{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,3]],"date-time":"2026-03-03T16:27:32Z","timestamp":1772555252254,"version":"3.50.1"},"reference-count":333,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2025,3,13]],"date-time":"2025-03-13T00:00:00Z","timestamp":1741824000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Japan Society for the Promotion of Science (JSPS)\u2013KAKENHI","award":["16655046"],"award-info":[{"award-number":["16655046"]}]},{"name":"Japan Society for the Promotion of Science (JSPS)\u2013KAKENHI","award":["22350052"],"award-info":[{"award-number":["22350052"]}]},{"name":"Japan Society for the Promotion of Science (JSPS)\u2013KAKENHI","award":["FY2009"],"award-info":[{"award-number":["FY2009"]}]},{"DOI":"10.13039\/501100012020","name":"the Sekisui Integrated Research Co. (SRI)","doi-asserted-by":"publisher","award":["16655046"],"award-info":[{"award-number":["16655046"]}],"id":[{"id":"10.13039\/501100012020","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012020","name":"the Sekisui Integrated Research Co. (SRI)","doi-asserted-by":"publisher","award":["22350052"],"award-info":[{"award-number":["22350052"]}],"id":[{"id":"10.13039\/501100012020","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012020","name":"the Sekisui Integrated Research Co. (SRI)","doi-asserted-by":"publisher","award":["FY2009"],"award-info":[{"award-number":["FY2009"]}],"id":[{"id":"10.13039\/501100012020","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Japan Science and Technology Agency (JST)","award":["16655046"],"award-info":[{"award-number":["16655046"]}]},{"name":"Japan Science and Technology Agency (JST)","award":["22350052"],"award-info":[{"award-number":["22350052"]}]},{"name":"Japan Science and Technology Agency (JST)","award":["FY2009"],"award-info":[{"award-number":["FY2009"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Symmetry"],"abstract":"<jats:p>Since the 1960s, theorists have claimed that the electroweak force, which unifies parity-conserving electromagnetic and parity-violating weak nuclear forces, induces tiny parity-violating energy differences (10\u221210\u201310\u221221 eV) between mirror-image molecules. This study reports the dual mirror-symmetry-breaking and second-order phase transition characteristics of mirror-symmetric 73-helical poly(di-n-butylsilane) in n-alkanes under static (non-stirring) conditions. In particular, n-dodecane-h26 significantly enhances the circular dichroism (CD) and circularly polarized luminescence (CPL) spectra. A new (\u2212)-CD band emerges at 299 nm below TC1 ~ 105 \u00b0C, with a helix\u2013helix transition at TC2 ~ 28 \u00b0C, and exhibits gabs = +1.3 \u00d7 10\u22122 at \u221210 \u00b0C. Synchronously, the CPL band at 340 nm exhibiting glum = \u22120.7 \u00d7 10\u22122 at 60 \u00b0C inverts to glum = +2.0 \u00d7 10\u22122 at 0 \u00b0C. Interestingly, clockwise and counterclockwise stirring of the mixture induced non-mirror-image CD spectra. n-Dodecane-d26 weakens the gabs values by an order of magnitude, and oppositely signed CD and a lower TC1 of ~45 \u00b0C are observed. The notable H\/D isotope effect suggests that the CH3 termini of the polysilane and n-dodecane-h26, which comprise a three identical nuclear spin-1\/2 system in a triple-well potential, effectively work as unidirectional hindered rotors due to the handedness of nuclear-spin-dependent parity-violating universal forces. This is supported by the (\u2212)-sign vibrational CD bands in the symmetric and asymmetric bending modes of the CH3 group in n-dodecane-h26.<\/jats:p>","DOI":"10.3390\/sym17030433","type":"journal-article","created":{"date-parts":[[2025,3,13]],"date-time":"2025-03-13T12:06:59Z","timestamp":1741867619000},"page":"433","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Nuclear-Spin-Dependent Chirogenesis: Hidden Symmetry Breaking of Poly(di-n-butylsilane) in n-Alkanes"],"prefix":"10.3390","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3139-9478","authenticated-orcid":false,"given":"Michiya","family":"Fujiki","sequence":"first","affiliation":[{"name":"Graduate School of Advanced Science and Technology, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama, Ikoma 630-0192, Nara, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Takashi","family":"Mori","sequence":"additional","affiliation":[{"name":"Graduate School of Advanced Science and Technology, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama, Ikoma 630-0192, Nara, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Julian R.","family":"Koe","sequence":"additional","affiliation":[{"name":"Department of Natural Sciences, International Christian University (ICU), 3-10-2 Osawa, Mitaka 181-8585, Tokyo, Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0167-2610","authenticated-orcid":false,"given":"Mohamed Mehawed","family":"Abdellatif","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University (TMU), 1-1 Minami-Osawa, Hachioji 192-0397, Tokyo, Japan"},{"name":"Chemistry of Tanning Materials and Leather Technology Department, Chemical Industries Research Institute, National Research Centre (NRC), 33 El Buhouth St., Dokki, Giza 12622, BP, Egypt"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2025,3,13]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"108","DOI":"10.1038\/scientificamerican0190-108","article-title":"The handedness of the universe","volume":"262","author":"Hegstrom","year":"1990","journal-title":"Sci. Am."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1007\/BF00928890","article-title":"Comparative analysis of the role of statistical fluctuations and factor of advantage (parity nonconservation) in the origins of optical activity","volume":"13","author":"Morozov","year":"1983","journal-title":"Orig. Life"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1063\/1.881264","article-title":"Handedness, Origin of life and evolution","volume":"44","author":"Avetisov","year":"1991","journal-title":"Phys. Today"},{"key":"ref_4","unstructured":"Mason, S.F. (1982). Chapter 11: Chiral energy discrimination. Molecular Optical Activity and the Chiral Discriminations, Cambridge University Press."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"1091","DOI":"10.1080\/00268978400102881","article-title":"The parity-violating energy difference between enantiomeric molecules","volume":"53","author":"Mason","year":"1984","journal-title":"Mol. Phys."},{"key":"ref_6","first-page":"45","article-title":"The electroweak origin of biomolecular handedness","volume":"397","author":"Mason","year":"1985","journal-title":"Proc. R. Soc. A Math. Phys. Sci."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"347","DOI":"10.1039\/cs9881700347","article-title":"Biomolecular homochirality","volume":"17","author":"Mason","year":"1988","journal-title":"Chem. Soc. Rev."},{"key":"ref_8","unstructured":"Mason, S.F. (1991). Chemical Evolution: Origin of the Elements, Molecules, and Living Systems, Clarendon."},{"key":"ref_9","doi-asserted-by":"crossref","unstructured":"Janoschek, R. (1991). Chapter 1: Parity violation in atomic physics. Chirality: From Weak Bosons to the \u03b1\u2013Helix, Springer.","DOI":"10.1007\/978-3-642-76569-8_1"},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Janoschek, R. (1991). Chapter 2: Theories on the origin of biomolecular homochirality. Chirality: From Weak Bosons to the \u03b1\u2013Helix, Springer.","DOI":"10.1007\/978-3-642-76569-8_2"},{"key":"ref_11","unstructured":"Gardner, M. (1995). The New Ambidextrous Universe: Symmetry and Asymmetry from Mirror Reflections to Superstrings, Dover. [3rd ed.]."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1016\/S1049-250X(02)80010-6","article-title":"The chirality of biomolecules","volume":"48","author":"Compton","year":"2002","journal-title":"Adv. Atom. Mol. Opt. Phys."},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Barron, L. (2004). Molecular Light Scattering and Optical Activity, Cambridge University Press. [2nd ed.].","DOI":"10.1017\/CBO9780511535468"},{"key":"ref_14","doi-asserted-by":"crossref","unstructured":"Wagni\u00e8re, G.H. (2007). On Chirality and the Universal Asymmetry: Reflections on Image and Mirror Image, Wiley-VCH.","DOI":"10.1002\/9783906390598"},{"key":"ref_15","unstructured":"Guijarro, A., and Yus, M. (2008). The Origin of Chirality in the Molecules of Life: A Revision from Awareness to the Current Theories and Perspectives of this Unsolved Problem, RSC."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1016\/0009-2614(86)80098-7","article-title":"On the measurement of the parity violating energy difference between enantiomers","volume":"132","author":"Quack","year":"1986","journal-title":"Chem. Phys. Lett."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"4618","DOI":"10.1002\/anie.200290005","article-title":"How important is parity violation for molecular and biomolecular chirality?","volume":"41","author":"Quack","year":"2002","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"741","DOI":"10.1146\/annurev.physchem.58.032806.104511","article-title":"High-resolution spectroscopic studies and theory of parity violation in chiral molecules","volume":"59","author":"Quack","year":"2008","journal-title":"Annu. Rev. Phys. Chem."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"10598","DOI":"10.1039\/D2SC01323A","article-title":"Perspectives on parity violation in chiral molecules: Theory, spectroscopic experiment and biomolecular homochirality","volume":"13","author":"Quack","year":"2022","journal-title":"Chem. Sci."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"3436","DOI":"10.1039\/D1CS01179K","article-title":"Possible chemical and physical scenarios towards biological homochirality","volume":"51","author":"Sallembien","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"669","DOI":"10.1002\/1521-3927(20010601)22:9<669::AID-MARC669>3.0.CO;2-0","article-title":"Experimental tests of parity violation at helical polysilylene level","volume":"22","author":"Fujiki","year":"2001","journal-title":"Macromol. Rapid Commun."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"271","DOI":"10.1002\/tcr.200900018","article-title":"Mirror symmetry breaking of silicon polymers\u2014From weak bosons to artificial helix","volume":"9","author":"Fujiki","year":"2009","journal-title":"Chem. Rec."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"1625","DOI":"10.3390\/sym2031625","article-title":"Mirror symmetry breaking in helical polysilanes: Preference between left and right of chemical and physical origin","volume":"2","author":"Fujiki","year":"2010","journal-title":"Symmetry"},{"key":"ref_24","doi-asserted-by":"crossref","unstructured":"Borovkov, V., and Aav, R. (2023). Chapter 1: Chirogenesis in parity violation and weak forces. Chirogenesis in Chemical Science, World Scientific.","DOI":"10.1142\/9789811259227_0001"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1086\/304123","article-title":"Measuring polarization in the cosmic microwave background","volume":"482","author":"Seljuk","year":"1997","journal-title":"Atrophys. J."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"772","DOI":"10.1038\/nature01269","article-title":"Detection of polarization in the cosmic microwave background using DASI","volume":"420","author":"Kovac","year":"2002","journal-title":"Nature"},{"key":"ref_27","unstructured":"National Research Council, Division on Engineering, Physical Sciences, Board on Physics, and Committee on the Physics of the Universe (2003). Connecting Quarks with the Cosmos: Eleven Science Questions for the New Century, National Academic Press."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"221301","DOI":"10.1103\/PhysRevLett.125.221301","article-title":"New extraction of the cosmic birefringence from the Planck 2018 polarization Data","volume":"125","author":"Minami","year":"2020","journal-title":"Phys. Rev. Lett."