{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,1]],"date-time":"2026-02-01T18:35:41Z","timestamp":1769970941216,"version":"3.49.0"},"reference-count":30,"publisher":"MDPI AG","issue":"21","license":[{"start":{"date-parts":[[2022,11,4]],"date-time":"2022-11-04T00:00:00Z","timestamp":1667520000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51906175"],"award-info":[{"award-number":["51906175"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJERPH"],"abstract":"<jats:p>Volatile organic compounds (VOCs) are an important source of air pollution, harmful to human health and the environment, and important precursors of secondary organic aerosols, O3 and photochemical smog. This study focused on the low-temperature catalytic oxidation and degradation of benzene, dichloroethane, methanethiol, methanol and methylamine by ozone. Benzene was used as a model compound, and a molecular sieve was selected as a catalyst carrier to prepare a series of supported active metal catalysts by impregnation. The effects of ozone on the catalytic oxidation of VOCs and catalysts\u2019 activity were studied. Taking benzene as a model compound, low-temperature ozone catalytic oxidation was conducted to explore the influence of the catalyst carrier, the active metal and the precious metal Pt on the catalytic degradation of benzene. The optimal catalyst appeared to be 0.75%Pt\u201310%Fe\/HZSM(200). The catalytic activity and formation of the by-products methylamine, methanethiol, methanol, dichloroethane and benzene over 0.75%Pt\u201310%Fe\/HZSM(200) were investigated. The structure, oxygen vacancy, surface properties and surface acidity of the catalysts were investigated. XRD, TEM, XPS, H2-TPR, EPR, CO2-TPD, BET, C6H6-TPD and Py-IR were combined to establish the correlation between the surface properties of the catalysts and the degradation activity.<\/jats:p>","DOI":"10.3390\/ijerph192114515","type":"journal-article","created":{"date-parts":[[2022,11,8]],"date-time":"2022-11-08T11:56:36Z","timestamp":1667908596000},"page":"14515","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Low-Temperature Catalytic Ozonation of Multitype VOCs over Zeolite-Supported Catalysts"],"prefix":"10.3390","volume":"19","author":[{"given":"Jiaming","family":"Shao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China"},{"name":"Zhejiang SUPCON Technology Co., Ltd., Hangzhou 310053, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5493-5299","authenticated-orcid":false,"given":"Yunchu","family":"Zhai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China"},{"name":"China Energy Engineering Group, Zhejiang Electric Power Design Institute Co. Ltd., Hangzhou 310012, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Luyang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering, Tianjin University and Tianjin Key Lab of Biomass and Wastes Utilization, Tianjin 300072, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li","family":"Xiang","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering, Tianjin University and Tianjin Key Lab of Biomass and Wastes Utilization, Tianjin 300072, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5461-8277","authenticated-orcid":false,"given":"Fawei","family":"Lin","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering, Tianjin University and Tianjin Key Lab of Biomass and Wastes Utilization, Tianjin 300072, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,4]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"4471","DOI":"10.1021\/acs.chemrev.8b00408","article-title":"Recent Advances in the Catalytic Oxidation of Volatile Organic Compounds: A Review Based on Pollutant Sorts and Sources","volume":"119","author":"He","year":"2019","journal-title":"Chem. Rev."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"123030","DOI":"10.1016\/j.cej.2019.123030","article-title":"Flue gas treatment with ozone oxidation: An overview on NOx, organic pollutants, and mercury","volume":"382","author":"Lin","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"126338","DOI":"10.1016\/j.chemosphere.2020.126338","article-title":"A review and perspective of recent research in biological treatment applied in removal of chlorinated volatile organic compounds from waste air","volume":"250","author":"Li","year":"2020","journal-title":"Chemosphere"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"111687","DOI":"10.1016\/j.envres.2021.111687","article-title":"Triple combination of natural microbial action, etching, and gas foaming to synthesize hierarchical porous carbon for efficient adsorption of VOCs","volume":"202","author":"Yu","year":"2021","journal-title":"Environ. Res."