}]},{"name":"National Heart Foundation Australia","award":["CE170100012"],"award-info":[{"award-number":["CE170100012"]}]},{"name":"ARC Centre of Excellence in Quantum Computation and Communication Technology","award":["DP180103238"],"award-info":[{"award-number":["DP180103238"]}]},{"name":"ARC Centre of Excellence in Quantum Computation and Communication Technology","award":["DP220102219"],"award-info":[{"award-number":["DP220102219"]}]},{"name":"ARC Centre of Excellence in Quantum Computation and Communication Technology","award":["102018"],"award-info":[{"award-number":["102018"]}]},{"name":"ARC Centre of Excellence in Quantum Computation and Communication Technology","award":["CE170100012"],"award-info":[{"award-number":["CE170100012"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Symmetry"],"abstract":"<jats:p>In addition to graphene, the transition metal dichalcogenides, black phosphorus and multiple other layered materials have undergone immense investigations. Among them, metal thiophosphates (MPSx) have emerged as a promising material for various applications. While several layered metal thiophosphates with general-formula MPSx have been scrutinized extensively, van der Waals (vdW) CdPS3 has been overlooked in the literature. Here we report on the extensive Raman scattering of layered CdPS3, showing structural phase transition at a low temperature. The emergence of multiple new peaks at low frequency and a significant shift in peak position with temperature implied a probable change in crystal symmetry from trigonal D3d to triclinic Ci below the phase transition temperature, TK~180 K. In addition, we also showed a p-type performance of CdPS3 FET fabricated using Au electrodes. This work adds CdPS3 to the list of potential layered materials for energy application.<\/jats:p>","DOI":"10.3390\/sym16020140","type":"journal-article","created":{"date-parts":[[2024,1,24]],"date-time":"2024-01-24T09:57:42Z","timestamp":1706090262000},"page":"140","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Temperature-Dependent Phase Variations in Van Der Waals CdPS3 Revealed by Raman Spectroscopy"],"prefix":"10.3390","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2195-0406","authenticated-orcid":false,"given":"Sharidya","family":"Rahman","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering, Monash University, Melbourne 3800, Australia"},{"name":"ARC Centre of Excellence in Exciton Science, Monash University, Melbourne 3800, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hieu","family":"Ngyuen","sequence":"additional","affiliation":[{"name":"School of Engineering, College of Engineering and Computer Science, The Australian National University, Canberra 2601, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daniel","family":"Macdonald","sequence":"additional","affiliation":[{"name":"School of Engineering, College of Engineering and Computer Science, The Australian National University, Canberra 2601, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuerui","family":"Lu","sequence":"additional","affiliation":[{"name":"School of Engineering, College of Engineering and Computer Science, The Australian National University, Canberra 2601, Australia"},{"name":"Centre for Quantum Computation and Communication Technology, School of Engineering, Australian National University, Canberra 2601, Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,1,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"17033","DOI":"10.1038\/natrevmats.2017.33","article-title":"2D transition metal dichalcogenides","volume":"2","author":"Manzeli","year":"2017","journal-title":"Nat. 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