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1038\/s42254-022-00452-4","article-title":"New physics from the polarised light of the cosmic microwave background","volume":"4","author":"Komatsu","year":"2022","journal-title":"Nat. Rev. Phys."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"5701","DOI":"10.1093\/mnras\/stad1062","article-title":"Measurement of parity-odd modes in the large-scale 4-point correlation function of Sloan digital survey baryon oscillation spectroscopic survey twelfth data release CMASS and LOWZ galaxies","volume":"522","author":"Hou","year":"2023","journal-title":"Mon. Not. R. Astron. Soc."},{"key":"ref_31","unstructured":"(2025, January 20). Standard Model. Available online: https:\/\/en.wikipedia.org\/wiki\/Standard_Model."},{"key":"ref_32","unstructured":"(2025, January 08). Particle Physics. Available online: https:\/\/en.wikipedia.org\/wiki\/Particle_physics."},{"key":"ref_33","unstructured":"(2025, January 19). Beta Decay. Available online: https:\/\/en.wikipedia.org\/wiki\/Beta_decay."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"589","DOI":"10.1038\/s41573-020-0073-9","article-title":"Radiopharmaceutical therapy in cancer: Clinical advances and challenges","volume":"19","author":"Sgouros","year":"2020","journal-title":"Nat. Rev. Drug Discov."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0550-3213(74)90038-8","article-title":"Observation of neutrino-like interactions without muon or electron in the Gargamelle neutrino experiment","volume":"73","author":"Hasert","year":"1974","journal-title":"Nucl. Phys. B"},{"key":"ref_36","doi-asserted-by":"crossref","unstructured":"Schopper, H., and Di Lella, L. (2015). Chapter 7: The discovery of weak neutral currents. 60 Years of CERN Experiments and Discovery, World Scientific.","DOI":"10.1142\/9441"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"130","DOI":"10.1016\/0370-2693(83)90744-X","article-title":"(The UA2 Collaboration). Evidence for Z0\u2192e+e\u2212 at the CERN pp collider","volume":"129","author":"Bagnaia","year":"1983","journal-title":"Phys. Lett. B"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"398","DOI":"10.1016\/0370-2693(83)90188-0","article-title":"(The UA2 Collaboration). Experimental observation of lepton pairs of invariant mass around 95 GeV\/c2 at the CERN SPS collider","volume":"126","author":"Arnison","year":"1983","journal-title":"Phys. Lett. B"},{"key":"ref_39","doi-asserted-by":"crossref","unstructured":"Schopper, H., and Di Lella, L. (2015). Chapter 6: The discovery of the W and Z particles. 60 Years of CERN Experiments and Discovery, World Scientific.","DOI":"10.1142\/9441"},{"key":"ref_40","first-page":"1184","article-title":"Electromagnetic interaction with parity violation","volume":"6","year":"1958","journal-title":"Sov. Phys. JETP"},{"key":"ref_41","first-page":"682","article-title":"Parity nonconservation in the first order in the weak-interaction constant in electron scattering and other effects","volume":"9","year":"1959","journal-title":"Sov. Phys. JETP Lett."},{"key":"ref_42","first-page":"777","article-title":"The effect of weak interaction on the electromagnetic properties of particles","volume":"12","author":"Perelomov","year":"1961","journal-title":"Sov. Phys. JETP"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"B329","DOI":"10.1103\/PhysRev.133.B329","article-title":"Parity nonconservation in nuclei","volume":"133","author":"Michel","year":"1964","journal-title":"Phys. Rev."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"352","DOI":"10.1016\/0370-2693(74)90688-1","article-title":"Neutron optics and weak currents","volume":"50","author":"Stodolsky","year":"1974","journal-title":"Phys. Lett. B"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1016\/0550-3213(82)90287-5","article-title":"Parity violation in threshold neutron scattering","volume":"197","author":"Stodolsky","year":"1982","journal-title":"Nucl. Phys. B"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/0370-2693(74)90656-X","article-title":"Weak neutral currents in atomic physics","volume":"48","author":"Bouchiat","year":"1974","journal-title":"Phys. Lett. B"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"899","DOI":"10.1051\/jphys:019740035012089900","article-title":"Parity violation induced by weak neutral currents in atomic physics","volume":"35","author":"Bouchiat","year":"1974","journal-title":"J. Phys."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"493","DOI":"10.1051\/jphys:01975003606049300","article-title":"Parity violation induced by weak neutral currents in atomic physics. Part II","volume":"36","author":"Bouchiat","year":"1975","journal-title":"J. Phys."},{"key":"ref_49","doi-asserted-by":"crossref","unstructured":"Frois, B., and Bouchiat, M.-A. (1999). Parity Violation in Atoms and Polarized Electron Scattering, World Scientific. Atomic parity violation: An overview.","DOI":"10.1142\/9789814527804"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"1086","DOI":"10.1119\/1.15751","article-title":"Mapping the weak chirality of atoms","volume":"56","author":"Hegstrom","year":"1988","journal-title":"Am. J. Phys."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"528","DOI":"10.1038\/264528a0","article-title":"Search for parity non-conserving optical rotation in atomic bismuth","volume":"264","author":"Baird","year":"1976","journal-title":"Nature"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"319","DOI":"10.1016\/S0065-2199(08)60011-1","article-title":"Parity nonconservation in atoms: Status of theory and experiment","volume":"16","author":"Fortson","year":"1980","journal-title":"Adv. Atom. Mol. Phys."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"358","DOI":"10.1016\/0370-2693(82)90736-5","article-title":"Observation of a parity violation in cesium","volume":"117","author":"Bouchiat","year":"1982","journal-title":"Phys. Lett. B"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"289","DOI":"10.1016\/0370-1573(84)90005-X","article-title":"Atomic parity nonconservation experiments","volume":"113","author":"Fortson","year":"1984","journal-title":"Phys. Rep."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"1351","DOI":"10.1088\/0034-4885\/60\/11\/004","article-title":"Parity violation in atoms","volume":"60","author":"Bouchiat","year":"1997","journal-title":"Rep. Prog. Phys."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"2088","DOI":"10.1103\/PhysRevLett.45.2088","article-title":"First measurement of parity-nonconserving neutron-spin rotation: The tin isotopes","volume":"45","author":"Forte","year":"1980","journal-title":"Phys. Rev. Lett."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/0375-9474(83)90649-8","article-title":"Parity nonconservation in neutron resonances","volume":"398","author":"Alfimenkov","year":"1983","journal-title":"Nucl. Phys. A"},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"2187","DOI":"10.1103\/PhysRevC.44.2187","article-title":"Parity nonconservation in polarized-neutron transmission through 139La","volume":"44","author":"Yuan","year":"1991","journal-title":"Phys. Rev. C"},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"1192","DOI":"10.1103\/PhysRevLett.65.1192","article-title":"Parity nonconservation for neutron resonances in 238U","volume":"65","author":"Crawford","year":"1990","journal-title":"Phys. Rev. Lett."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"445","DOI":"10.1103\/RevModPhys.71.445","article-title":"Parity violation in the compound nucleus","volume":"71","author":"Mitchell","year":"1999","journal-title":"Rev. Mod. Phys."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"015502","DOI":"10.1103\/PhysRevC.64.015502","article-title":"Parity violation in neutron resonances of 117Sn","volume":"64","author":"Smith","year":"2001","journal-title":"Phys. Rev. C"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1016\/0022-5193(66)90110-X","article-title":"A hypothesis for the asymmetric appearance of biomolecules on Earth","volume":"11","author":"Yamagata","year":"1966","journal-title":"J. Theor. Biol."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1007\/BF01732768","article-title":"Some remarks on parity violating effects of intramolecular interactions","volume":"4","author":"Rein","year":"1974","journal-title":"J. Mol. Evol."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/0375-9601(75)90064-X","article-title":"On difference of energy levels of left and right molecules due to weak interactions","volume":"53","author":"Letokhov","year":"1975","journal-title":"Phys. Lett. A"},{"key":"ref_65","first-page":"94","article-title":"Energy difference between right\u2013hand and left-hand molecules, due to parity nonconservation in weak interactions of electrons with nuclei","volume":"25","author":"Saakyan","year":"1977","journal-title":"Sov. Phys. JETP Lett."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1007\/BF00927903","article-title":"Origin of the asymmetry of biomolecules and weak interaction","volume":"8","author":"Keszthelyi","year":"1977","journal-title":"Orig. Life"},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"313","DOI":"10.1016\/0370-2693(78)90030-8","article-title":"Quantum beats in optical activity and weak interactions","volume":"78","author":"Harris","year":"1978","journal-title":"Phys. Lett. B"},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"499","DOI":"10.1016\/0375-9601(79)90647-9","article-title":"Parity non-conserving energy difference between mirror image molecules","volume":"71","author":"Rein","year":"1979","journal-title":"Phys. Lett. A"},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1007\/BF00927030","article-title":"Experimental attempts for the study of the origin of optical activity on earth","volume":"5","author":"Thiemann","year":"1974","journal-title":"Orig. Life"},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"2329","DOI":"10.1063\/1.440383","article-title":"Calculation of the parity nonconverging energy difference between mirror-image molecules","volume":"73","author":"Hegstrom","year":"1980","journal-title":"J. Chem. Phys."},{"key":"ref_71","doi-asserted-by":"crossref","unstructured":"Mason, S.F., and Tranter, G.E. (1983). Energy inequivalence of peptide enantiomers from parity non-conservation. J. Chem. Soc. Chem. Commun., 117\u2013119.","DOI":"10.1039\/c39830000117"},{"key":"ref_72","doi-asserted-by":"crossref","unstructured":"Tranter, G.E. (1986). Preferential stabilization of the D-sugar series by the parity-violating weak interactions. J. Chem. Soc. Chem. Commun., 60\u201361.","DOI":"10.1039\/c39860000060"},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"739","DOI":"10.1080\/00268978800100523","article-title":"Effect of atomic number on parity-violating energy differences between enantiomers","volume":"64","author":"Wiesenfeld","year":"1988","journal-title":"Mol. Phys."},{"key":"ref_74","doi-asserted-by":"crossref","unstructured":"Laerdahl, J.K., Wesendrup, R., and Schwerdtfeger, P. (2000). D- or L-alanine: That is the question. ChemPhysChem, 60\u201362.","DOI":"10.1002\/1439-7641(20000804)1:1<60::AID-CPHC60>3.0.CO;2-M"},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"1293","DOI":"10.1002\/anie.200390333","article-title":"Large parity-violation effects in heavy-metal-containing chiral compounds","volume":"42","author":"Schwerdtfeger","year":"2003","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"2218","DOI":"10.1039\/b504212g","article-title":"Recent experimental and theoretical developments towards the observation of parity violation (PV) effects in molecules by spectroscopy","volume":"3","author":"Crassous","year":"2005","journal-title":"Org. Biomol. Chem."