{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T04:40:47Z","timestamp":1760244047323,"version":"build-2065373602"},"reference-count":61,"publisher":"MDPI AG","issue":"7","license":[{"start":{"date-parts":[[2009,7,8]],"date-time":"2009-07-08T00:00:00Z","timestamp":1247011200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>The structures, electron affinities and bond dissociation energies of BrO4F\/BrO4F\u2212 species have been investigated with five density functional theory (DFT) methods with DZP++ basis sets. The planar F-Br\u2026O2\u2026O2 complexes possess 3A' electronic state for neutral molecule and 4A' state for the corresponding anion. Three types of the neutral-anion energy separations are the adiabatic electron affinity (EAad), the vertical electron affinity (EAvert), and the vertical detachment energy (VDE). The EAad value predicted by B3LYP method is 4.52 eV. The bond dissociation energies De (BrO4F \u2192 BrO4-mF + Om) (m = 1-4) and De- (BrO4F- \u2192 BrO4-mF- + Om and BrO4F- \u2192 BrO4-mF + Om-) are predicted. The adiabatic electron affinities (EAad) were predicted to be 4.52 eV for F-Br\u2026O2\u2026O2 (3A'\u2190 4A') (B3LYP method).<\/jats:p>","DOI":"10.3390\/ijms10073128","type":"journal-article","created":{"date-parts":[[2009,7,8]],"date-time":"2009-07-08T12:33:17Z","timestamp":1247056397000},"page":"3128-3148","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Density Functional Study of Structures and Electron Affinities of BrO4F\/BrO4F-"],"prefix":"10.3390","volume":"10","author":[{"given":"Liangfa","family":"Gong","sequence":"first","affiliation":[{"name":"College of Chemical Engineering, Beijing Institute of Petro-Chemical Technology, Beijing 102617, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jieming","family":"Xiong","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering, Beijing Institute of Petro-Chemical Technology, Beijing 102617, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xinmin","family":"Wu","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering, Beijing Institute of Petro-Chemical Technology, Beijing 102617, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chuansong","family":"Qi","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering, Beijing Institute of Petro-Chemical Technology, Beijing 102617, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering, Beijing Institute of Petro-Chemical Technology, Beijing 102617, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wenli","family":"Guo","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering, Beijing Institute of Petro-Chemical Technology, Beijing 102617, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2009,7,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"195","DOI":"10.1016\/S1381-1169(98)00051-X","article-title":"Electronic and structural properties of montmorillonite\u2014a quantum chemical study","volume":"136","author":"Chatterjee","year":"1998","journal-title":"J. Mol. Catal"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"7306","DOI":"10.1021\/jp045775z","article-title":"Effects of Water on the structure and bonding of resorcinol in the interlayer of montmorillonite nanocomposite: A periodic first principle study","volume":"109","author":"Chatterjee","year":"2005","journal-title":"J. Phys. Chem. B"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1016\/S0927-0256(98)00083-4","article-title":"A DFT study on clay\u2013cation\u2013water interaction in montmorillonite and beidellite","volume":"14","author":"Chatterjee","year":"1999","journal-title":"Comput. Mater. Sci"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"8216","DOI":"10.1021\/jp001029s","article-title":"A novel method to correlate layer charge and the catalytic activity of 2:1 dioctahedral smectite clays in terms of binding the interlayer cation surrounded by monohydrate","volume":"104","author":"Chatterjee","year":"2000","journal-title":"J. Phys. Chem A"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"3414","DOI":"10.1063\/1.1640333","article-title":"Effect of exchangeable cation on the swelling property of 2:1 dioctahedral smectite\u2014A periodic first principle