{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,2]],"date-time":"2025-11-02T06:15:53Z","timestamp":1762064153022,"version":"build-2065373602"},"reference-count":150,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2022,8,20]],"date-time":"2022-08-20T00:00:00Z","timestamp":1660953600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>This contribution aims at providing a critical overview of experimental results for the sorption of low molecular weight compounds in the Cu-BTC Metal\u2013Organic Framework (MOF) and of their interpretation using available and new, specifically developed, theoretical approaches. First, a literature review of experimental results for the sorption of gases and vapors is presented, with particular focus on the results obtained from vibrational spectroscopy techniques. Then, an overview of theoretical models available in the literature is presented starting from semiempirical theoretical approaches suitable to interpret the adsorption thermodynamics of gases and vapors in Cu-BTC. A more detailed description is provided of a recently proposed Lattice Fluid approach, the Rigid Adsorbent Lattice Fluid (RALF) model. In addition, to deal with the cases where specific self- and cross-interactions (e.g., H-bonding, Lewis acid\/Lewis base interactions) play a role, a modification of the RALF model, i.e., the RALFHB model, is introduced here for the first time. An extension of both RALF and RALFHB is also presented to cope with the cases in which the heterogeneity of the rigid adsorbent displaying a different kind of adsorbent cages is of relevance, as it occurs for the adsorption of some low molecular weight substances in Cu-BTC MOF.<\/jats:p>","DOI":"10.3390\/ijms23169406","type":"journal-article","created":{"date-parts":[[2022,8,21]],"date-time":"2022-08-21T22:23:13Z","timestamp":1661120593000},"page":"9406","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Survey on Adsorption of Low Molecular Weight Compounds in Cu-BTC Metal\u2013Organic Framework: Experimental Results and Thermodynamic Modeling"],"prefix":"10.3390","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1563-1441","authenticated-orcid":false,"given":"Antonio","family":"Baldanza","sequence":"first","affiliation":[{"name":"Department of Chemical, Materials and Production Engineering, University of Napoles Federico II, P.le Tecchio 80, 80125 Naples, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7168-7263","authenticated-orcid":false,"given":"Domenico","family":"Mallamace","sequence":"additional","affiliation":[{"name":"Departments of ChiBioFarAm\u2014Section of Industrial Chemistry, University of Messina, CASPE-INSTM, V.le F. Stagno d\u2019Alcontres 31, 98166 Messina, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9333-0292","authenticated-orcid":false,"given":"Giuseppe","family":"Mensitieri","sequence":"additional","affiliation":[{"name":"Department of Chemical, Materials and Production Engineering, University of Napoles Federico II, P.le Tecchio 80, 80125 Naples, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1489-7835","authenticated-orcid":false,"given":"Cosimo","family":"Brondi","sequence":"additional","affiliation":[{"name":"Department of Chemical, Materials and Production Engineering, University of Napoles Federico II, P.le Tecchio 80, 80125 Naples, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6307-1410","authenticated-orcid":false,"given":"Pellegrino","family":"Musto","sequence":"additional","affiliation":[{"name":"Institute for Polymers, Composites and Biomaterials, National Research Council of Italy, Via Campi Flegrei 34, 80078 Pozzuoli, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2757-0647","authenticated-orcid":false,"given":"Giuseppe","family":"Scherillo","sequence":"additional","affiliation":[{"name":"Department of Chemical, Materials and Production Engineering, University of Napoles Federico II, P.le Tecchio 80, 80125 Naples, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,8,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1021\/cs1000625","article-title":"Expanding applications of metal\u2212organic frameworks: Zeolite imidazolate framework ZIF-8 as an efficient heterogeneous catalyst for the knoevenagel reaction","volume":"1","author":"Tran","year":"2011","journal-title":"ACS Catal."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1016\/j.trac.2019.06.007","article-title":"A review on metal-organic frameworks: Synthesis and applications","volume":"118","author":"Safaei","year":"2019","journal-title":"TRAC-Trend Anal. 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