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"10011","DOI":"10.1021\/acs.jpclett.2c02434","article-title":"Toward detection of the molecular parity violation in chiral Ru(acac)3 and Os(acac)3","volume":"13","author":"Fiechter","year":"2022","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1021\/cg0200154","article-title":"Asymmetric synthesis of optically active sodium chlorate and bromate crystals","volume":"2","author":"Pagni","year":"2002","journal-title":"Cryst. Grow. Des."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0009-2614(89)80001-6","article-title":"The search for large parity-violating energy differences between enantiomers","volume":"163","author":"Macdermott","year":"1989","journal-title":"Chem. Phys. Lett."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1016\/j.chemphys.2004.06.017","article-title":"A proposed experiment to measure the parity-violating energy difference between enantiomers from the optical rotation of chiral ammonia-like \u201ccat\u201d molecules","volume":"305","author":"MacDermott","year":"2004","journal-title":"Chem. Phys."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"764","DOI":"10.1002\/chir.22076","article-title":"Chiroptical signatures of life and fundamental physics","volume":"24","author":"Macdermott","year":"2012","journal-title":"Chirality"},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"240","DOI":"10.1016\/S0009-2614(98)00108-0","article-title":"On the stabilization of natural L-enantiomers of \u03b1-amino acids via parity-violating effects","volume":"286","author":"Zanasi","year":"1998","journal-title":"Chem. Phys. Lett."},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"3382","DOI":"10.1103\/PhysRevE.59.3382","article-title":"Theoretical results which strengthen the hypothesis of electroweak bioenantioselection","volume":"59","author":"Zanasi","year":"1999","journal-title":"Phys. Rev. E"},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"012110","DOI":"10.1103\/PhysRevA.80.012110","article-title":"Detection of parity violation in chiral molecules by external tuning of electroweak optical activity","volume":"80","author":"Gonzalo","year":"2009","journal-title":"Phys. Rev. A"},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1016\/j.cplett.2010.02.055","article-title":"Towards the detection of parity symmetry breaking in chiral molecules","volume":"489","author":"Gonzalo","year":"2010","journal-title":"Chem. Phys. Lett."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"806","DOI":"10.1039\/C0CP00907E","article-title":"An alternative route to detect parity violating energy differences through Bose\u2013Einstein condensation of chiral molecules","volume":"13","author":"Gonzalo","year":"2011","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"174505","DOI":"10.1063\/1.4707735","article-title":"Dissipative geometric phase and decoherence in parity-violating chiral molecules","volume":"136","year":"2012","journal-title":"J. Chem. Phys."},{"key":"ref_88","doi-asserted-by":"crossref","unstructured":"Mart\u00ednez-Gil, D., Bargue\u00f1o, P., and Miret-Art\u00e9s, S. (2024). The interplay between tunneling and parity violation in chiral molecules. Entropy, 26.","DOI":"10.20944\/preprints202402.0075.v1"},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"042119","DOI":"10.1103\/PhysRevA.96.042119","article-title":"Measuring molecular parity nonconservation using nuclear-magnetic-resonance spectroscopy","volume":"96","author":"Eills","year":"2017","journal-title":"Phys. Rev. A"},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"023258","DOI":"10.1103\/PhysRevResearch.2.023258","article-title":"Molecular parity nonconservation in nuclear spin couplings","volume":"2","author":"Blanchard","year":"2020","journal-title":"Phys. Rev. Res."},{"key":"ref_91","unstructured":"Wilen, S.H., Eliel, E.L., and Mander, L.N. (1994). Stereochemistry of Organic Compounds, Wiley-Interscience."},{"key":"ref_92","unstructured":"Mislow, K. (2003). Introduction to Stereochemistry, Dover."},{"key":"ref_93","doi-asserted-by":"crossref","unstructured":"Berova, N., Polavarapu, P., Nakanishi, K., and Woody, R.W. (2012). Comprehensive Chiroptical Spectroscopy, Volume 1: Instrumentation, Methodologies, and Theoretical Simulations, Wiley.","DOI":"10.1002\/9781118120392"},{"key":"ref_94","doi-asserted-by":"crossref","unstructured":"Berova, N., Polavarapu, P., Nakanishi, K., and Woody, R.W. (2012). Comprehensive Chiroptical Spectroscopy, Volume 2: Applications in Stereochemical Analysis of Synthetic Compounds, Natural Products, and Biomolecules, Wiley.","DOI":"10.1002\/9781118120392"},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"4252","DOI":"10.1073\/pnas.96.8.4252","article-title":"Demonstration of the parity-violating energy difference between enantiomers","volume":"96","author":"Keszthelyi","year":"1999","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1023\/A:1005187416704","article-title":"Parity violation of electroweak force in phase transitions of single crystals of D-and L-alanine and valine","volume":"26","author":"Wang","year":"2000","journal-title":"J. Biol. Phys."},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"289","DOI":"10.1016\/S0301-4622(02)00320-4","article-title":"NMR and parity violation: Low-temperature dependence in 1H CRAMPS and 13C CP\/MAS ssNMR spectra of alanine enantiomer","volume":"103","author":"Wang","year":"2003","journal-title":"Biophys. Chem."},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"12545","DOI":"10.1021\/ja00079a038","article-title":"Chiral surfaces in micelles of enantiomeric N-palmitoyl- and N-stearoylserine","volume":"115","author":"Shinitzky","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"285","DOI":"10.1023\/A:1020535415283","article-title":"Unexpected differences between D-and L-tyrosine lead to chiral enhancement in racemic mixtures","volume":"32","author":"Shinitzky","year":"2002","journal-title":"Orig. Life Evol. Biosph."},{"key":"ref_100","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1039\/B513974K","article-title":"Subtle differences in structural transitions between poly-L- and poly-D-amino acids of equal length in water","volume":"8","author":"Scolnik","year":"2006","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"754","DOI":"10.1002\/chir.20319","article-title":"Ortho\u2013para spin isomers of the protons in the methylene group\u2014Possible implications for protein structure","volume":"18","author":"Shinitzky","year":"2006","journal-title":"Chirality"},{"key":"ref_102","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1002\/chir.20434","article-title":"Intrinsic asymmetries of amino acid enantiomers and their peptides: A possible role in the origin of biochirality","volume":"19","author":"Deamer","year":"2007","journal-title":"Chirality"},{"key":"ref_103","doi-asserted-by":"crossref","first-page":"308","DOI":"10.1002\/chir.22152","article-title":"Space asymmetry as a possible global feature","volume":"25","author":"Shinitzky","year":"2013","journal-title":"Chirality"},{"key":"ref_104","doi-asserted-by":"crossref","first-page":"1","DOI":"10.3390\/e13010001","article-title":"Information storage in liquids with ordered molecular assemblies","volume":"13","author":"Shinitzky","year":"2011","journal-title":"Entropy"},{"key":"ref_105","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1016\/j.jcis.2007.10.063","article-title":"Chirality and helix stability of polyglutamic acid enantiomers","volume":"319","author":"Kodona","year":"2008","journal-title":"J. Colloid Interface. Sci."},{"key":"ref_106","doi-asserted-by":"crossref","unstructured":"Fujiki, M., Okazaki, S., Rahim, N.A.A., Yamada, T., and Nomura, K. (2021). Synchronization in non-mirror-symmetrical chirogenesis: Non-helical \u03c0\u2013conjugated polymers with helical polysilane copolymers in co-colloids. Symmetry, 13.","DOI":"10.3390\/sym13040594"},{"key":"ref_107","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1007\/BF02193624","article-title":"The role of chirality in the origin of life","volume":"33","author":"Salam","year":"1991","journal-title":"J. Mol. Evol."},{"key":"ref_108","doi-asserted-by":"crossref","first-page":"153","DOI":"10.1016\/0370-2693(92)91970-K","article-title":"Chirality, phase transitions and their induction in amino acids","volume":"288","author":"Salam","year":"1992","journal-title":"Phys. Lett. B"},{"key":"ref_109","doi-asserted-by":"crossref","first-page":"234302","DOI":"10.1063\/1.4922542","article-title":"Abnormal difference between the mobilities of left- and right-twisted conformations of C6H12N2 roto-symmetrical molecules at very low temperatures","volume":"142","author":"Gabuda","year":"2015","journal-title":"J. Chem. Phys."},{"key":"ref_110","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1016\/j.ccr.2018.07.008","article-title":"DABCO molecule in the M2(C8H4O4)2\u00b7C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks","volume":"376","author":"Kozlova","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"ref_111","doi-asserted-by":"crossref","first-page":"11505","DOI":"10.1038\/s41598-017-11326-6","article-title":"Thermal properties of Zn2(C8H4O4)2\u00b7C6H12N2 metalorganic framework compound and mirror symmetry violation of dabco molecules","volume":"7","author":"Kozlova","year":"2017","journal-title":"Sci. Rep."},{"key":"ref_112","doi-asserted-by":"crossref","unstructured":"Kozlova, S., Ryzhikov, M., Pishchur, D., and Mirzaeva, I. (2019). Overview of low-temperature heat capacity data for Zn2(C8H4O4)2\u00b7C6H12N2 and the Salam hypothesis. Symmetry, 11.","DOI":"10.3390\/sym11050657"},{"key":"ref_113","doi-asserted-by":"crossref","unstructured":"Fujiki, M., Koe, J.R., Mori, T., and Kimura, Y. (2018). Questions of mirror symmetry at the photoexcited and ground states of non-rigid luminophores raised by circularly polarized luminescence and circular dichroism spectroscopy: Part 1. Oligofluorenes, oligophenylenes, binaphthyls and fused aromatics. Molecules, 23.","DOI":"10.3390\/molecules23102606"},{"key":"ref_114","doi-asserted-by":"crossref","unstructured":"Fujiki, M., Koe, J.R., and Amazumi, S. (2019). Questions of mirror symmetry at the photoexcited and ground states of non-rigid luminophores raised by circularly polarized luminescence and circular dichroism spectroscopy. Part 2: Perylenes, BODIPYs, molecular scintillators, coumarins, rhodamine B, and DCM. Symmetry, 11.","DOI":"10.3390\/sym11030363"},{"key":"ref_115","doi-asserted-by":"crossref","unstructured":"Puneet, P., Singh, S., Fujiki, M., and Nandan, B. (2021). Handed mirror symmetry breaking at the photo-excited state of \u03c0-conjugated rotamers in solutions. Symmetry, 13.","DOI":"10.3390\/sym13020272"},{"key":"ref_116","unstructured":"McGlynn, S.P., Azumi, T., and Kinoshita, M. (1969). Molecular Spectroscopy of The Triplet State, Prentice-Hall."},{"key":"ref_117","unstructured":"Turro, N.J. (1991). Modern Molecular Photochemistry, University Science Books."},{"key":"ref_118","doi-asserted-by":"crossref","first-page":"109","DOI":"10.6028\/jres.075A.010","article-title":"Table of spin-orbit energies for p-electrons in neutral atomic (core) np configurations","volume":"75","author":"Matin","year":"1971","journal-title":"J. Res. Natl. Bur. Stand. A Phys. Chem."},{"key":"ref_119","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1016\/j.adt.2005.04.001","article-title":"Table of nuclear magnetic dipole and electric quadruple moments","volume":"90","author":"Stone","year":"2014","journal-title":"At. Data Nucl. Data Tables"},{"key":"ref_120","first-page":"835","article-title":"P-odd nuclear force\u2014A source of parity violation in atoms","volume":"52","author":"Flambaum","year":"1980","journal-title":"Sov. Phys. JETP"},{"key":"ref_121","first-page":"873","article-title":"Possibility of investigating P- and T-odd nuclear forces in atomic and molecular experiments","volume":"60","author":"Sushkov","year":"1984","journal-title":"Sov. Phys. JETP"},{"key":"ref_122","doi-asserted-by":"crossref","first-page":"507","DOI":"10.1007\/BF01412088","article-title":"P-odd difference of hyperfine structure constants in optical isomers","volume":"322","author":"Khriplovich","year":"1985","journal-title":"Z. Phys. A"},{"key":"ref_123","first-page":"81","article-title":"Anapole moment of a chiral molecule","volume":"47","author":"Khriplovich","year":"1990","journal-title":"Z. Phys."