study","volume":"120","author":"Chatterjee","year":"2004","journal-title":"J. Chem. Phys"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"641","DOI":"10.1021\/jp0127418","article-title":"Sorbent for dioxins and furans: reactivity index study","volume":"106","author":"Chatterjee","year":"2002","journal-title":"J. Phys. Chem. A"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"447","DOI":"10.1016\/j.jmgm.2005.01.002","article-title":"Structure and property correlation for Ag deposition on \u03b1-Al2O3 - a first principle study","volume":"23","author":"Chatterjee","year":"2005","journal-title":"J. Mol. Graph. Model"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"860","DOI":"10.1021\/jp045882t","article-title":"Structure-property relationship in py-hexahydrocinchonidine diastereomers: ab Initio and NMR study","volume":"109","author":"Chatterjee","year":"2005","journal-title":"J. Phys. Chem. A"},{"key":"ref_9","doi-asserted-by":"crossref","unstructured":"Chattaraj, PK (2009). Chemical Reactivity Theory: A Density Functional Theory View, Taylor & Francis Group.","DOI":"10.1201\/9781420065442"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"4049","DOI":"10.1021\/ja00326a036","article-title":"Density functional approach to the frontier-electron theory of chemical reactivity","volume":"106","author":"Parr","year":"1984","journal-title":"J. Am. Chem. Soc"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"1793","DOI":"10.1021\/cr990029p","article-title":"Conceptual density functional theory","volume":"103","author":"Geerlings","year":"2003","journal-title":"J. Chem. Rev"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"5992","DOI":"10.1021\/ja983394r","article-title":"Mechanism of [2 + 1] cycloadditions of hydrogen isocyanide to alkynes: molecular orbital and density functional theory study","volume":"121","author":"Nguyen","year":"1999","journal-title":"J. Am. Chem. Soc"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"5944","DOI":"10.1021\/jp9807064","article-title":"Ab initio and density functional theory study of the geometry and reactivity of benzyne, 3-fluorobenzyne, 4-fluorobenzyne, and 4,5-Didehydro-pyrimidine","volume":"102","author":"Langenaeker","year":"1998","journal-title":"J. Phys. Chem. A"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"6419","DOI":"10.1021\/jo9703055","article-title":"On the asynchronism of isocyanide addition to dipolarophiles: Application of local softness","volume":"62","author":"Chandra","year":"1997","journal-title":"J. Org. Chem"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1016\/S0009-2614(99)00587-4","article-title":"Assessment of the importance of the solvent in the calculation of condensed Fukui function: a self-consistent reaction field calculation study","volume":"308","author":"Sivanesan","year":"1999","journal-title":"Chem. Phys. Lett"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"5708","DOI":"10.1021\/ja00279a008","article-title":"The use of global and local molecular parameters for the analysis of the gas-phase basicity of amines","volume":"108","author":"Yang","year":"1986","journal-title":"J. Am. Chem. Soc"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1126\/science.283.5398.55","article-title":"DOAS Measurements of tropospheric bromine oxide in mid-latitudes","volume":"283","author":"Hebestreit","year":"1999","journal-title":"Science"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"4802","DOI":"10.1021\/jp8087435","article-title":"Post-CCSD(T) ab initio thermochemistry of halogen Oxides and related hydrides XOX, XOOX, HOX, XO, and HXO (X = F, Cl), and evaluation of DFT methods for these systems","volume":"113","author":"Karton","year":"2009","journal-title":"J. Phys. Chem. A"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"9623","DOI":"10.1021\/jp806220r","article-title":"ClClO2 is the most stable isomer of Cl2O2. Accurate coupled cluster energetics and electronic spectra of Cl2O2 isomers","volume":"112","author":"Matus","year":"2009","journal-title":"J. Phys. Chem. A"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/S0009-2614(02)00117-3","article-title":"A density functional study of structure and heat of formation