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The UDMA-TEGDMA photopolymer was prepared in a 3:1 weight ratio and doped with dodecanethiol- (DDT) capped gold nanorods of 25 \u00d7 75 or 25 \u00d7 85 nm nominal diameter and length. It was found that the presence of the gold nanorods alone (without direct plasmonic excitation) can increase the DC of the photopolymer by 6\u201315%. This increase was found to be similar to what could be achieved with a control heat treatment of 30 min at 180 \u00b0C. It was also shown that femtosecond laser impulses (795 nm, 5 mJ pulse energy, 50 fs pulse length, 2.83 Jcm\u22122 fluence), applied after the photopolymerization under a standard dental curing lamp, can cause a 2\u20137% increase in the DC of undoped samples, even after thermal pre-treatment. The best DC values (12\u201315% increase) were obtained with combined nanorod doping and subsequent laser irradiation close to the plasmon resonance peak of the nanorods (760\u2013800 nm), which proves that the excited plasmon field can directly facilitate double bond breakage (without thermoplasmonic effects due to the short pulse length) and increase the crosslink density independently from the initial photopolymerization process.<\/jats:p>","DOI":"10.3390\/ijms232113575","type":"journal-article","created":{"date-parts":[[2022,11,8]],"date-time":"2022-11-08T10:53:06Z","timestamp":1667904786000},"page":"13575","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["The Effect of Femtosecond Laser Irradiation and Plasmon Field on the Degree of Conversion of a UDMA-TEGDMA Copolymer Nanocomposite Doped with Gold Nanorods"],"prefix":"10.3390","volume":"23","author":[{"given":"Attila","family":"Bony\u00e1r","sequence":"first","affiliation":[{"name":"Department of Electronics Technology, Faculty of Electrical Engineering and Informatics, Budapest University of Technology and Economics, 1111 Budapest, Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7052-0322","authenticated-orcid":false,"given":"Melinda","family":"Szal\u00f3ki","sequence":"additional","affiliation":[{"name":"Department of Biomaterials and Prosthetic Dentistry, Faculty of Dentistry, University of Debrecen, 4032 Debrecen, Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexandra","family":"Bor\u00f3k","sequence":"additional","affiliation":[{"name":"Department of Electronics Technology, Faculty of Electrical Engineering and Informatics, Budapest University of Technology and Economics, 1111 Budapest, Hungary"},{"name":"Wigner Research Centre for Physics, 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