{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,22]],"date-time":"2026-04-22T17:03:22Z","timestamp":1776877402909,"version":"3.51.2"},"reference-count":81,"publisher":"MDPI AG","issue":"17","license":[{"start":{"date-parts":[[2022,8,28]],"date-time":"2022-08-28T00:00:00Z","timestamp":1661644800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"program for science &amp; technology innovation team in universities of Henan province","award":["21IRTSTHN004"],"award-info":[{"award-number":["21IRTSTHN004"]}]},{"name":"program for science &amp; technology innovation team in universities of Henan province","award":["U1804131"],"award-info":[{"award-number":["U1804131"]}]},{"name":"program for science &amp; technology innovation team in universities of Henan province","award":["22A430032"],"award-info":[{"award-number":["22A430032"]}]},{"DOI":"10.13039\/501100001809","name":"national natural science foundation of China","doi-asserted-by":"publisher","award":["21IRTSTHN004"],"award-info":[{"award-number":["21IRTSTHN004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"national natural science foundation of China","doi-asserted-by":"publisher","award":["U1804131"],"award-info":[{"award-number":["U1804131"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"national natural science foundation of China","doi-asserted-by":"publisher","award":["22A430032"],"award-info":[{"award-number":["22A430032"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"key scientific research projects of universities in Henan province","award":["21IRTSTHN004"],"award-info":[{"award-number":["21IRTSTHN004"]}]},{"name":"key scientific research projects of universities in Henan province","award":["U1804131"],"award-info":[{"award-number":["U1804131"]}]},{"name":"key scientific research projects of universities in Henan province","award":["22A430032"],"award-info":[{"award-number":["22A430032"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>The paper reports a strategy to synthesize Cd0.9Co0.1S nanorods (NRs) via a one-pot solvothermal method. Remarkably, the pencil-shaped Cd0.9Co0.1S NRs with a large aspect ratio and good polycrystalline plane structure significantly shorten the photogenerated carrier transfer path and achieve fast separation. An appropriate amount of Co addition enhances visible light-harvesting and generates a photothermal effect to improve the surface reaction kinetics and increases the charge transfer rate. Moreover, the internal electric field facilitates the separation and transfer of carriers and effectively impedes their recombination. As a result, the optimized Cd0.9Co0.1S NRs yield a remarkable H2 evolution rate of 8.009 mmol\u00b7g\u22121\u00b7h\u22121, which is approximately 7.2 times higher than that of pristine CdS. This work improves the photocatalytic hydrogen production rate by tuning and optimizing electronic structures through element addition and using the photothermal synergistic effect.<\/jats:p>","DOI":"10.3390\/ijms23179756","type":"journal-article","created":{"date-parts":[[2022,8,29]],"date-time":"2022-08-29T03:34:56Z","timestamp":1661744096000},"page":"9756","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Cd0.9Co0.1S Nanorods with an Internal Electric Field and Photothermal Effect Synergistically for Boosting Photocatalytic H2 Evolution"],"prefix":"10.3390","volume":"23","author":[{"given":"Lilei","family":"Zhang","sequence":"first","affiliation":[{"name":"Henan Key Laboratory of Function Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manzhou","family":"Hong","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"},{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ka","family":"Zhang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"},{"name":"Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Botan","family":"Li","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Haipeng","family":"Fang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xun","family":"Feng","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Function Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiuchan","family":"Xiao","sequence":"additional","affiliation":[{"name":"School of Materials and Environmental Engineering, Chengdu Technological University, Chengdu 611730, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,8,28]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1239176","DOI":"10.1126\/science.1239176","article-title":"Solar synthesis: Prospects in visible light photocatalysis","volume":"343","author":"Schultz","year":"2014","journal-title":"Science"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"294","DOI":"10.1038\/nature11475","article-title":"Opportunities and challenges for a sustainable energy future","volume":"488","author":"Chu","year":"2012","journal-title":"Nature"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"e1905739","DOI":"10.1002\/adma.201905739","article-title":"Structural-Phase Catalytic Redox Reactions in Energy and Environmental Applications","volume":"32","author":"Uddin","year":"2020","journal-title":"Adv. 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