{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T21:03:35Z","timestamp":1792789415990,"version":"4.5.0"},"reference-count":51,"publisher":"MDPI AG","issue":"19","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Council for Scientific and Technological De-velopment","id":[{"id":"https:\/\/ror.org\/03swz6y49","id-type":"ROR","asserted-by":"crossref"}]},{"id":[{"id":"https:\/\/ror.org\/03swz6y49","id-type":"ROR","asserted-by":"publisher"}]},{"name":"Federal University of Technology\u2014Parana"},{"name":"Araucaria Foundation","id":[{"id":"https:\/\/ror.org\/02r7nkw81","id-type":"ROR","asserted-by":"crossref"}]},{"id":[{"id":"https:\/\/ror.org\/02r7nkw81","id-type":"ROR","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Foods"],"abstract":"<jats:p>This study evaluated the effect of cationic cassava starch with different degrees of substitution (DS: 0.019, 0.027, and 0.033 mol\/mol) and polyvinyl alcohol (PVA) with different hydrolysis degrees (HD: 88 and 98%) on the properties of sheets produced by extrusion-calendering, using glycerol as a plasticizer. Machine learning (ML) models were used to predict sheet properties. The HD influenced material properties more significantly than the DS of cationic starch, with higher HD PVA yielding superior mechanical performance regardless of starch type. The sheets exhibited high thermal stability and processing continuity during extrusion-calendering, demonstrating laboratory-scale production viability. ML demonstrated that Gradient Boosting models better predicted tensile strength and elongation at break with R2 ~0.98 and MAPE of the 7.1 and 2.8%, respectively; the Young\u2019s modulus was adequately predicted by the Decision Tree model (R2 ~0.96 and MAPE ~8.1%) and the apparent opacity was better predicted by the Extreme Gradient Boosting model (R2 ~0.90 and MAPE ~4.7%). For these adjustments, the HD was more important than DS when predicting the properties of the sheets, as observed experimentally.<\/jats:p>","DOI":"10.3390\/foods15193360","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T08:17:54Z","timestamp":1790065074000},"page":"3360","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cationic Starch and Polyvinyl Alcohol Composite Sheets Produced by Extrusion-Calendering"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5759-1575","authenticated-orcid":false,"given":"Juliano","family":"Zanela","sequence":"first","affiliation":[{"name":"Department of Food Science and Technology, Universidade Estadual de Londrina, Rod. Celso Garcia Cid (PR 445), km 380, P.O. Box 6001, Londrina 86051-990, PR, Brazil"},{"name":"Bioprocess Engineering and Biotechnology Course, Federal University of Technology\u2014Paran\u00e1, Estrada para Boa Esperan\u00e7a, Km 04, Dois Vizinhos 85660-000, PR, Brazil"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"conceptualization","vocabulary":"credit"},{"role":"formal-analysis","vocabulary":"credit"},{"role":"methodology","vocabulary":"credit"},{"role":"writing-original-draft","vocabulary":"credit"}]},{"given":"Ana Paula","family":"Bilck","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology, Universidade Estadual de Londrina, Rod. Celso Garcia Cid (PR 445), km 380, P.O. Box 6001, Londrina 86051-990, PR, Brazil"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"methodology","vocabulary":"credit"},{"role":"formal-analysis","vocabulary":"credit"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8523-003X","authenticated-orcid":false,"given":"Gracielle","family":"Johann","sequence":"additional","affiliation":[{"name":"Bioprocess Engineering and Biotechnology Course, Federal University of Technology\u2014Paran\u00e1, Estrada para Boa Esperan\u00e7a, Km 04, Dois Vizinhos 85660-000, PR, Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0795-6358","authenticated-orcid":false,"given":"Marianne Ayumi","family":"Shirai","sequence":"additional","affiliation":[{"name":"Department of Food Technology, Federal University of Technology\u2014Paran\u00e1, Jo\u00e3o Miguel Caram, 731, Londrina 86036-700, PR, Brazil"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"visualization","vocabulary":"credit"}]},{"given":"Maria Victoria Eiras","family":"Grossmann","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology, Universidade Estadual de Londrina, Rod. Celso Garcia Cid (PR 445), km 380, P.O. Box 6001, Londrina 86051-990, PR, Brazil"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"supervision","vocabulary":"credit"},{"role":"project-administration","vocabulary":"credit"},{"role":"funding-acquisition","vocabulary":"credit"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9280-0683","authenticated-orcid":false,"given":"Fabio","family":"Yamashita","sequence":"additional","affiliation":[{"name":"Department of Food Science and Technology, Universidade Estadual de Londrina, Rod. Celso Garcia Cid (PR 445), km 380, P.O. Box 6001, Londrina 86051-990, PR, Brazil"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"supervision","vocabulary":"credit"},{"role":"project-administration","vocabulary":"credit"},{"role":"funding-acquisition","vocabulary":"credit"}]}],"member":"1968","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"120627","DOI":"10.1016\/j.carbpol.2023.120627","article-title":"Recent Advances and Future Challenges of the Starch-Based Bio-Composites for Engineering Applications","volume":"307","author":"Wang","year":"2023","journal-title":"Carbohydr. Polym."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"553","DOI":"10.1007\/s00289-009-0158-4","article-title":"Effect of Amylose Contents of Starches on Physical Properties and Biodegradability of Starch\/PVA-Blended Films","volume":"64","author":"Yun","year":"2010","journal-title":"Polym. 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