{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,13]],"date-time":"2026-06-13T04:56:44Z","timestamp":1781326604534,"version":"3.54.1"},"reference-count":33,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2026,6,9]],"date-time":"2026-06-09T00:00:00Z","timestamp":1780963200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100012190","name":"Ministry of Science and Higher Education of the Russian Federation","doi-asserted-by":"crossref","award":["FEWZ-2024-0015"],"award-info":[{"award-number":["FEWZ-2024-0015"]}],"id":[{"id":"10.13039\/501100012190","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Entropy"],"abstract":"<jats:p>The reaction scheme of the partial oxidation of methane is still currently undetermined for many catalysts due to a lack of accurate experimental data to develop kinetic studies. In this work, a kinetic modeling study of partial oxidation of methane was performed using experimental data from the literature. A kinetic model is proposed, and a new set of kinetic parameters was obtained in view of the failed reproduction of a model from the literature. The kinetic parameters of the proposed model were calculated and determined by using an optimization approach based on non-lineal parameter estimation, proper selection of initial values of parameters, and sensitivity and statistical analyses. Experimental data from the literature obtained in a packed-bed reactor with a Pt\/Al2O3 catalyst at reaction temperatures of 465\u2013574 \u00b0C were used to develop the kinetic model. Experimental data were accurately predicted by the proposed model with determination coefficient of 0.988.<\/jats:p>","DOI":"10.3390\/e28060658","type":"journal-article","created":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T05:50:58Z","timestamp":1781157058000},"page":"658","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Revised Kinetic Model for the Catalytic Partial Oxidation of Methane"],"prefix":"10.3390","volume":"28","author":[{"given":"Javier","family":"Jurado","sequence":"first","affiliation":[{"name":"Instituto Polit\u00e9cnico Nacional, Centro de Investigaci\u00f3n en Ciencia Aplicada y Tecnolog\u00eda Avanzada, Legaria 694, Col. Irrigaci\u00f3n, Mexico City 11500, Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2623-852X","authenticated-orcid":false,"given":"Fernando","family":"Trejo","sequence":"additional","affiliation":[{"name":"Instituto Polit\u00e9cnico Nacional, Centro de Investigaci\u00f3n en Ciencia Aplicada y Tecnolog\u00eda Avanzada, Legaria 694, Col. Irrigaci\u00f3n, Mexico City 11500, Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jorge","family":"Ancheyta","sequence":"additional","affiliation":[{"name":"Escuela Superior de Ingenier\u00eda Qu\u00edmica e Industrias Extractivas, Instituto Polit\u00e9cnico Nacional, Unidad Profesional Adolfo L\u00f3pez Mateos, Zacatenco, Mexico City 07738, Mexico"},{"name":"School of Natural Sciences, Tyumen State University, 15 a Perekopskaya St., Tyumen 625033, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrey","family":"Elyshev","sequence":"additional","affiliation":[{"name":"School of Natural Sciences, Tyumen State University, 15 a Perekopskaya St., Tyumen 625033, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6217-0302","authenticated-orcid":false,"given":"Andrey","family":"Zagoruiko","sequence":"additional","affiliation":[{"name":"School of Natural Sciences, Tyumen State University, 15 a Perekopskaya St., Tyumen 625033, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2026,6,9]]},"reference":[{"key":"ref_1","first-page":"40","article-title":"Modeling of partial oxidation of methane in a membrane reactor","volume":"5","author":"Fernandes","year":"2006","journal-title":"Rev. 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