{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,19]],"date-time":"2026-01-19T06:46:30Z","timestamp":1768805190709,"version":"3.49.0"},"reference-count":219,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2025,2,14]],"date-time":"2025-02-14T00:00:00Z","timestamp":1739491200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Symmetry"],"abstract":"<jats:p>The analysis of natural and artificial chiral compounds is vital wherever the nuances in the three-dimensional structure are decisive for the possibility of their further use, e.g., as pharmaceuticals or catalysts. The qualitative determination of the structure of a chiral entity requires either an anomalous scattering of X-ray radiation or chiroptical techniques, of which electronic circular dichroism (ECD) is one of the most useful. Chiroptical sensing that uses stereodynamic probes remains one of the remedies for the problem of the lack of a suitable chromophore in the molecules of the chiral compound. A covalent or non-covalent binding of an ECD-silent chiral molecule (the inducer) to the UV-active chromophoric system (chiroptical probe) led to obtaining complex ECD active at a given spectral region. The transfer of structural information from a permanently chiral inducer molecule to the structurally labile chromophoric system of the probe results in adjusting the latter\u2019s structure to the chiral environment. This contribution focuses on some fundamental aspects of chirality sensing using conformationally labile probes. It discusses the mechanism of action of arbitrarily chosen stereodynamic chirality sensors, with particular emphasis on probes based on di- and triarylmethyl derivatives and biphenyl and its congeners.<\/jats:p>","DOI":"10.3390\/sym17020293","type":"journal-article","created":{"date-parts":[[2025,2,14]],"date-time":"2025-02-14T11:14:41Z","timestamp":1739531681000},"page":"293","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Dynamic Point-to-Helical and Point-to-Axial Chirality Transmission and Induction of Optical Activity in Multichromophoric Systems: Basic Principles and Relevant Applications in Chirality Sensing"],"prefix":"10.3390","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3249-6306","authenticated-orcid":false,"given":"Tomasz","family":"M\u0105dry","sequence":"first","affiliation":[{"name":"Department of Computational Biology of Non-Coding RNA, Institute of Bioorganic Chemistry Polish Academy of Sciences, Noskowskiego 12\/14, 61-704 Poznan, Poland"}]},{"given":"Jadwiga","family":"Gajewy","sequence":"additional","affiliation":[{"name":"Department of Metalorganic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznanskiego 8, 61-614 Poznan, Poland"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7830-4560","authenticated-orcid":false,"given":"Marcin","family":"Kwit","sequence":"additional","affiliation":[{"name":"Department of Stereochemistry, Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznanskiego 8, 61-614 Poznan, Poland"}]}],"member":"1968","published-online":{"date-parts":[[2025,2,14]]},"reference":[{"key":"ref_1","unstructured":"Berg, J.M., Tymoczko, J.L., and Stryer, L. 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