},{"key":"ref_124","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1146\/annurev-nucl-102014-022331","article-title":"Parity and time-reversal violation in atomic systems","volume":"65","author":"Roberts","year":"2015","journal-title":"Annu. Rev. Nucl. Part. Sci."},{"key":"ref_125","doi-asserted-by":"crossref","first-page":"1759","DOI":"10.1126\/science.275.5307.1759","article-title":"Measurement of parity nonconservation and an anapole moment in cesium","volume":"275","author":"Wood","year":"1997","journal-title":"Science"},{"key":"ref_126","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1146\/annurev.nucl.51.101701.132458","article-title":"Atomic parity violation and nuclear anapole moments","volume":"51","author":"Haxton","year":"2001","journal-title":"Annu. Rev. Nucl. Part. Sci."},{"key":"ref_127","doi-asserted-by":"crossref","first-page":"217","DOI":"10.1209\/0295-5075\/5\/3\/006","article-title":"Possible observation of parity nonconservation by high-resolution NMR","volume":"5","author":"Barra","year":"1988","journal-title":"Europhys. Lett."},{"key":"ref_128","doi-asserted-by":"crossref","first-page":"1933","DOI":"10.1088\/0953-4075\/28\/10\/008","article-title":"Parity Violation effects in diatomics","volume":"28","author":"Kozlov","year":"1995","journal-title":"J. Phys. B At. Mol. Opt. Phys."},{"key":"ref_129","doi-asserted-by":"crossref","first-page":"023003","DOI":"10.1103\/PhysRevLett.100.023003","article-title":"Using molecules to measure nuclear spin-dependent parity violation","volume":"100","author":"DeMille","year":"2008","journal-title":"Phys. Rev. Lett."},{"key":"ref_130","first-page":"142501","article-title":"Demonstration of a sensitive method to measure nuclear-spin-dependent parity violation","volume":"120","author":"Ammon","year":"2018","journal-title":"Phys. Rev. A"},{"key":"ref_131","doi-asserted-by":"crossref","first-page":"052828","DOI":"10.1103\/PhysRevA.102.052828","article-title":"Nuclear spin-dependent parity-violating effects in light polyatomic molecules","volume":"102","author":"Hao","year":"2020","journal-title":"Phys. Rev. A"},{"key":"ref_132","doi-asserted-by":"crossref","first-page":"4439","DOI":"10.1103\/PhysRevA.60.4439","article-title":"Fully relativistic ab initio calculations of the energies of chiral molecules including parity-violating weak interactions","volume":"60","author":"Laerdahl","year":"1999","journal-title":"Phys. Rev. A"},{"key":"ref_133","doi-asserted-by":"crossref","first-page":"134307","DOI":"10.1063\/5.0065487","article-title":"Relativistic study of parity-violating nuclear spin-rotation tensors","volume":"155","author":"Aucar","year":"2021","journal-title":"J. Chem. Phys."},{"key":"ref_134","doi-asserted-by":"crossref","first-page":"094306","DOI":"10.1063\/5.0141176","article-title":"Relativistic relationship between nuclear-spin-dependent parity-violating NMR shielding and nuclear spin-rotation tensors","volume":"152","author":"Aucar","year":"2023","journal-title":"J. Chem. Phys."},{"key":"ref_135","doi-asserted-by":"crossref","first-page":"2345","DOI":"10.1080\/00268976.2013.816444","article-title":"Investigation of parity violation in nuclear spin-rotation interaction of fluorooxirane","volume":"111","author":"Fabian","year":"2013","journal-title":"Mol. Phys."},{"key":"ref_136","doi-asserted-by":"crossref","first-page":"042819","DOI":"10.1103\/PhysRevA.103.042819","article-title":"Parity-violation effects in the vibrational spectra of CHFClBr and CDFClBr","volume":"103","author":"Rauhut","year":"2021","journal-title":"Phys. Rev. A"},{"key":"ref_137","doi-asserted-by":"crossref","first-page":"062802","DOI":"10.1103\/PhysRevA.106.062802","article-title":"Parity-violating contributions to nuclear spin-rotation interactions and to NMR shielding constants in tetrahedral molecules","volume":"106","author":"Aucar","year":"2022","journal-title":"Phys. Rev. A"},{"key":"ref_138","doi-asserted-by":"crossref","first-page":"264","DOI":"10.1140\/epjd\/e2015-60284-3","article-title":"Anapole moment of a chiral molecule revisited","volume":"69","author":"Fukuyama","year":"2015","journal-title":"Eur. Phys. J. D"},{"key":"ref_139","doi-asserted-by":"crossref","first-page":"1552","DOI":"10.1002\/jcc.24369","article-title":"Computational study of basis set and electron correlation effects on anapole magnetizabilities of chiral molecules","volume":"37","author":"Zarycz","year":"2016","journal-title":"J. Comput. Chem."},{"key":"ref_140","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1038\/s42005-019-0181-1","article-title":"Nuclear-spin dependent parity violation in optically trapped polyatomic molecules","volume":"2","author":"Norrgard","year":"2019","journal-title":"Commun. Phys."},{"key":"ref_141","doi-asserted-by":"crossref","first-page":"1510","DOI":"10.1126\/science.1197172","article-title":"Toroidal dipolar response in a metamaterial","volume":"330","author":"Kaelberer","year":"2010","journal-title":"Science"},{"key":"ref_142","doi-asserted-by":"crossref","first-page":"6894","DOI":"10.1039\/C4CS00095A","article-title":"Single-molecule toroics in Ising-type lanthanide molecular clusters","volume":"43","author":"Ungur","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"ref_143","doi-asserted-by":"crossref","first-page":"8069","DOI":"10.1038\/ncomms9069","article-title":"Nonradiating anapole modes in dielectric nanoparticles","volume":"6","author":"Miroshnichenko","year":"2015","journal-title":"Nat. Commun."},{"key":"ref_144","doi-asserted-by":"crossref","first-page":"1021","DOI":"10.1038\/nature05088","article-title":"Optical detection of liquid-state NMR","volume":"442","author":"Savukov","year":"2006","journal-title":"Nature"},{"key":"ref_145","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1021\/jz3018539","article-title":"Observation of optical chemical shift by precision nuclear spin optical rotation measurements and calculations","volume":"4","author":"Shi","year":"2013","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_146","doi-asserted-by":"crossref","first-page":"134103","DOI":"10.1063\/1.4869849","article-title":"Nuclear spin circular dichroism","volume":"140","author":"Vaara","year":"2014","journal-title":"J. Chem. Phys."},{"key":"ref_147","doi-asserted-by":"crossref","first-page":"989","DOI":"10.1039\/CT8977100989","article-title":"LXXXVIIL\u2014Racemism and pseudoracemism","volume":"71","author":"Kipping","year":"1897","journal-title":"J. Chem. Soc. Trans."},{"key":"ref_148","doi-asserted-by":"crossref","first-page":"606","DOI":"10.1039\/CT8987300606","article-title":"LXIIL\u2014Enantiomorphism","volume":"73","author":"Kipping","year":"1898","journal-title":"J. Chem. Soc. Trans."},{"key":"ref_149","doi-asserted-by":"crossref","first-page":"1728","DOI":"10.1002\/cphc.202100280","article-title":"Remarkable effects of external magnetic field on circularly polarized luminescence of EuIII(hfa)3 with phosphine chirality","volume":"22","author":"Mishima","year":"2021","journal-title":"ChemPhysChem"},{"key":"ref_150","doi-asserted-by":"crossref","first-page":"243","DOI":"10.1007\/BF01436678","article-title":"Enhancement of P- and T-nonconserving effects in rare-earth atoms","volume":"1","author":"Dzuba","year":"1986","journal-title":"Z. Phys. D"},{"key":"ref_151","doi-asserted-by":"crossref","first-page":"054105","DOI":"10.1103\/PhysRevA.63.054105","article-title":"Parity-violation effect in heliumlike gadolinium and europium","volume":"63","author":"Labzowsky","year":"2001","journal-title":"Phys. Rev. A"},{"key":"ref_152","doi-asserted-by":"crossref","first-page":"11852","DOI":"10.1021\/jp030681v","article-title":"Conformational analysis of poly(di-n-butylsilane), poly(di-n-hexylsilane), and poly(methyl-n-propylsilane) by a rotational isomeric state scheme with molecular dynamics simulations","volume":"107","author":"Sasanuma","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"ref_153","doi-asserted-by":"crossref","first-page":"262","DOI":"10.1021\/ma991435d","article-title":"Unperturbed chain dimensions of poly(di-n-hexylsilane), poly(methyl-n-propylsilane), and poly(di-n-butylsilane)","volume":"34","author":"Kato","year":"2001","journal-title":"Macromolecules"},{"key":"ref_154","doi-asserted-by":"crossref","first-page":"3055","DOI":"10.1021\/ma00197a028","article-title":"Solid-state structures and thermochromism of poly(di-n-butylsilylene) and poly(di-n-pentylsilylene)","volume":"22","author":"Schilling","year":"1989","journal-title":"Macromolecules"},{"key":"ref_155","unstructured":"Zeigler, J.M., and Fearon, F.G. (1989). Chapter 22: Order-disorder transitions and thermochromism of polysilylenes in solution. Silicon-Based Polymer Science: A Comprehensive Resource, ACS."},{"key":"ref_156","doi-asserted-by":"crossref","first-page":"1359","DOI":"10.1021\/cr00096a006","article-title":"Polysilane high polymers","volume":"89","author":"Miller","year":"1989","journal-title":"Chem. Rev."},{"key":"ref_157","doi-asserted-by":"crossref","first-page":"1281","DOI":"10.1021\/ja00186a020","article-title":"Ab initio studies on silicon compounds. 2. On the gauche structure of the parent polysilane","volume":"111","author":"Teramae","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"ref_158","doi-asserted-by":"crossref","first-page":"4363","DOI":"10.1103\/PhysRevB.47.4363","article-title":"Spectra of one-dimensional excitons in polysilanes with various backbone conformations","volume":"47","author":"Tachibana","year":"1993","journal-title":"Phys. Rev. B"},{"key":"ref_159","doi-asserted-by":"crossref","first-page":"3251","DOI":"10.1063\/1.112428","article-title":"Effect of main chain length in the exciton spectra of helical-rod polysilanes as a model of a 5 \u00c5 wide quantum wire","volume":"65","author":"Fujiki","year":"1994","journal-title":"Appl. Phys. Lett."},{"key":"ref_160","doi-asserted-by":"crossref","first-page":"539","DOI":"10.1002\/1521-3927(20010501)22:8<539::AID-MARC539>3.0.CO;2-K","article-title":"Optically active polysilylenes: State-of-the-art chiroptical polymers","volume":"22","author":"Fujiki","year":"2001","journal-title":"Macromol. Rapid Commun."},{"key":"ref_161","doi-asserted-by":"crossref","first-page":"501","DOI":"10.1016\/S0969-806X(03)00218-4","article-title":"The effects of free volumes on charge carrier transport in polysilanes probed by positron annihilation","volume":"68","author":"Seki","year":"2003","journal-title":"Rad. Phys. Chem."},{"key":"ref_162","doi-asserted-by":"crossref","first-page":"3521","DOI":"10.1021\/ja039840e","article-title":"Dynamics of positive charge carriers on Si chains of polysilanes","volume":"126","author":"Seki","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"ref_163","doi-asserted-by":"crossref","first-page":"5231","DOI":"10.1021\/jacs.5b02215","article-title":"Confinement of single polysilane chains in coordination nanospaces","volume":"137","author":"Kitao","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"ref_164","doi-asserted-by":"crossref","first-page":"573","DOI":"10.1021\/ja971406n","article-title":"Gauche, ortho, and anti conformations of saturated A4X10 chains: When will all six conformers exist?","volume":"120","author":"Neumann","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"ref_165","doi-asserted-by":"crossref","first-page":"821","DOI":"10.1021\/ar0001057","article-title":"Conformations of linear chains. Systematics and suggestions for nomenclature","volume":"33","author":"Michl","year":"2000","journal-title":"Acc. Chem. Res."