for Br2O4 and Br2O5","volume":"354","author":"Li","year":"2002","journal-title":"Chem. Phys. Lett"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"879","DOI":"10.1080\/00268970050025493","article-title":"Electron affinities of the bromine oxides BrOn, n = 1\u20134","volume":"98","author":"Xie","year":"2000","journal-title":"Mol. Phys"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"19","DOI":"10.1016\/j.theochem.2006.03.035","article-title":"Heats of formation of perchloric acid, HClO4, and perchloric anhydride, Cl2O7. Probing the limits of W1 and W2 theory","volume":"771","author":"Martin","year":"2006","journal-title":"J. Mol. Struct.: THEOCHEM"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"95","DOI":"10.1016\/j.theochem.2006.10.017","article-title":"Density functional theory studies on dioxygen difluoride and other fluorine\/oxygen binary compounds: Availability and shortcoming","volume":"804","author":"Ju","year":"2007","journal-title":"J. Mol. Struct.: THEOCHEM"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.theochem.2007.02.040","article-title":"A computational study of dihalogen-l-dichalcogenides: XAAX (X = F, Cl, Br; A = S, Se)","volume":"814","author":"Prascher","year":"2007","journal-title":"J. Mol. Struct. : THEOCHEM"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"9641","DOI":"10.1021\/jp030267v","article-title":"Coupled cluster theory and multireference configuration interaction study of FO, F2O, FO2, and FOOF","volume":"107","author":"Feller","year":"2003","journal-title":"J. Phys. Chem. A"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"3269","DOI":"10.1021\/jp002852r","article-title":"Quantum chemical descriptions of FOOF: the unsolved problem of predicting its equilibrium geometry","volume":"105","author":"Kraka","year":"2001","journal-title":"J. Phys. Chem. A"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"800","DOI":"10.1021\/ic50110a028","article-title":"Thermodynamic properties of perbromyl fluoride (BrO3F)","volume":"11","author":"Johnson","year":"1972","journal-title":"Inorg. Chem"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1016\/0022-2860(76)80109-3","article-title":"An electron-diffraction study of the molecular structure of gaseous perbromyl fluoride and calculation of its force field and vibrational amplitudes","volume":"35","author":"Appelman","year":"1976","journal-title":"J. Mol. Struct. : THEOCHEM"},{"key":"ref_29","doi-asserted-by":"crossref","unstructured":"Gillespie, RJ, and Spekkens, P (1976). Preparation and characterization of potassiumdifluorodioxobromate and tetrafluoro-oxobromate. J Chem Soc Dalton Trans, 2391\u20132396.","DOI":"10.1039\/dt9760002391"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1533","DOI":"10.1021\/ic50184a029","article-title":"Bromine trifluoride oxide. Vibrational spectrum, force constants and thermodynamic properties","volume":"17","author":"Christe","year":"1978","journal-title":"Inorg. Chem"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"9416","DOI":"10.1021\/ja0402607","article-title":"Synthesis and characterization of salts containing the BrO3F2\u2212 anion; A rare example of a bromine (VII) species","volume":"127","author":"Lehmann","year":"2005","journal-title":"J. Am. Chem. Soc"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"8343","DOI":"10.1021\/ic800929h","article-title":"Behavior of BrO3F and ClO3F Toward strong lewis acids and the characterization of [XO2][SbF6] (X = Cl, Br) by single cCrystal X-ray diffraction, raman spectroscopy, and computational methods","volume":"47","author":"Lehmann","year":"2008","journal-title":"Inorg. Chem"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1016\/S0009-2614(98)00256-5","article-title":"Structure, vibrational spectra and energetics of OBrO+","volume":"288","author":"Francisco","year":"1998","journal-title":"Chem. Phys. Lett"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"1995","DOI":"10.1080\/00268970500130225","article-title":"Novel bromine oxyfluorides: Structures, thermochemistry and electron affinities of BrOFn\/BrOFn\u2212 (n = 