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"2069","DOI":"10.1002\/jctb.6308","article-title":"A review on recent advances in catalytic combustion of chlorinated volatile organic compounds","volume":"95","author":"Li","year":"2020","journal-title":"J. Chem. Tech. Biotech."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"126534","DOI":"10.1016\/j.cej.2020.126534","article-title":"How to achieve complete elimination of Cl-VOCs: A critical review on byproducts formation and inhibition strategies during catalytic oxidation","volume":"404","author":"Lin","year":"2021","journal-title":"Chem. Eng. J."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"118662","DOI":"10.1016\/j.apcatb.2020.118662","article-title":"Low temperature catalytic ozonation of toluene in flue gas over Mn-based catalysts: Effect of support property and SO2\/water vapor addition","volume":"266","author":"Shao","year":"2020","journal-title":"Appl. Catal. B"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"126847","DOI":"10.1016\/j.jhazmat.2021.126847","article-title":"Catalytic ozonation of VOCs at low temperature: A comprehensive review","volume":"422","author":"Liu","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"2649","DOI":"10.1039\/C4CY01733A","article-title":"Low temperature catalytic oxidation of volatile organic compounds: A review","volume":"5","author":"Huang","year":"2015","journal-title":"Catal. Sci. Technol."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"311","DOI":"10.1080\/10643389.2020.1818490","article-title":"Comprehensive review on catalytic degradation of Cl-VOCs under the practical application conditions","volume":"52","author":"Lin","year":"2022","journal-title":"Crit. Rev. Environ. Sci. Technol."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"134807","DOI":"10.1016\/j.cej.2022.134807","article-title":"Efficient degradation of multiple Cl-VOCs by catalytic ozonation over MnOx catalysts with different supports","volume":"435","author":"Lin","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"569","DOI":"10.1016\/j.apcatb.2019.01.023","article-title":"Facile and green synthetic strategy of birnessite-type MnO2 with high efficiency for airborne benzene removal at low temperatures","volume":"245","author":"Liu","year":"2019","journal-title":"Appl. Catal. B"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1016\/j.mcat.2017.12.020","article-title":"Catalytic deep combustion characteristics of benzene over cobalt doped Mn-Ce solid solution catalysts at lower temperatures","volume":"446","author":"Deng","year":"2018","journal-title":"Mol. Catal."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"670","DOI":"10.1016\/j.apsusc.2018.06.302","article-title":"Enhanced formaldehyde oxidation performance over Pt\/ZSM through a facile nickel cation modification","volume":"457","author":"Ding","year":"2018","journal-title":"Appl. Surf. Sci."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"130929","DOI":"10.1016\/j.cej.2021.130929","article-title":"Synergistic effect for simultaneously catalytic ozonation of chlorobenzene and NO over MnCoOx catalysts: Byproducts formation under practical conditions","volume":"427","author":"Zhang","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"129217","DOI":"10.1016\/j.jhazmat.2022.129217","article-title":"Catalytic ozonation of CH2Cl2 over hollow urchin-like MnO2 with regulation of active oxygen by catalyst modification and ozone promotion","volume":"436","author":"Xiang","year":"2022","journal-title":"J. Hazard. Mater."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"122218","DOI":"10.1016\/j.jhazmat.2020.122218","article-title":"Comparative investigation on catalytic ozonation of VOCs in different types over supported MnOx catalysts","volume":"391","author":"Chen","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"129997","DOI":"10.1016\/j.jhazmat.2022.129997","article-title":"Tentative exploration on water-promoted catalytic ozonation of Cl-VOCs and feasibility of application in complex flue gas over monolithic cobalt catalyst","volume":"441","author":"Xiang","year":"2023","journal-title":"J. Hazard. Mater."