},{"key":"ref_166","doi-asserted-by":"crossref","first-page":"243","DOI":"10.1016\/S0166-1280(00)00416-4","article-title":"The five favored backbone conformations of n-Si4Et10: Cisoid, gauche, ortho, deviant, and transoid","volume":"506","author":"Fogarty","year":"2000","journal-title":"J. Mol. Struct. Theochem."},{"key":"ref_167","doi-asserted-by":"crossref","first-page":"3336","DOI":"10.1021\/ja9938581","article-title":"Helix magic. Thermo-driven chiroptical switching and screw-sense inversion of flexible rod helical polysilylenes","volume":"122","author":"Fujiki","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"ref_168","doi-asserted-by":"crossref","first-page":"6253","DOI":"10.1021\/ja0026509","article-title":"Computing handedness: Quantized and superposed switch and dynamic memory of helical polysilylene","volume":"123","author":"Fujiki","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"ref_169","doi-asserted-by":"crossref","first-page":"4128","DOI":"10.1063\/1.466109","article-title":"J-aggregate formation of a water-soluble porphyrin in acidic aqueous media","volume":"99","author":"Ohno","year":"1993","journal-title":"J. Chem. Phys."},{"key":"ref_170","doi-asserted-by":"crossref","first-page":"2063","DOI":"10.1126\/science.1060835","article-title":"Chiral sign induction by vortices during the formation of mesophases in stirred solutions","volume":"292","author":"Crusats","year":"2001","journal-title":"Science"},{"key":"ref_171","doi-asserted-by":"crossref","first-page":"569","DOI":"10.1039\/B916369G","article-title":"Hydrodynamic effects on chiral induction","volume":"39","author":"Crusats","year":"2010","journal-title":"Chem. Soc. Rev."},{"key":"ref_172","doi-asserted-by":"crossref","first-page":"12474","DOI":"10.1002\/anie.201104708","article-title":"Circularly polarized luminescence of rhodamine B in a supramolecular chiral medium formed by a vortex flow","volume":"50","author":"Okano","year":"2011","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_173","doi-asserted-by":"crossref","first-page":"852","DOI":"10.1002\/asia.201501318","article-title":"Achiral polydialkylsilane aggregates that record stirring direction","volume":"11","author":"Tang","year":"2016","journal-title":"Chem. Asian J."},{"key":"ref_174","doi-asserted-by":"crossref","first-page":"2599","DOI":"10.1038\/s41467-018-05017-7","article-title":"Control over the emerging chirality in supramolecular gels and solutions by chiral microvortices in milliseconds","volume":"9","author":"Sun","year":"2018","journal-title":"Nat. Commun."},{"key":"ref_175","doi-asserted-by":"crossref","first-page":"18454","DOI":"10.1002\/anie.201911366","article-title":"Chiral Supramolecular nanoarchitectures from macroscopic mechanical rotations: Effects on enantioselective aggregation behavior of phthalocyanines","volume":"58","author":"Kuroha","year":"2019","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_176","doi-asserted-by":"crossref","first-page":"895","DOI":"10.1002\/bbpc.19800840913","article-title":"PVT-daten von acetonitril, undecan und dodecan bis 3 kbar und \u201350 \u00b0C. druckabhangigkeit der umwandlungsvolumina, -enthalpien und -entropien","volume":"84","author":"Landau","year":"1980","journal-title":"Ber. Bunsenges. Phys. Chem."},{"key":"ref_177","doi-asserted-by":"crossref","first-page":"1015","DOI":"10.1007\/s10762-010-9678-0","article-title":"Temperature-dependent terahertz spectroscopy of liquid n-alkanes","volume":"31","author":"Laib","year":"2010","journal-title":"J. Infrared Millim. Terahertz Waves"},{"key":"ref_178","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1088\/0953-8984\/6\/21\/011","article-title":"Defects in the rotator and liquid phases of n-alkanes: A study using FTIR and positron annihilation","volume":"6","author":"Naidu","year":"1994","journal-title":"J. Phys. Cond. Matter"},{"key":"ref_179","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1126\/science.177.4047.393","article-title":"More is different\u2014Broken symmetry and the nature of the hierarchical structure of science","volume":"177","author":"Anderson","year":"1972","journal-title":"Science"},{"key":"ref_180","doi-asserted-by":"crossref","first-page":"1189","DOI":"10.1103\/PhysRev.104.1189","article-title":"Bound electron pairs in a degenerate fermi gas","volume":"104","author":"Cooper","year":"1956","journal-title":"Phys. Rev."},{"key":"ref_181","doi-asserted-by":"crossref","first-page":"1175","DOI":"10.1103\/PhysRev.108.1175","article-title":"Theory of superconductivity","volume":"108","author":"Bardeen","year":"1957","journal-title":"Phys. Rev."},{"key":"ref_182","doi-asserted-by":"crossref","first-page":"477","DOI":"10.1103\/PhysRev.78.477","article-title":"Isotope effect in the superconductivity of mercury","volume":"78","author":"Maxwell","year":"1950","journal-title":"Phys. Rev."},{"key":"ref_183","doi-asserted-by":"crossref","first-page":"487","DOI":"10.1103\/PhysRev.78.487","article-title":"Superconductivity of isotopes of mercury","volume":"78","author":"Reynolds","year":"1950","journal-title":"Phys. Rev."},{"key":"ref_184","doi-asserted-by":"crossref","first-page":"114","DOI":"10.1103\/PhysRevLett.11.114","article-title":"Isotope effect in superconductivity","volume":"11","author":"Garland","year":"1963","journal-title":"Phys. Rev. Lett."},{"key":"ref_185","doi-asserted-by":"crossref","unstructured":"Power, P.P. (2003). Silicon, germanium, tin and lead analogues of acetylenes. Chem. Commun., 2091\u20132101.","DOI":"10.1039\/b212224c"},{"key":"ref_186","unstructured":"Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Scalmani, G., Barone, V., Mennucci, B., and Petersson, G.A. (2013). Gaussian09 (Rev.D.01), Gaussian, Inc."},{"key":"ref_187","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1103\/RevModPhys.42.201","article-title":"Tunneling states of defects in solids","volume":"42","author":"Narayanamurtic","year":"1970","journal-title":"Rev. Mod. Phys."},{"key":"ref_188","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1063\/1.1510281","article-title":"The early history of quantum tunneling","volume":"55","author":"Merzbacher","year":"2002","journal-title":"Phys. Today"},{"key":"ref_189","unstructured":"Akagi, K. (2024). Chapter 17: Ultraweak intermolecular interactions in chirogenesis from noncharged CPL-\/CD-silent molecules, oligomers, and polymers endowed with noncharged chiral terpenes, mono-\/polysaccharides, and helical polysilanes. Chiral Luminescence: From Molecules to Materials and Devices, Wiley-VCH."},{"key":"ref_190","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1103\/RevModPhys.73.307","article-title":"Bose-Einstein condensation in the alkali gases: Some fundamental concepts","volume":"73","author":"Leggett","year":"2001","journal-title":"Rev. Mod. Phys."},{"key":"ref_191","doi-asserted-by":"crossref","first-page":"271","DOI":"10.1016\/S0166-1280(09)80015-8","article-title":"Parity-violating energy shift of helical n-alkanes","volume":"312","author":"Kikuchi","year":"1994","journal-title":"J. Mol. Struct. Theochem."},{"key":"ref_192","doi-asserted-by":"crossref","first-page":"2041","DOI":"10.1063\/1.475583","article-title":"Calculation of contributions of one- and two-electron spin-orbit coupling terms to the parity-violating energy shifts for amino acids and helical alkanes","volume":"108","author":"Kiyonaga","year":"1998","journal-title":"J. Chem. Phys."},{"key":"ref_193","doi-asserted-by":"crossref","first-page":"5798","DOI":"10.1063\/1.439102","article-title":"Raman spectra of liquid n-alkanes. II. Longitudinal acoustic modes and the gauche-trans energy difference","volume":"72","author":"Scherer","year":"1980","journal-title":"J. Chem. Phys."},{"key":"ref_194","doi-asserted-by":"crossref","first-page":"3921","DOI":"10.1063\/1.443508","article-title":"The structure of chain molecules in the liquid state: Low frequency Raman spectra of n-alkanes and perfluoro-n-alkanes","volume":"76","author":"Snyder","year":"1982","journal-title":"J. Chem. Phys."},{"key":"ref_195","doi-asserted-by":"crossref","first-page":"602","DOI":"10.1021\/j100155a022","article-title":"Conformation and low-frequency isotropic Raman spectra of the liquid n-alkanes C4\u2013C9","volume":"95","author":"Snyder","year":"1991","journal-title":"J. Phys. Chem."},{"key":"ref_196","doi-asserted-by":"crossref","first-page":"1823","DOI":"10.1039\/FT9928801823","article-title":"Chain conformation from the direct calculation of the Raman spectra of the liquid n-alkanes C12\u2013C20","volume":"88","author":"Snyder","year":"1992","journal-title":"J. Chem. Soc. Faraday Trans."},{"key":"ref_197","doi-asserted-by":"crossref","first-page":"21198","DOI":"10.1021\/jp064811m","article-title":"Conformation of alkanes in the gas phase and pure liquids","volume":"110","author":"Thomas","year":"2006","journal-title":"J. Phys. Chem. B"},{"key":"ref_198","doi-asserted-by":"crossref","first-page":"12724","DOI":"10.1039\/c1cp20618d","article-title":"Raman spectra of long chain hydrocarbons: Anharmonic calculations, experiment and implications for imaging of biomembranes","volume":"13","author":"Pele","year":"2011","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_199","doi-asserted-by":"crossref","first-page":"3139","DOI":"10.1021\/jp027132u","article-title":"Ab initio calculation of entropy and heat capacity of gas-phase n-alkanes using internal rotations","volume":"107","author":"Vansteenkiste","year":"2003","journal-title":"J. Phys. Chem. A"},{"key":"ref_200","doi-asserted-by":"crossref","first-page":"18718","DOI":"10.1021\/jp960413f","article-title":"Quantum chemistry study of conformational energies and rotational energy barriers in n-alkanes","volume":"100","author":"Smith","year":"1996","journal-title":"J. Phys. Chem."},{"key":"ref_201","doi-asserted-by":"crossref","first-page":"1316","DOI":"10.1063\/1.1712087","article-title":"Vibrational study of the chain conformation of the liquid n-paraffins and molten polyethylene","volume":"47","author":"Snyder","year":"1967","journal-title":"J. Chem. Phys."},{"key":"ref_202","doi-asserted-by":"crossref","first-page":"2811","DOI":"10.1063\/1.448280","article-title":"The distribution of conformational disorder in the high-temperature phases of the crystalline n-alkanes","volume":"82","author":"Maroncelli","year":"1980","journal-title":"J. Chem. Phys."},{"key":"ref_203","doi-asserted-by":"crossref","first-page":"6237","DOI":"10.1021\/ja00387a013","article-title":"Nonplanar conformers and the phase behavior of solid n-alkanes","volume":"104","author":"Maroncelli","year":"1982","journal-title":"J. Am. Chem. Soc."},{"key":"ref_204","doi-asserted-by":"crossref","first-page":"3436","DOI":"10.1021\/j100296a066","article-title":"Raman-active bands sensitive to motion and conformation at the chain termini and backbones of alkanes and lipids","volume":"91","author":"Brown","year":"1987","journal-title":"J. Phys. Chem."},{"key":"ref_205","doi-asserted-by":"crossref","first-page":"8241","DOI":"10.1021\/ja00232a049","article-title":"Does the conformation of hydrocarbon chains depend on solvation?","volume":"110","author":"Menger","year":"1988","journal-title":"J. Am. Chem. Soc."},{"key":"ref_206","doi-asserted-by":"crossref","first-page":"4885","DOI":"10.1039\/C4SM00508B","article-title":"Stretching and folding of 2-nanometer hydrocarbon rods","volume":"10","author":"Suhm","year":"2014","journal-title":"Soft Matter"},{"key":"ref_207","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1016\/0001-8716(75)80025-3","article-title":"Dielectric absorption of liquid normal alkanes in the microwave and far infrared regions","volume":"7","author":"Stumper","year":"1975","journal-title":"Adv. Mol. Relax. Proc."},{"key":"ref_208","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1039\/f29827800147","article-title":"Microwave dielectric losses of n-alkanes","volume":"78","author":"Hermiz","year":"1982","journal-title":"J. Chem. Soc. Faraday Trans."