{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T03:35:45Z","timestamp":1768448145329,"version":"3.49.0"},"reference-count":69,"publisher":"MDPI AG","issue":"24","license":[{"start":{"date-parts":[[2021,12,8]],"date-time":"2021-12-08T00:00:00Z","timestamp":1638921600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Energies"],"abstract":"<jats:p>Landfills have been identified as one of the major sources of greenhouse gas (GHG) emissions and as a contributor to climate change. Landfill facilities exhibit considerable spatial and temporal variability of both methane (CH4) and carbon dioxide (CO2) rates. The present work aimed to evaluate the spatial distribution of CH4 and CO2 and their \u03b413C isotopic composition originating from a municipal landfill site, to identify its contribution to the local GHG budget and the potential impact on the air quality of the immediate surroundings in a short-term response to environmental conditions. The objective was met by performing direct measurements of atmospheric CO2 and CH4 at the selected monitoring points on the surface and applying a binary mixing model for the determination of carbon isotopic ratios in the vicinity of the municipal waste landfill site. Air samples were collected and analysed for isotopic composition using flask sampling with a Picarro G2201-I Cavity Ring-Down Spectroscopy (CRDS) technique. Kriging and Inverse distance weighting (IDW) methods were used to evaluate the values at unsampled locations and to map the excess of GHGs emitted from the landfill surface. The large off-site dispersion of methane from the landfill site at a 500 m distance was identified during field measurements using isotopic data. The mean \u03b413C of the landfill biogas emitted to the surrounded atmosphere was \u221253.9 \u00b1 2.2\u2030, which corresponded well to the microbial degradation processes during acetate fermentation in the waste deposits. The calculated isotopic compositions of CO2 (\u03b413C = \u221218.64 \u00b1 1.75\u2030) indicate the domination of biogenic carbon reduction by vegetation surrounding the landfill. Finally, amounts of methane escaping into the air can be limited by the appropriate landfill management practices (faster covers active quarter through separation layer), and CH4 reduction can be achieved by sealing the cover on the leachate tank.<\/jats:p>","DOI":"10.3390\/en14248259","type":"journal-article","created":{"date-parts":[[2021,12,9]],"date-time":"2021-12-09T21:52:32Z","timestamp":1639086752000},"page":"8259","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Assessment of GHG Interactions in the Vicinity of the Municipal Waste Landfill Site\u2014Case Study"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8588-1219","authenticated-orcid":false,"given":"Maciej","family":"G\u00f3rka","sequence":"first","affiliation":[{"name":"Faculty of Earth Science and Environmental Management, University of Wroc\u0142aw, Cybulskiego 32, 50-205 Wroclaw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yaroslav","family":"Bezyk","sequence":"additional","affiliation":[{"name":"Faculty of Environmental Engineering, Wroclaw University of Science and Technology, Plac Grunwaldzki 13, 50-377 Wroclaw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9810-4673","authenticated-orcid":false,"given":"Izabela","family":"S\u00f3wka","sequence":"additional","affiliation":[{"name":"Faculty of Environmental Engineering, Wroclaw University of Science and Technology, Plac Grunwaldzki 13, 50-377 Wroclaw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2021,12,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3269","DOI":"10.5194\/essd-12-3269-2020","article-title":"Global Carbon Budget 2020","volume":"12","author":"Friedlingstein","year":"2020","journal-title":"Earth Syst. 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