1\u20135)","volume":"103","author":"Gong","year":"2005","journal-title":"Mol. Phys"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"395","DOI":"10.1016\/j.cplett.2007.03.097","article-title":"Structures and electron affinities of BrO2F and BrO3F","volume":"439","author":"Li","year":"2007","journal-title":"Chem. Phys. Lett"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1080\/0026897021000026845","article-title":"Electron affinities of the dibromine oxides: Br2On (n = 0\u20134)","volume":"101","author":"Pak","year":"2003","journal-title":"Mol. Phys"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"6904","DOI":"10.1021\/ja990144h","article-title":"Bromine halides: The neutral molecules BrClFn (n = 1\u20135) and their anions structures, energetics, and electron affinities","volume":"121","author":"Ignatyev","year":"1999","journal-title":"J. Am. Chem. Soc"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.theochem.2008.12.027","article-title":"Structures, vibrational frequencies, and electron affinities of SF5On\/SF5On\u2212 (n = 1\u20133)","volume":"900","author":"Xu","year":"2009","journal-title":"J. Mol. Struct. : THEOCHEM"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1021\/cr990044u","article-title":"Atomic and molecular electron affinities: Photoelectron experiments and theoretical computations","volume":"102","author":"Tschumper","year":"2002","journal-title":"Chem. Rev"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"7512","DOI":"10.1021\/ja00364a005","article-title":"Absolute Hardness: Companion parameter to absolute electronegativity","volume":"105","author":"Parr","year":"1983","journal-title":"J. Am. Chem. Soc"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"561","DOI":"10.1021\/ed064p561","article-title":"Recent advances in the concept of hard and soft acids and bases","volume":"64","author":"Pearson","year":"1987","journal-title":"J. Chem. Educ"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"1372","DOI":"10.1063\/1.464304","article-title":"A new mixing of Hartree\u2013Fock and local density-functional theories","volume":"98","author":"Becke","year":"1993","journal-title":"J Chem Phys"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"785","DOI":"10.1103\/PhysRevB.37.785","article-title":"Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density","volume":"37","author":"Lee","year":"1988","journal-title":"Phys. Rev. B"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","article-title":"Density-functional thermochemistry. III. The role of exact exchange","volume":"98","author":"Becke","year":"1993","journal-title":"J. Chem. Phys"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"8822","DOI":"10.1103\/PhysRevB.33.8822","article-title":"Density-functional approximation for the correlation energy of the inhomogeneous electron gas","volume":"33","author":"Perdew","year":"1986","journal-title":"Phys. Rev. B"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"3098","DOI":"10.1103\/PhysRevA.38.3098","article-title":"Density-functional exchange-energy approximation with correct asymptotic behavior","volume":"38","author":"Becke","year":"1988","journal-title":"Phys. Rev. A"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"2571","DOI":"10.1063\/1.463096","article-title":"Br Basis sets. Fully optimized contracted Gaussian basis sets for atoms Li to Kr","volume":"97","author":"Schafer","year":"1992","journal-title":"J. Chem. Phys"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"1293","DOI":"10.1063\/1.1696113","article-title":"F and O Basis setsGaussian-Type Functions for Polyatomic Systems I","volume":"42","author":"Huzinaga","year":"1965","journal-title":"J. Chem. Phys"},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"2823","DOI":"10.1063\/1.1674408","article-title":"Gaussian Basis Functions for Use in Molecular Calculations. I. Contraction of (9s5p) Atomic Basis Sets for the First-Row Atoms F and O Basis