},{"key":"ref_209","doi-asserted-by":"crossref","first-page":"751","DOI":"10.1007\/BF02453215","article-title":"Microwave and far-infra-red dielectric absorption in n-alkanes","volume":"2","author":"Vij","year":"1983","journal-title":"II Nuovo Cimento D"},{"key":"ref_210","unstructured":"(2025, March 09). Weinberg angle. Available online: https:\/\/en.wikipedia.org\/wiki\/Weinberg_angle."},{"key":"ref_211","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1103\/PhysRev.57.1006","article-title":"Hindered rotation in methyl alcohol","volume":"57","author":"Koehler","year":"1940","journal-title":"Phys. Rev."},{"key":"ref_212","doi-asserted-by":"crossref","first-page":"A392","DOI":"10.1103\/PhysRev.134.A392","article-title":"Nuclear magnetic relaxation of three spin systems undergoing hindered rotations","volume":"134","author":"Hilt","year":"1964","journal-title":"Phys. Rev."},{"key":"ref_213","doi-asserted-by":"crossref","first-page":"A28","DOI":"10.1103\/PhysRev.134.A28","article-title":"Nuclear spin-lattice relaxation in three-spin molecules","volume":"134","author":"Runnels","year":"1964","journal-title":"Phys. Rev."},{"key":"ref_214","doi-asserted-by":"crossref","first-page":"201","DOI":"10.1103\/PhysRevLett.47.201","article-title":"Coexistence of spin-glass and ferromagnetic orderings","volume":"47","author":"Gabay","year":"1981","journal-title":"Phys. Rev. Lett."},{"key":"ref_215","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/S0009-2614(96)01424-8","article-title":"Competing spin interactions and degenerate frustration for discrete molecular species","volume":"265","author":"Khan","year":"1997","journal-title":"Chem. Phys. Lett."},{"key":"ref_216","doi-asserted-by":"crossref","first-page":"4677","DOI":"10.1039\/b925358k","article-title":"Effects of frustration on magnetic molecules: A survey from Olivier Kahn till today","volume":"39","author":"Schnack","year":"2010","journal-title":"Dalton Trans."},{"key":"ref_217","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1038\/nature08917","article-title":"Spin liquids in frustrated magnets","volume":"464","author":"Balents","year":"2010","journal-title":"Nature"},{"key":"ref_218","doi-asserted-by":"crossref","first-page":"2948","DOI":"10.1021\/jacs.7b00515","article-title":"Spin frustration in the triradical trianion of a naphthalenediimide, molecular triangle","volume":"139","author":"Wu","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"ref_219","doi-asserted-by":"crossref","first-page":"e202310147","DOI":"10.1002\/anie.202310147","article-title":"Spin frustration in organic radicals","volume":"63","author":"Tang","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_220","doi-asserted-by":"crossref","first-page":"2933","DOI":"10.1021\/cr9500848","article-title":"Heidemann. Rotational tunneling and neutron spectroscopy: A compilation","volume":"97","author":"Prager","year":"1997","journal-title":"Chem. Rev."},{"key":"ref_221","doi-asserted-by":"crossref","first-page":"379","DOI":"10.1016\/0584-8539(92)80065-5","article-title":"Rotational tunneling in organic molecules","volume":"48","author":"Horsewill","year":"1992","journal-title":"Spectrochim. Acta A"},{"key":"ref_222","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1016\/S0079-6565(99)00016-3","article-title":"Quantum tunnelling aspects of methyl group rotation studied by NMR","volume":"35","author":"Horsewill","year":"1999","journal-title":"Prog. Nucl. Magn. Res. Spectrosc."},{"key":"ref_223","doi-asserted-by":"crossref","first-page":"2755","DOI":"10.1021\/acsomega.9b03351","article-title":"The methyl torsion in unsaturated compounds","volume":"5","author":"Zachariou","year":"2020","journal-title":"ACS Omega"},{"key":"ref_224","doi-asserted-by":"crossref","first-page":"L525","DOI":"10.1088\/0022-3719\/14\/19\/002","article-title":"The correlation of methyl tunnelling and thermally activated reorientation","volume":"14","author":"Clough","year":"1981","journal-title":"J. Phys. C"},{"key":"ref_225","doi-asserted-by":"crossref","first-page":"L1039","DOI":"10.1088\/0022-3719\/15\/29\/003","article-title":"The correlation of methyl tunnelling and thermally activated reorientation: II","volume":"15","author":"Clough","year":"1982","journal-title":"J. Phys. C"},{"key":"ref_226","doi-asserted-by":"crossref","first-page":"2495","DOI":"10.1088\/0022-3719\/15\/11\/026","article-title":"The rate of thermally activated methyl group rotation in solids","volume":"15","author":"Clough","year":"1982","journal-title":"J. Phys. C"},{"key":"ref_227","first-page":"121","article-title":"The tunnelling methyl group: A probe of the quantum classical transition","volume":"75","author":"Clough","year":"1991","journal-title":"Sci. Progr. Oxford"},{"key":"ref_228","doi-asserted-by":"crossref","first-page":"596","DOI":"10.1515\/zna-1985-0610","article-title":"CH3 rotational tunnelling in alkali acetates and correlation between NMR spin-lattice relaxation and neutron scattering Data","volume":"40","author":"Montjoie","year":"1985","journal-title":"Z. Naturforsch. A"},{"key":"ref_229","doi-asserted-by":"crossref","first-page":"651","DOI":"10.1016\/S0009-2614(00)00288-8","article-title":"Methyl group rotational tunneling in vibrational spectra of crystals at low temperatures","volume":"320","author":"Plazanet","year":"2000","journal-title":"Chem. Phys. Lett."},{"key":"ref_230","doi-asserted-by":"crossref","first-page":"154201","DOI":"10.1063\/5.0149664","article-title":"Mechanistic origins of methyl-driven Overhauser DNP","volume":"158","author":"Perras","year":"2023","journal-title":"J. Chem. Phys."},{"key":"ref_231","doi-asserted-by":"crossref","first-page":"635","DOI":"10.1007\/s00723-021-01375-6","article-title":"Rotational coupling in methyl-tunneling electron spin echo envelope modulation","volume":"53","author":"Jescheke","year":"2022","journal-title":"Appl. Magn. Reson."},{"key":"ref_232","doi-asserted-by":"crossref","first-page":"209","DOI":"10.1016\/0009-2614(87)80924-7","article-title":"Methyl tunneling rotation in the n-alkanes","volume":"142","author":"Abed","year":"1987","journal-title":"Chem. Phys. Lett."},{"key":"ref_233","doi-asserted-by":"crossref","first-page":"716","DOI":"10.1039\/b110091b","article-title":"Inelastic neutron scattering spectra of the transverse acoustic modes of the normal alkanes","volume":"4","author":"Tomkinson","year":"2002","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_234","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/S0301-0104(01)00248-8","article-title":"The low temperature phase transition in octane and its possible generalization to other n-alkanes","volume":"266","author":"Neumann","year":"2011","journal-title":"Chem. Phys."},{"key":"ref_235","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1016\/0009-2614(86)85152-1","article-title":"Rotational dynamics of the methyl group in the 4-methyl pyridine crystal","volume":"125","author":"Soulard","year":"1986","journal-title":"Chem. Phys. Lett."},{"key":"ref_236","doi-asserted-by":"crossref","first-page":"6121","DOI":"10.1088\/0953-8984\/5\/34\/001","article-title":"Symmetry-species conversion in CD3 systems","volume":"5","author":"Diezemann","year":"1993","journal-title":"J. Phys. Cond. Matter"},{"key":"ref_237","doi-asserted-by":"crossref","first-page":"493","DOI":"10.1007\/BF01313358","article-title":"Rotational tunneling dynamics of methyl groups in n-alkane host lattices: An optical investigation and external isotope effect","volume":"95","author":"Orth","year":"1994","journal-title":"Z. Phys. B"},{"key":"ref_238","doi-asserted-by":"crossref","first-page":"174","DOI":"10.1016\/0921-4526(96)00297-9","article-title":"Rotational tunneling of methyl groups of Sc(CH3COO)3 and Sc(CD3COO)3","volume":"226","author":"Takeda","year":"1996","journal-title":"Phys. B"},{"key":"ref_239","doi-asserted-by":"crossref","first-page":"1020","DOI":"10.1063\/1.2389008","article-title":"The physics of rotational tunneling: Hole-burning spectroscopy of methyl groups","volume":"32","author":"Somoza","year":"2006","journal-title":"Low Temp. Phys."},{"key":"ref_240","doi-asserted-by":"crossref","first-page":"700","DOI":"10.1021\/ma60064a017","article-title":"Methyl group tunneling and viscoelastic relaxation in poly(methyl methacrylate)","volume":"11","author":"Williams","year":"1978","journal-title":"Macromolecules"},{"key":"ref_241","doi-asserted-by":"crossref","first-page":"560","DOI":"10.1021\/ma00134a009","article-title":"Rotational motion of the ester methyl group in stereoregular poly(methyl methacrylate): A neutron scattering study","volume":"17","author":"Gabryi","year":"1984","journal-title":"Macromolecules"},{"key":"ref_242","doi-asserted-by":"crossref","first-page":"2350","DOI":"10.1103\/PhysRevLett.80.2350","article-title":"Quantum rotational tunneling of methyl groups in polymers","volume":"80","author":"Colmenero","year":"1998","journal-title":"Phys. Rev. Lett."},{"key":"ref_243","doi-asserted-by":"crossref","first-page":"1147","DOI":"10.1016\/j.progpolymsci.2005.08.001","article-title":"Neutron scattering investigations on methyl group dynamics in polymers","volume":"30","author":"Colmenero","year":"2005","journal-title":"Prog. Polym. Sci."},{"key":"ref_244","doi-asserted-by":"crossref","first-page":"160","DOI":"10.1021\/ma049651w","article-title":"High-resolution incoherent inelastic neutron scattering spectra of polyisobutylene and polyisoprene","volume":"38","author":"Adams","year":"2005","journal-title":"Macromolecules"},{"key":"ref_245","doi-asserted-by":"crossref","first-page":"221","DOI":"10.1366\/10-06036","article-title":"Far-Ultraviolet spectra of n-alkanes and branched alkanes in the liquid phase observed using an attenuated total reflection-far ultraviolet (ATR-FUV) spectrometer","volume":"65","author":"Tachibana","year":"2011","journal-title":"Appl. Spectrosc."},{"key":"ref_246","doi-asserted-by":"crossref","first-page":"11957","DOI":"10.1021\/jp307634m","article-title":"Elucidating electronic transitions from \u03c3 orbitals of liquid n- and branched alkanes by far-ultraviolet spectroscopy and quantum chemical calculations","volume":"116","author":"Morisawa","year":"2012","journal-title":"J. Phys. Chem. A"},{"key":"ref_247","doi-asserted-by":"crossref","first-page":"119549","DOI":"10.1016\/j.saa.2021.119549","article-title":"ATR-far-ultraviolet spectroscopy in the condensed phase\u2014The present status and future perspectives","volume":"253","author":"Ozaki","year":"2021","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_248","doi-asserted-by":"crossref","unstructured":"Lin-Vien, D., Colthup, N.B., Fateley, W.G., and Grasselli, J.G. (1991). Chapter 2: Alkanes. The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules, Elsevier.","DOI":"10.1016\/B978-0-08-057116-4.50008-0"},{"key":"ref_249","unstructured":"Socrates, G. (2001). Chapter 2: Alkane Group Residue: C\u2013H Group. Infrared and Raman Characteristic Group Frequencies: Tables and Charts, Wiley. [3rd ed.]."},{"key":"ref_250","doi-asserted-by":"crossref","first-page":"106582","DOI":"10.1016\/j.jqsrt.2019.106582","article-title":"Experimental and theoretical studies on the absorption spectra of n-dodecane in the IR and VUV regions","volume":"236","author":"Gorai","year":"2019","journal-title":"J. Quant. Spectrosc. Radiat. Transf."},{"key":"ref_251","doi-asserted-by":"crossref","first-page":"16389","DOI":"10.1021\/jp110550t","article-title":"Transmission infrared spectra of CH3, CD3, and C10H21-Ge(111) surfaces","volume":"115","author":"Knapp","year":"2011","journal-title":"J. Phys. Chem. C"},{"key":"ref_252","doi-asserted-by":"crossref","first-page":"1080","DOI":"10.1021\/jp210013g","article-title":"A comparative study of the CD and CH stretching spectral regions of typical surfactants systems using VSFS: Orientation analysis of the terminal CH3 and CD3 groups","volume":"116","author":"Tyrode","year":"2012","journal-title":"J. Phys. Chem. C"},{"key":"ref_253","doi-asserted-by":"crossref","first-page":"8174","DOI":"10.1021\/ja00021a057","article-title":"Mirror-image DNA","volume":"113","author":"Urata","year":"1993","journal-title":"J. Am. Chem. Soc."