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"130814","DOI":"10.1016\/j.cej.2021.130814","article-title":"Catalytic deep degradation of Cl-VOCs with the assistance of ozone at low temperature over MnO2 catalysts","volume":"426","author":"Zhang","year":"2021","journal-title":"Chem. Eng. J."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1515\/rams-2020-0002","article-title":"Catalytic oxidation of CO over CuO\/CeO2 nanocomposites synthesized via solution combustion method: Effect of fuels","volume":"59","author":"Cam","year":"2020","journal-title":"Rev. Adv. Mater. Sci."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"100","DOI":"10.1016\/j.apcatb.2016.05.058","article-title":"Catalytic deep oxidation of NO by ozone over MnOx loaded spherical alumina catalyst","volume":"198","author":"Lin","year":"2016","journal-title":"Appl. Catal. B"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"25132","DOI":"10.1039\/C7RA04010E","article-title":"Catalyst tolerance to SO2 and water vapor of Mn based bimetallic oxides for NO deep oxidation by ozone","volume":"7","author":"Lin","year":"2017","journal-title":"RSC Adv."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"3341","DOI":"10.1021\/acs.est.0c07862","article-title":"Comparative Investigation on Chlorobenzene Oxidation by Oxygen and Ozone over a MnOx\/Al2O3 Catalyst in the Presence of SO2","volume":"55","author":"Lin","year":"2021","journal-title":"Environ. Sci. Technol."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"13379","DOI":"10.1021\/acs.est.2c03811","article-title":"Evaluation of the Flexibility for Catalytic Ozonation of Dichloromethane over Urchin-Like CuMnOx in Flue Gas with Complicated Components","volume":"56","author":"Xiang","year":"2022","journal-title":"Environ. Sci. Technol."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"4268","DOI":"10.1021\/acs.est.0c08179","article-title":"Recent Progress of Thermocatalytic and Photo\/Thermocatalytic Oxidation for VOCs Purification over Manganese-based Oxide Catalysts","volume":"55","author":"Wu","year":"2021","journal-title":"Environ. Sci. Technol."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"34737","DOI":"10.1016\/j.ijhydene.2021.08.059","article-title":"Agaricus bisporus residue-derived Fe\/N co-doped carbon materials as an efficient electrocatalyst for oxygen reduction reaction","volume":"46","author":"Chen","year":"2021","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"153115","DOI":"10.1016\/j.scitotenv.2022.153115","article-title":"Utilizing waste duckweed from phytoremediation to synthesize highly efficient FeNxC catalysts for oxygen reduction reaction electrocatalysis","volume":"819","author":"Li","year":"2022","journal-title":"Sci. Total Environ."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"117210","DOI":"10.1016\/j.apcata.2019.117210","article-title":"Effects of supports on bimetallic Pd-Cu catalysts for CO2 hydrogenation to methanol","volume":"585","author":"Lin","year":"2019","journal-title":"Appl. Catal. A"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"375","DOI":"10.1016\/j.jcat.2019.06.041","article-title":"The oxidation of chlorinated organic compounds over W-modified Pt\/CeO2 catalysts","volume":"380","author":"Gu","year":"2019","journal-title":"J. Catal."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"118237","DOI":"10.1016\/j.apcatb.2019.118237","article-title":"Catalytic oxidation of chlorinated VOCs over Ru\/TixSn1\u2212x catalysts","volume":"263","author":"Zhao","year":"2020","journal-title":"Appl. Catal. B"}],"container-title":["International Journal of Environmental Research and Public Health"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1660-4601\/19\/21\/14515\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:11:01Z","timestamp":1760145061000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1660-4601\/19\/21\/14515"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,4]]},"references-count":30,"journal-issue":{"issue":"21","published-online":{"date-parts":[[2022,11]]}},"alternative-id":["ijerph192114515"],"URL":"https:\/\/doi.org\/10.3390\/ijerph192114515","relation":{},"ISSN":["1660-4601"],"issn-type":[{"value":"1660-4601","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,11,4]]}}}