sets","volume":"53","author":"Dunning","year":"1970","journal-title":"J. Chem. Phys"},{"key":"ref_50","unstructured":"Frisch, MJ, Trucks, GW, Schlegel, HB, Scuseria, GE, Robb, MA, Cheeseman, JR, Montgomery, JA, Vreven, T, Kudin, KN, Burant, JC, Millam, JM, Iyengar, SS, Tomasi, J, Barone, V, Mennucci, B, Cossi, M, Scalmani, G, Rega, N, Petersson, GA, Nakatsuji, H, Hada, M, Ehara, M, Toyota, K, Fukuda, R, Hasegawa, J, Ishida, M, Nakajima, T, Honda, Y, Kitao, O, Nakai, H, Klene, M, Li, X, Knox, JE, Hratchian, HP, Cross, JB, Adamo, C, Jaramillo, J, Gomperts, R, Stratmann, RE, Yazyev, O, Austin, AJ, Cammi, R, Pomelli, C, Ochterski, JW, Ayala, PY, Morokuma, K, Voth, GA, Salvador, P, Dannenberg, JJ, Zakrzewski, VG, Dapprich, S, Daniels, AD, Strain, MC, Farkas, O, Malick, DK, Rabuck, AD, Raghavachari, K, Foresman, JB, Ortiz, JV, Cui, Q, Baboul, AG, Clifford, S, Cioslowski, J, Stefanov, BB, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Martin, RL, Fox, DJ, Keith, T, Al-Laham, MA, Peng, CY, Nanayakkara, A, Challacombe, M, Gill, PMW, Johnson, B, Chen, W, Wong, MW, Gonzalez, C, and Pople, JA (2004). Gaussian 03: IA32W-G03RevC 02 12-Jun-2004, Gaussian, Inc."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"899","DOI":"10.1021\/cr00088a005","article-title":"Intermolecular interactions from a natural bond orbital, donor-acceptor viewpoint","volume":"88","author":"Reed","year":"1988","journal-title":"Chem. Rev"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"553","DOI":"10.1080\/00268977000101561","article-title":"The calculation of small molecular interactions by the differences of separate total energies. Some procedures with reduced errors","volume":"19","author":"Boys","year":"1970","journal-title":"Mol. Phys"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"161","DOI":"10.1016\/j.susc.2004.08.019","article-title":"A comparison of CO adsorption on Pt(211), Ni(211), and Pd(211) surfaces using density functional theory","volume":"571","author":"Orita","year":"2004","journal-title":"Surf. Sci"},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"3005","DOI":"10.1063\/1.1589004","article-title":"The role of the basis set: Assessing density functional theory","volume":"119","author":"Boese","year":"2003","journal-title":"J. Chem. Phys"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"2529","DOI":"10.1063\/1.474593","article-title":"Predicting electron affinities with density functional theory: Some positive results for negative ions","volume":"107","author":"Tschumper","year":"1997","journal-title":"J. Chem. Phys"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"11115","DOI":"10.1021\/ja981131r","article-title":"Electron affinities of the bromine fluorides, BrFn (n = 1\u20137)","volume":"120","author":"Pak","year":"1998","journal-title":"J. Am. chem. Soc"},{"key":"ref_57","unstructured":"Lawley, KP (1987). Ab Initio Methods in Quantum Chemistry, John Wiley & Sons."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"3239","DOI":"10.1021\/jp993964p","article-title":"Structures, vibrational spectra, and relative energetics of CH3BrO3 isomers","volume":"104","author":"Guha","year":"2000","journal-title":"J. Phys. Chem A"},{"key":"ref_59","first-page":"146","article-title":"NIST-JANAF Thermochemical Tables","volume":"1","author":"Chase","year":"1985","journal-title":"J. Phys. Chem. Ref. Data"},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"7795","DOI":"10.1063\/1.468273","article-title":"Experiment determination of \u0394Hf\u03b8 (HOBr) and ionization potentials (HOBr): Implications for the corresponding properties of HOI","volume":"101","author":"Ruscic","year":"1994","journal-title":"J. Chem. Phys"},{"key":"ref_61","first-page":"8","article-title":"JANAF Thermochemical Tables, 3rd ed","volume":"14","author":"Chase","year":"1985","journal-title":"J Phys Chem Ref Data"}],"container-title":["International Journal of Molecular Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1422-0067\/10\/7\/3128\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T22:10:42Z","timestamp":1760220642000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1422-0067\/10\/7\/3128"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,7,8]]},"references-count":61,"journal-issue":{"issue":"7","published-online":{"date-parts":[[2009,7]]}},"alternative-id":["i10073128"],"URL":"https:\/\/doi.org\/10.3390\/ijms10073128","relation":{},"ISSN":["1422-0067"],"issn-type":[{"type":"electronic","value":"1422-0067"}],"subject":[],"published":{"date-parts":[[2009,7,8]]}}}