},{"key":"ref_254","doi-asserted-by":"crossref","first-page":"1445","DOI":"10.1126\/science.1604320","article-title":"Total chemical synthesis of a D-enzyme: The Enantiomers of HIV-1 protease show demonstration of reciprocal chiral substrate specificity","volume":"256","author":"Milton","year":"1992","journal-title":"Science"},{"key":"ref_255","doi-asserted-by":"crossref","first-page":"4002","DOI":"10.1021\/ja00036a073","article-title":"A racemic protein","volume":"114","author":"Zawadzke","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref_256","doi-asserted-by":"crossref","first-page":"11679","DOI":"10.1073\/pnas.1410900111","article-title":"Synthesis and folding of a mirror-image enzyme reveals ambidextrous chaperone activity","volume":"111","author":"Weinstock","year":"2014","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"ref_257","doi-asserted-by":"crossref","first-page":"698","DOI":"10.1038\/nchem.2517","article-title":"A synthetic molecular system capable of mirror-image genetic replication and transcription","volume":"8","author":"Wang","year":"2016","journal-title":"Nat. Chem."},{"key":"ref_258","doi-asserted-by":"crossref","first-page":"1548","DOI":"10.1038\/s41587-021-00969-6","article-title":"Bioorthogonal information storage in L-DNA with a high-fidelity mirror-image Pfu DNA polymerase","volume":"39","author":"Fan","year":"2021","journal-title":"Nat. Biotechnol."},{"key":"ref_259","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1107\/S0907444903027690","article-title":"First look at RNA in L-configuration","volume":"60","author":"Vallazza","year":"2004","journal-title":"Acta Cryst. D"},{"key":"ref_260","doi-asserted-by":"crossref","first-page":"1877","DOI":"10.1261\/rna.564507","article-title":"First experimental evidence for the preferential stabilization of the natural D- over the nonnatural L-configuration in nucleic acids","volume":"13","author":"Bolik","year":"2007","journal-title":"RNA"},{"key":"ref_261","doi-asserted-by":"crossref","first-page":"12535","DOI":"10.1093\/nar\/gkab480","article-title":"Broken symmetry between RNA enantiomers in a crystal lattice","volume":"49","author":"Kiliszek","year":"2021","journal-title":"Nucleic Acids Res."},{"key":"ref_262","doi-asserted-by":"crossref","first-page":"481","DOI":"10.18388\/abp.2020_6914","article-title":"The emergence of biological homochirality","volume":"70","author":"Kiliszek","year":"2023","journal-title":"Acta Biochim. Pol."},{"key":"ref_263","doi-asserted-by":"crossref","first-page":"549","DOI":"10.1016\/0009-2614(73)89026-8","article-title":"Differences in the annihilation of positrons in optical isomers","volume":"23","author":"Garay","year":"1973","journal-title":"Chem. Phys. Lett."},{"key":"ref_264","doi-asserted-by":"crossref","first-page":"6674","DOI":"10.1021\/jp0225673","article-title":"Search for electroweak interactions in amino acid crystals. II. The Salam hypothesis","volume":"107","author":"Sullivan","year":"2003","journal-title":"J. Phys. Chem. A"},{"key":"ref_265","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1107\/S2052252517015573","article-title":"Hydrogen bonds in crystalline D-alanine: Diffraction and spectroscopic evidence for differences between enantiomers","volume":"5","author":"Belo","year":"2018","journal-title":"IUCrJ"},{"key":"ref_266","doi-asserted-by":"crossref","first-page":"654","DOI":"10.1107\/S2052252518007406","article-title":"Comments on \u2018Hydrogen bonds in crystalline D-alanine: Diffraction and spectroscopic evidence for differences between enantiomers\u2019","volume":"5","author":"Macchi","year":"2018","journal-title":"IUCrJ"},{"key":"ref_267","doi-asserted-by":"crossref","first-page":"658","DOI":"10.1107\/S2052252518010321","article-title":"Response to comment on \u2018Hydrogen bonds in crystalline D-alanine: Diffraction and spectroscopic evidence for differences between enantiomers\u2019","volume":"5","author":"Belo","year":"2018","journal-title":"IUCrJ"},{"key":"ref_268","doi-asserted-by":"crossref","first-page":"117279","DOI":"10.1016\/j.molliq.2021.117279","article-title":"Probing physical invariance between enantiomers: The magnetooptical and refractive properties of the simplest chiral amino acid\u2014Alanine","volume":"339","author":"Koralewski","year":"2021","journal-title":"J. Mol. Liq."},{"key":"ref_269","doi-asserted-by":"crossref","first-page":"8202","DOI":"10.1039\/C5CE01180A","article-title":"Can enantiomer ligands produce structurally distinct homochiral MOFs?","volume":"17","author":"Dubey","year":"2015","journal-title":"CrystEngComm"},{"key":"ref_270","doi-asserted-by":"crossref","first-page":"102","DOI":"10.1016\/j.ppnp.2008.08.002","article-title":"Torsion balance experiments: A low-energy frontier of particle physics","volume":"62","author":"Adelberger","year":"2009","journal-title":"Prog. Part. Nucl. Phys."},{"key":"ref_271","doi-asserted-by":"crossref","first-page":"1660010","DOI":"10.1142\/S2010194516600107","article-title":"Searches for the role of spin and polarization in gravity: A five-year update","volume":"40","author":"Ni","year":"2016","journal-title":"Int. J. Mod. Phys. Conf. Ser."},{"key":"ref_272","doi-asserted-by":"crossref","first-page":"025008","DOI":"10.1103\/RevModPhys.90.025008","article-title":"Search for new physics with atoms and molecules","volume":"90","author":"Safronova","year":"2018","journal-title":"Rev. Mod. Phys."},{"key":"ref_273","doi-asserted-by":"crossref","first-page":"1109086","DOI":"10.3389\/fspas.2022.1109086","article-title":"Testing parity symmetry of gravity with gravitational waves","volume":"9","author":"Qiao","year":"2023","journal-title":"Front. Astron. Space Sci."},{"key":"ref_274","doi-asserted-by":"crossref","first-page":"B1542","DOI":"10.1103\/PhysRev.136.B1542","article-title":"Parity, charge conjugation, and time reversal in the gravitational interaction","volume":"136","author":"Leitner","year":"1964","journal-title":"Phys. Rev."},{"key":"ref_275","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1103\/PhysRevLett.36.393","article-title":"Test for C, P, and T nonconservation in gravitation","volume":"36","author":"Dass","year":"1976","journal-title":"Phys. Rev. Lett."},{"key":"ref_276","doi-asserted-by":"crossref","first-page":"1660","DOI":"10.1103\/PhysRevLett.48.1660","article-title":"Tests of parity and time-reversal noninvariance using neutron Interference","volume":"48","author":"Anandan","year":"1982","journal-title":"Phys. Rev. Lett."},{"key":"ref_277","doi-asserted-by":"crossref","first-page":"201101","DOI":"10.1103\/PhysRevLett.90.201101","article-title":"Test of cosmic spatial isotropy for polarized electrons using a rotatable torsion balance","volume":"90","author":"Hou","year":"2003","journal-title":"Phys. Rev. Lett."},{"key":"ref_278","doi-asserted-by":"crossref","first-page":"021603","DOI":"10.1103\/PhysRevLett.97.021603","article-title":"New CP-violation and preferred-frame tests with polarized electrons","volume":"97","author":"Heckel","year":"2006","journal-title":"Phys. Rev. Lett."},{"key":"ref_279","doi-asserted-by":"crossref","first-page":"201801","DOI":"10.1103\/PhysRevLett.115.201801","article-title":"Short-range, spin-dependent interactions of electrons: A probe for exotic pseudo-Goldstone bosons","volume":"115","author":"Terrano","year":"2015","journal-title":"Phys. Rev. Lett."},{"key":"ref_280","doi-asserted-by":"crossref","first-page":"240404","DOI":"10.1103\/PhysRevLett.93.240404","article-title":"Atomic interferometer with amplitude gratings of light and its applications to atom based tests of the equivalence principle","volume":"93","author":"Fray","year":"2004","journal-title":"Phys. Rev. Lett."},{"key":"ref_281","doi-asserted-by":"crossref","first-page":"023005","DOI":"10.1103\/PhysRevLett.113.023005","article-title":"Test of Einstein equivalence principle for 0-Spin and half-integer-spin atoms: Search for spin-gravity coupling effects","volume":"113","author":"Tarallo","year":"2014","journal-title":"Phys. Rev. Lett."},{"key":"ref_282","doi-asserted-by":"crossref","first-page":"15529","DOI":"10.1038\/ncomms15529","article-title":"Quantum test of the equivalence principle for atoms in coherent superposition of internal energy states","volume":"8","author":"Rosi","year":"2016","journal-title":"Nat. Commun."},{"key":"ref_283","doi-asserted-by":"crossref","first-page":"023001","DOI":"10.1103\/PhysRevLett.117.023001","article-title":"Test of the universality of free fall with atoms in different spin orientations","volume":"117","author":"Duan","year":"2016","journal-title":"Phys. Rev. Lett."},{"key":"ref_284","doi-asserted-by":"crossref","first-page":"201401","DOI":"10.1103\/PhysRevLett.130.201401","article-title":"Search for spin-dependent gravitational interactions at earth range","volume":"130","author":"Zhang","year":"2023","journal-title":"Phys. Rev. Lett."},{"key":"ref_285","doi-asserted-by":"crossref","first-page":"231101","DOI":"10.1103\/PhysRevLett.119.231101","article-title":"MICROSCOPE mission: First results of a space test of the equivalence principle","volume":"119","author":"Touboul","year":"2017","journal-title":"Phys. Rev. Lett."},{"key":"ref_286","doi-asserted-by":"crossref","first-page":"121102","DOI":"10.1103\/PhysRevLett.129.121102","article-title":"MICROSCOPE mission: Final results of the test of the equivalence principle","volume":"129","author":"Touboul","year":"2022","journal-title":"Phys. Rev. Lett."},{"key":"ref_287","doi-asserted-by":"crossref","first-page":"261101","DOI":"10.1103\/PhysRevLett.121.261101","article-title":"Test of the equivalence principle with chiral masses using a rotating torsion pendulum","volume":"121","author":"Zhu","year":"2018","journal-title":"Phys. Rev. Lett."},{"key":"ref_288","doi-asserted-by":"crossref","first-page":"102004","DOI":"10.1103\/PhysRevD.78.102004","article-title":"Constraining long-range parity violation in gravitation using high resolution spectroscopy of chiral molecules","volume":"78","year":"2008","journal-title":"Phys. Rev. D"},{"key":"ref_289","doi-asserted-by":"crossref","first-page":"375","DOI":"10.1002\/chir.22439","article-title":"Chirality and gravitational parity violation","volume":"27","year":"2015","journal-title":"Chirality"},{"key":"ref_290","doi-asserted-by":"crossref","first-page":"123004","DOI":"10.1103\/PhysRevLett.125.123004","article-title":"Chiral molecules as sensitive probes for direct detection of P-odd cosmic fields","volume":"125","author":"Gaul","year":"2020","journal-title":"Phys. Rev. Lett."},{"key":"ref_291","doi-asserted-by":"crossref","first-page":"032816","DOI":"10.1103\/PhysRevA.102.032816","article-title":"Parity-nonconserving interactions of electrons in chiral molecules with cosmic fields","volume":"102","author":"Gaul","year":"2020","journal-title":"Phys. Rev. A"},{"key":"ref_292","doi-asserted-by":"crossref","first-page":"637","DOI":"10.1039\/b9nj00733d","article-title":"Limonene magic: Noncovalent molecular chirality transfer leading to ambidextrous circularly polarised luminescent p-conjugated polymers","volume":"34","author":"Kawagoe","year":"2010","journal-title":"New J. Chem."