{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,11]],"date-time":"2026-04-11T14:04:08Z","timestamp":1775916248893,"version":"3.50.1"},"reference-count":42,"publisher":"MDPI AG","issue":"24","license":[{"start":{"date-parts":[[2022,12,8]],"date-time":"2022-12-08T00:00:00Z","timestamp":1670457600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Russian Science Foundation","award":["22-73-10203"],"award-info":[{"award-number":["22-73-10203"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>A coordination polymer has been synthesized using ferrocene-based ligand-bearing phosphinic groups of 1,1\u2032-ferrocene-diyl-bis(H-phosphinic acid)), and samarium (III). The coordination polymer\u2019s structure was studied by both single-crystal and powder XRD, TG, IR, and Raman analyses. For the first time, the M\u00f6ssbauer effect studies were performed on ferrocenyl phosphinate and the polymer based on it. Additionally, the obtained polymer was studied by the method of cyclic and differential pulse voltammetry. It is shown that it has the most positive potential known among ferrocenyl phosphinate-based coordination polymers and metal\u2013organic frameworks. Using the values of the oxidation potential, the polymer was oxidized and the ESR method verified the oxidized Fe(III) form in the solid state. Additionally, the effect of the size of the phosphorus atom substituent of the phosphinate group on the dimension of the resulting coordination compounds is shown.<\/jats:p>","DOI":"10.3390\/ijms232415569","type":"journal-article","created":{"date-parts":[[2022,12,9]],"date-time":"2022-12-09T01:51:26Z","timestamp":1670550686000},"page":"15569","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and M\u00f6ssbauer Study"],"prefix":"10.3390","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2203-6675","authenticated-orcid":false,"given":"Ruslan P.","family":"Shekurov","sequence":"first","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4714-4143","authenticated-orcid":false,"given":"Mikhail N.","family":"Khrizanforov","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia"},{"name":"A.M. Butlerov Chemistry Institute of the Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3125-7506","authenticated-orcid":false,"given":"Almaz A.","family":"Zagidullin","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4961-2863","authenticated-orcid":false,"given":"Almaz L.","family":"Zinnatullin","sequence":"additional","affiliation":[{"name":"Institute of Physics, Kazan Federal University, Kremlevskaya str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kirill V.","family":"Kholin","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia"},{"name":"Department of Physics, Kazan National Research Technological University, 68 Karl Marx Street, 420015 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kamil A.","family":"Ivshin","sequence":"additional","affiliation":[{"name":"A.M. Butlerov Chemistry Institute of the Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8473-5327","authenticated-orcid":false,"given":"Tatiana P.","family":"Gerasimova","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aisylu R.","family":"Sirazieva","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Olga N.","family":"Kataeva","sequence":"additional","affiliation":[{"name":"A.M. Butlerov Chemistry Institute of the Kazan Federal University, Kremlevskaya Str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7965-1583","authenticated-orcid":false,"given":"Farit G.","family":"Vagizov","sequence":"additional","affiliation":[{"name":"Institute of Physics, Kazan Federal University, Kremlevskaya str. 18, 420008 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8069-457X","authenticated-orcid":false,"given":"Vasili A.","family":"Miluykov","sequence":"additional","affiliation":[{"name":"Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Str. 8, 420088 Kazan, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,12,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"801","DOI":"10.1016\/j.jre.2020.01.012","article-title":"Advances and prospects of rare earth metal-organic frameworks in catalytic applications","volume":"38","author":"Sun","year":"2020","journal-title":"J. Rare Earths"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"213639","DOI":"10.1016\/j.ccr.2020.213639","article-title":"Chemical sensors for rare earth metal ions","volume":"429","author":"Paderni","year":"2021","journal-title":"Coord. Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"213232","DOI":"10.1016\/j.ccr.2020.213232","article-title":"Syntheses of reactive rare earth complexes by redox transmetallation\/protolysis reactions\u2014A simple and convenient method","volume":"415","author":"Guo","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"427","DOI":"10.1021\/acs.accounts.0c00684","article-title":"A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices","volume":"54","author":"Bernot","year":"2021","journal-title":"Acc. Chem. Res."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"7949","DOI":"10.1039\/D0CS00292E","article-title":"Rare-earth metal\u2013organic frameworks: From structure to applications","volume":"49","author":"Saraci","year":"2020","journal-title":"Chem. Soc. Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"5302","DOI":"10.1021\/ic070303v","article-title":"Rare-earth complexes of ferrocene-containing ligands: Visible-light excitable luminescent materials","volume":"46","author":"Yuan","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"6405","DOI":"10.1039\/C5DT04948B","article-title":"Synthesis, structure, and physical properties of new rare earth ferrocenoylacetonates","volume":"45","author":"Koroteev","year":"2016","journal-title":"Dalton Trans."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"2397","DOI":"10.1002\/cplu.202000584","article-title":"Electrochemical Applications of Ferrocene-Based Coordination Polymers","volume":"85","author":"Hu","year":"2020","journal-title":"ChemPlusChem"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"213737","DOI":"10.1016\/j.ccr.2020.213737","article-title":"Ferrocene-contained metal organic frameworks: From synthesis to applications","volume":"430","author":"Huang","year":"2021","journal-title":"Coord. Chem. Rev."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"213685","DOI":"10.1016\/j.ccr.2020.213685","article-title":"Recent advances in the development of ferrocene based electroactive small molecules for cation recognition: A comprehensive review of the years 2010\u20132020","volume":"431","author":"Pal","year":"2021","journal-title":"Coord. Chem. Rev."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"5355","DOI":"10.1002\/ejic.201000525","article-title":"Ferrocene-Containing Coordination Polymers: Ligand Design and Assembled Structures","volume":"2010","author":"Horikoshi","year":"2010","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"2490","DOI":"10.1021\/cg900566v","article-title":"Secondary ligand-directed assembly of CdII coordination architectures: From 0D to 3D complexes based on ferrocenyl carboxylate","volume":"10","author":"Shi","year":"2010","journal-title":"Cryst. Growth Des."},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Shearan, S.J., Stock, N., Emmerling, F., Demel, J., Wright, P.A., Demadis, K.D., Vassaki, M., Costantino, F., Vivani, R., and Sallard, S. (2019). New directions in metal phosphonate and phosphinate chemistry. Crystals, 9.","DOI":"10.3390\/cryst9050270"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"16986","DOI":"10.1039\/C9DT03592C","article-title":"Excellent supercapacitor and sensor performance of robust cobalt phosphinate ferrocenyl organic framework materials achieved by intrinsic redox and structure properties","volume":"48","author":"Khrizanforov","year":"2019","journal-title":"Dalton Trans."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"107019","DOI":"10.1016\/j.elecom.2021.107019","article-title":"Zwitterionic form of Ugi amine H-phosphinic acid: Structure and electrochemical properties","volume":"126","author":"Khrizanforov","year":"2021","journal-title":"Electrochem. Commun."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"2791","DOI":"10.1039\/D0NJ04783J","article-title":"First Example of Ugi\u2019s Amine as a Platform for Construction of Chiral Coordination Polymers: Synthesis and Properties","volume":"45","author":"Gilmanova","year":"2021","journal-title":"New J. Chem."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"121233","DOI":"10.1016\/j.jorganchem.2020.121233","article-title":"Synthesis, crystal structure and electrochemical properties of poly(cadmium 1,10-ferrocenediyl-bis(H-phosphinate))","volume":"914","author":"Shekurov","year":"2020","journal-title":"J. Organomet. Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"2794","DOI":"10.1039\/C9DT04834K","article-title":"3D Ni and Co Redox-Active Metal-Organic Frameworks Based on Ferrocenyl Diphosphinate and 4,4\u2032-Bipyridine Ligands as Efficient Electrocatalysts for Hydrogen Evolution Reaction","volume":"49","author":"Khrizanforova","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"3601","DOI":"10.1039\/C8DT04618B","article-title":"Zn and Co Redox Active Coordination Polymers Based on Ferrocene-containing Diphosphinate Ligand as Efficient Electrocatalysts for Hydrogen Evolution Reaction","volume":"48","author":"Shekurov","year":"2019","journal-title":"Dalton Trans."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"121004","DOI":"10.1016\/j.jorganchem.2019.121004","article-title":"Supramolecular architecture of diammonium ferrocene-1,1\u2032-diyldi(methylphosphinate)","volume":"904","author":"Shekurov","year":"2019","journal-title":"J. Organomet. Chem."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1039\/B008824M","article-title":"Lanthanide complexes with O2PH2, O2P(CH2Cl)2 and O2P(CH2OH)2 ligands: A solid-state tubular micelle","volume":"2","author":"Kresinski","year":"2000","journal-title":"CrystEngComm"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1819","DOI":"10.1007\/s11172-015-1077-1","article-title":"Synthesis and structure of the iron (III) tris-chelate complex based on 1,1\u2032-ferrocenediylbis(phenylphosphinic acid)","volume":"64","author":"Shekurov","year":"2015","journal-title":"Russ. Chem. Bull."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"2883","DOI":"10.1007\/s10008-015-2901-0","article-title":"Novel paste electrodes based on phosphonium salt room temperature ionic liquids for studying the redox properties of insoluble compounds","volume":"19","author":"Khrizanforov","year":"2015","journal-title":"J. Solid State Electrochem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"120240","DOI":"10.1016\/j.ica.2020.120240","article-title":"Aerogel based on nanoporous aluminium ferrocenyl diphosphinate metal-organic framework","volume":"518","author":"Khrizanforova","year":"2021","journal-title":"Inorgan. Chim. Acta"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1007","DOI":"10.1080\/10426507.2019.1630408","article-title":"New porous Fe(III)-based ferrocene-containing diphosphinate","volume":"194","author":"Shekurov","year":"2019","journal-title":"Phosphorus Sulfur Silicon Relat. Elem."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1010","DOI":"10.1080\/10426507.2019.1630409","article-title":"Electrochemical properties of poly ([Eu or Dy or Y] 1,1\u2032-ferrocenediyl-bis(H-phosphinates))","volume":"194","author":"Khrizanforov","year":"2019","journal-title":"Phosphorus Sulfur Silicon Relat. Elem."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"2726","DOI":"10.1016\/j.jorganchem.2010.07.037","article-title":"Synthesis and characterization of lanthanide complexes bearing a ferrocene-containing N-aryloxo-\u03b2-ketoiminate ligand","volume":"695","author":"Gu","year":"2010","journal-title":"J. Organomet. Chem."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"5084","DOI":"10.1021\/acs.cgd.6b00681","article-title":"Reversible water-induced structural and magnetic transformations and selective water adsorption properties of poly(manganese 1,1\u2032-ferrocenediyl-bis(H-phosphinate))","volume":"16","author":"Shekurov","year":"2016","journal-title":"Cryst. Growth Des."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"237","DOI":"10.1016\/j.molstruc.2018.04.033","article-title":"IR and UV study of reversible water-induced structural transformations of poly(manganese 1,1\u2032-ferrocenediyl-bis(H-phosphinate)) and poly(cobalt 1,1\u2032-ferrocenediyl-bis(H-phosphinate))","volume":"1166","author":"Gerasimova","year":"2018","journal-title":"J. Mol. Struct."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1072","DOI":"10.1063\/1.1696044","article-title":"M\u00f6ssbauer Studies of Iron Organometallic Complexes. IV. Sign of the Electric-Field Gradient in Ferrocene","volume":"42","author":"Collins","year":"1965","journal-title":"J. Chem. Phys."},{"key":"ref_31","unstructured":"Goldanskii, V.I., and Herber, R.H. (1968). Chemical Applications of M\u00f6ssbauer Spectroscopy, Academic Press."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"581","DOI":"10.1007\/BF01000961","article-title":"A M\u00f6ssbauer study of some ferrocene derivatives","volume":"2","author":"Stukan","year":"1966","journal-title":"Theor. Exp. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"243001","DOI":"10.1103\/PhysRevLett.92.243001","article-title":"Combined nuclear-molecular resonance inelastic scattering of X-rays","volume":"92","author":"Kohn","year":"2004","journal-title":"Phys. Rev. Lett."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"L391","DOI":"10.1088\/0953-8984\/6\/27\/006","article-title":"Mixed valence behaviour in polymers containing ferrocene","volume":"6","author":"Wagener","year":"1994","journal-title":"J. Phys. Condens. Matter"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"3079","DOI":"10.1021\/ic00314a044","article-title":"Powder EPR of tris(diethylthioselenocarbamato)-and tris(diethyldiselenocarbamato) iron(III) diluted in the analogous cobalt(III) and indium(III) complex matrixes","volume":"28","author":"Dietzsch","year":"1989","journal-title":"Inorg. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1016\/S1566-7367(02)00092-4","article-title":"The nature of the active site in bis(imino) pyridine iron ethylene polymerisation catalysts","volume":"3","author":"Britovsek","year":"2002","journal-title":"Catal. Commun."},{"key":"ref_37","unstructured":"Bruker (2016). APEX3 Crystallography Software Suite, Bruker AXS Inc."},{"key":"ref_38","unstructured":"Bruker (2016). SAINT Crystallography Software Suite, Bruker AXS Inc."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S1600576714022985","article-title":"Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination","volume":"48","author":"Krause","year":"2015","journal-title":"J. Appl. Crystallogr."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A Short History of SHELX","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr. Sect. A"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"178","DOI":"10.1063\/1.4759488","article-title":"SpectrRelax: An application for M\u00f6ssbauer spectra modeling and fitting","volume":"1489","author":"Matsnev","year":"2012","journal-title":"AIP Conf. Proc."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"40","DOI":"10.1016\/j.jorganchem.2014.04.035","article-title":"Synthesis and structure of ferrocenylphosphinic acids","volume":"766","author":"Shekurov","year":"2014","journal-title":"J. Organomet. Chem."}],"container-title":["International Journal of Molecular Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1422-0067\/23\/24\/15569\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:36:41Z","timestamp":1760146601000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1422-0067\/23\/24\/15569"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,12,8]]},"references-count":42,"journal-issue":{"issue":"24","published-online":{"date-parts":[[2022,12]]}},"alternative-id":["ijms232415569"],"URL":"https:\/\/doi.org\/10.3390\/ijms232415569","relation":{},"ISSN":["1422-0067"],"issn-type":[{"value":"1422-0067","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,12,8]]}}}