},{"key":"ref_293","doi-asserted-by":"crossref","first-page":"7035","DOI":"10.3390\/molecules18067035","article-title":"Mirror-symmetry-breaking in poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-biphenyl] (PF8P2) is susceptible to terpene chirality, achiral solvents, and mechanical stirring","volume":"18","author":"Fujiki","year":"2013","journal-title":"Molecules"},{"key":"ref_294","doi-asserted-by":"crossref","first-page":"3797","DOI":"10.1073\/pnas.1012293108","article-title":"Molecular vibration-sensing component in Drosophila melanogaster olfaction","volume":"108","author":"Franco","year":"2011","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"ref_295","doi-asserted-by":"crossref","first-page":"20133089","DOI":"10.1098\/rspb.2013.3089","article-title":"Honeybees (Apis mellifera) learn to discriminate the smell of organic compounds from their respective deuterated isotopomers","volume":"281","author":"Gronenberg","year":"2014","journal-title":"Proc. Roy. Soc. B"},{"key":"ref_296","doi-asserted-by":"crossref","first-page":"773","DOI":"10.1093\/chemse\/21.6.773","article-title":"A Spectroscopic mechanism for primary olfactory reception","volume":"21","author":"Turin","year":"1996","journal-title":"Chem. Sens."},{"key":"ref_297","doi-asserted-by":"crossref","first-page":"032724","DOI":"10.1103\/PhysRevE.92.032724","article-title":"Dissipative vibrational model for chiral recognition in olfaction","volume":"92","author":"Tirandaz","year":"2015","journal-title":"Phys. Rev. E"},{"key":"ref_298","unstructured":"Asogwa, C. (2019). Quantum biology: Can we explain olfaction using quantum phenomenon?. arXiv."},{"key":"ref_299","doi-asserted-by":"crossref","first-page":"bbae074","DOI":"10.1093\/bib\/bbae074","article-title":"New classifications for quantum bioinformatics: Q-bioinformatics, QCt-bioinformatics, QCg-bioinformatics, and QCr-bioinformatics","volume":"25","author":"Mokhtari","year":"2024","journal-title":"Brief. Bioinform."},{"key":"ref_300","doi-asserted-by":"crossref","unstructured":"Nafie, L.A. (2011). Vibrational Optical Activity\u2014Principles and Applications, Wiley.","DOI":"10.1002\/9781119976516"},{"key":"ref_301","doi-asserted-by":"crossref","first-page":"489","DOI":"10.1089\/153110703322610609","article-title":"Terahertz circular dichroism spectroscopy: A potential approach to the in situ detection of life\u2019s metabolic and genetic machinery","volume":"3","author":"Xu","year":"2003","journal-title":"Astrobiology"},{"key":"ref_302","doi-asserted-by":"crossref","first-page":"22789","DOI":"10.1021\/jacs.2c04817","article-title":"Terahertz circular dichroism spectroscopy of molecular assemblies, and nanostructures","volume":"144","author":"Choi","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"ref_303","doi-asserted-by":"crossref","first-page":"114001","DOI":"10.1016\/j.sna.2022.114001","article-title":"Enhancing terahertz circular dichroism spectrum of amino acid chiral enantiomers by all-dielectric metasurface","volume":"348","author":"Zhang","year":"2022","journal-title":"Sens. Actuat. A"},{"key":"ref_304","doi-asserted-by":"crossref","first-page":"5959","DOI":"10.1021\/jp000705n","article-title":"Cavity ring-down polarimetry (CRDP): A new scheme for probing circular birefringence and circular dichroism in the gas phase","volume":"104","author":"Wiberg","year":"2000","journal-title":"J. Phys. Chem. A"},{"key":"ref_305","doi-asserted-by":"crossref","first-page":"052127","DOI":"10.1103\/PhysRevA.89.052127","article-title":"Fundamentals of cavity-enhanced polarimetry for parity-nonconserving optical rotation measurements: Application to Xe, Hg, and I","volume":"89","author":"Bougas","year":"2014","journal-title":"Phys. Rev. A"},{"key":"ref_306","doi-asserted-by":"crossref","first-page":"2563","DOI":"10.1063\/1.452059","article-title":"Inelastic incoherent neutron scattering study of the methyl rotation in various methyl halides","volume":"86","author":"Prager","year":"1987","journal-title":"J. Chem. Phys."},{"key":"ref_307","doi-asserted-by":"crossref","first-page":"2513","DOI":"10.1002\/cphc.200700465","article-title":"Thin-film infrared spectroscopy of acetonitrile","volume":"8","author":"Kosower","year":"2007","journal-title":"ChemPhysChem"},{"key":"ref_308","doi-asserted-by":"crossref","first-page":"5994","DOI":"10.1063\/1.452486","article-title":"Coupling of CH stretching and bending vibration of trihalomethanes","volume":"86","author":"Wong","year":"1987","journal-title":"J. Chem. Phys."},{"key":"ref_309","doi-asserted-by":"crossref","first-page":"234501","DOI":"10.1063\/1.4770264","article-title":"Anharmonic coupling of the CH-stretch and CH-bend vibrations of chloroform as studied by near-infrared electroabsorption spectroscopy","volume":"137","author":"Nishida","year":"2012","journal-title":"J. Chem. Phys."},{"key":"ref_310","doi-asserted-by":"crossref","unstructured":"Nolasco, M.M., Coimbra, M.M., Parker, S.F., Vaz, P.D., and Ribeiro-Claro, P.J. (2022). Structural dynamics of chloromethanes through computational spectroscopy: Combining INS and DFT. Molecules, 27.","DOI":"10.3390\/molecules27217661"},{"key":"ref_311","first-page":"1821","article-title":"Internal torsional modes in methyl halogenocarbons studied by inelastic neutron scattering","volume":"72","author":"Ratcliffe","year":"1976","journal-title":"J. Chem. Soc. Faraday Trans. 2 Mol. Chem. Phys."},{"key":"ref_312","doi-asserted-by":"crossref","first-page":"5646","DOI":"10.1021\/jp004001p","article-title":"Internal rotation of the CF3 group in the (trifluoromethyl)anilines: A zero-kinetic-energy pulsed-field-ionization study","volume":"105","author":"Macleod","year":"2001","journal-title":"J. Phys. Chem. A"},{"key":"ref_313","doi-asserted-by":"crossref","first-page":"3947","DOI":"10.1021\/jp056643o","article-title":"CF3 rotation in 3-(trifluoromethyl)phenanthrene: Solid state 19F and 1H NMR relaxation and Bloch-Wangsness-Redfield theory","volume":"110","author":"Beckmann","year":"2006","journal-title":"J. Phys. Chem. A"},{"key":"ref_314","doi-asserted-by":"crossref","first-page":"154308","DOI":"10.1063\/1.4944981","article-title":"1H and 19F spin-lattice relaxation and CH3 or CF3 reorientation in molecular solids containing both H and F atoms","volume":"144","author":"Beckmann","year":"2016","journal-title":"J. Chem. Phys."},{"key":"ref_315","doi-asserted-by":"crossref","first-page":"106656","DOI":"10.1016\/j.jqsrt.2019.106656","article-title":"Disentangling the IR spectra of 2,3,3,3-tetrafluoropropene using an ab initio description of vibrational polyads by means of canonical van Vleck perturbation theory","volume":"239","author":"Charmet","year":"2019","journal-title":"J. Quant. Spectrosc. Radia. Transfer."},{"key":"ref_316","doi-asserted-by":"crossref","first-page":"245","DOI":"10.1016\/0022-2860(84)87221-X","article-title":"Molecular structure of the rotational isomers in short chain n-perfluoroalkanes","volume":"118","year":"1984","journal-title":"J. Mol. Struct."},{"key":"ref_317","doi-asserted-by":"crossref","first-page":"9290","DOI":"10.1021\/jp982769s","article-title":"Photochemical attachment of fluorobutyl moieties on a diamond (110)-oriented surface: A multiple internal reflection infrared spectroscopic (MIRIRS) investigation","volume":"102","author":"Kim","year":"1998","journal-title":"J. Phys. Chem. B"},{"key":"ref_318","doi-asserted-by":"crossref","first-page":"5331","DOI":"10.1021\/ma025645t","article-title":"The source of helicity in perfluorinated N-alkanes","volume":"36","author":"Jang","year":"2003","journal-title":"Macromolecules"},{"key":"ref_319","doi-asserted-by":"crossref","first-page":"834","DOI":"10.1246\/cl.150198","article-title":"An origin of complicated infrared spectra of perfluoroalkyl compounds involving a normal alkyl group","volume":"44","author":"Hasegawa","year":"2015","journal-title":"Chem. Lett."},{"key":"ref_320","doi-asserted-by":"crossref","first-page":"3985","DOI":"10.1021\/acs.jpca.8b11613","article-title":"Raman optical activity on a solid sample: Identification of atropisomers of perfluoroalkyl chains having a helical conformation and no chiral center","volume":"123","author":"Shimoaka","year":"2019","journal-title":"J. Phys. Chem. A"},{"key":"ref_321","doi-asserted-by":"crossref","first-page":"692","DOI":"10.1021\/ma60035a010","article-title":"Dynamics of polymers as structurally disordered systems. Vibrational spectrum and structure of poly(tetrafluoroethylene)","volume":"6","author":"Zerbi","year":"1973","journal-title":"Macromolecules"},{"key":"ref_322","doi-asserted-by":"crossref","first-page":"1684","DOI":"10.1021\/ma00151a007","article-title":"Infrared spectra of amorphous and crystalline poly(tetrafluoro-ethylene)","volume":"18","author":"Starkweather","year":"1985","journal-title":"Macromolecules"},{"key":"ref_323","first-page":"62","article-title":"A molecular model for the helicity of polytetrafluoroethylene (Tefloin\u00ae)","volume":"2","author":"Dixon","year":"1988","journal-title":"Int. J. Supercomput. Appl."},{"key":"ref_324","doi-asserted-by":"crossref","first-page":"735","DOI":"10.1002\/qua.560450620","article-title":"Ab initio study of the influence of aggregation on the infrared spectrum of acetonitrile","volume":"45","author":"Mathieu","year":"1993","journal-title":"Int. J. Quantum Chem."},{"key":"ref_325","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1051\/jphys:0198400450109700","article-title":"Neutron and Raman scattering studies of the methyl dynamics in solid toluene and nitromethane","volume":"45","author":"Cavagnat","year":"1984","journal-title":"J. Phys."},{"key":"ref_326","doi-asserted-by":"crossref","first-page":"911","DOI":"10.1139\/v57-123","article-title":"The infrared and Raman spectra of toluene, toluene-\u03b1-d3, m-xylene, and m-xylene-\u03b1\u03b1\u2019-d6","volume":"35","author":"Wilmshurst","year":"1957","journal-title":"Can. J. Chem."},{"key":"ref_327","doi-asserted-by":"crossref","first-page":"726","DOI":"10.4236\/ajac.2017.811053","article-title":"Traceability of active compounds of essential oils in antimicrobial food packaging using a chemometric method by ATR-FTIR","volume":"8","author":"Valderrama","year":"2017","journal-title":"Am. J. Anal. Chem."},{"key":"ref_328","doi-asserted-by":"crossref","first-page":"5310","DOI":"10.1002\/anie.200352493","article-title":"The origin of solvent-controlled supramolecular chirality switching in a bis(zinc porphyrin) system","volume":"42","author":"Borovkov","year":"2003","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_329","doi-asserted-by":"crossref","first-page":"449","DOI":"10.1021\/ar0302437","article-title":"Origin, control, and application of supramolecular chirogenesis in bisporphyrin-based systems","volume":"37","author":"Borovkov","year":"2004","journal-title":"Acc. Chem. Res."},{"key":"ref_330","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1021\/cr050005k","article-title":"Chirality-sensing supramolecular systems","volume":"108","author":"Hembury","year":"2008","journal-title":"Chem. Rev."},{"key":"ref_331","doi-asserted-by":"crossref","first-page":"184","DOI":"10.3390\/sym2010184","article-title":"Effective supramolecular chirogenesis in ethane-bridged bis-porphyrinoids","volume":"2","author":"Borovkov","year":"2010","journal-title":"Symmetry"},{"key":"ref_332","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1016\/j.jphotochem.2016.01.027","article-title":"Tempo-spatial chirogenesis. Limonene-induced mirror symmetry breaking of Si\u2013Si bond polymers during aggregation in chiral fluidic media","volume":"331","author":"Fujiki","year":"2016","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"ref_333","doi-asserted-by":"crossref","first-page":"6636","DOI":"10.1039\/c2cc17845a","article-title":"Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality","volume":"48","author":"Nakano","year":"2012","journal-title":"Chem. Commun."}],"container-title":["Symmetry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-8994\/17\/3\/433\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T16:53:19Z","timestamp":1760028799000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-8994\/17\/3\/433"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3,13]]},"references-count":333,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2025,3]]}},"alternative-id":["sym17030433"],"URL":"https:\/\/doi.org\/10.3390\/sym17030433","relation":{},"ISSN":["2073-8994"],"issn-type":[{"value":"2073-8994","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,3,13]]}}}