{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,13]],"date-time":"2026-05-13T00:22:59Z","timestamp":1778631779087,"version":"3.51.4"},"reference-count":62,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2022,12,26]],"date-time":"2022-12-26T00:00:00Z","timestamp":1672012800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 106-2113-M-260-007-"],"award-info":[{"award-number":["MOST 106-2113-M-260-007-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 107-2113-M-260-001-"],"award-info":[{"award-number":["MOST 107-2113-M-260-001-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 108-2113-M-260-002-"],"award-info":[{"award-number":["MOST 108-2113-M-260-002-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 109-2113-M-260-007-"],"award-info":[{"award-number":["MOST 109-2113-M-260-007-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 106-2113-M-260-007-"],"award-info":[{"award-number":["MOST 106-2113-M-260-007-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 107-2113-M-260-001-"],"award-info":[{"award-number":["MOST 107-2113-M-260-001-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 108-2113-M-260-002-"],"award-info":[{"award-number":["MOST 108-2113-M-260-002-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 109-2113-M-260-007-"],"award-info":[{"award-number":["MOST 109-2113-M-260-007-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 106-2113-M-260-007-"],"award-info":[{"award-number":["MOST 106-2113-M-260-007-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 107-2113-M-260-001-"],"award-info":[{"award-number":["MOST 107-2113-M-260-001-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 108-2113-M-260-002-"],"award-info":[{"award-number":["MOST 108-2113-M-260-002-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 109-2113-M-260-007-"],"award-info":[{"award-number":["MOST 109-2113-M-260-007-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 106-2113-M-260-007-"],"award-info":[{"award-number":["MOST 106-2113-M-260-007-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 107-2113-M-260-001-"],"award-info":[{"award-number":["MOST 107-2113-M-260-001-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 108-2113-M-260-002-"],"award-info":[{"award-number":["MOST 108-2113-M-260-002-"]}]},{"name":"the National Chi Nan University and the National Science and Technology Council","award":["MOST 109-2113-M-260-007-"],"award-info":[{"award-number":["MOST 109-2113-M-260-007-"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>Two Cd(II) based coordination polymers, {Cd3(btc)2(BTD-bpy)2]\u22191.5MeOH\u22194H2O}n (1) and [Cd2(1,4-ndc)2(BTD-bpy)2]n (2), where BTD-bpy = bis(pyridin-4-yl)benzothiadiazole, btc = benzene-1,3,5-tricarboxylate, and 1,4-ndc = naphthalene-1,4-dicarboxylate, were hydro(solvo)thermally synthesized. Compound 1 has a three-dimensional non-interpenetrating pillared-bilayer open framework with sufficient free voids of 25.1%, which is simplified to show a topological (4,6,8)-connected net with the point symbol of (324256)(344454628)(3442619728). Compound 2 has a three-dimensional two-fold interpenetrating bipillared-layer condense framework regarded as a 6-connected primitive cubic (pcu) net topology. Compounds 1 and 2 both exhibited good water stability and high thermal stability approaching 350 \u00b0C. Upon excitation, compounds 1 and 2 both emitted blue light fluorescence at 471 and 479 nm, respectively, in solid state and at 457 and 446 nm, respectively, in the suspension phase of H2O. Moreover, compounds 1 and 2 in the suspension phase of H2O both exhibited a fluorescence quenching effect in sensing Ag+, attributed to framework collapse, and a fluorescence enhancement response in sensing Al3+ and Cr3+, ascribed to weak ion\u2013framework interactions, with high selectivity and sensitivity and low detection limit.<\/jats:p>","DOI":"10.3390\/ijms24010369","type":"journal-article","created":{"date-parts":[[2022,12,27]],"date-time":"2022-12-27T04:42:47Z","timestamp":1672116167000},"page":"369","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Fluorescence-Responsive Detection of Ag(I), Al(III), and Cr(III) Ions Using Cd(II) Based Pillared-Layer Frameworks"],"prefix":"10.3390","volume":"24","author":[{"given":"Qi-Jin","family":"Jiang","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry, National Chi Nan University, Nantou 545, Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Po-Min","family":"Chuang","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry, National Chi Nan University, Nantou 545, Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7257-4711","authenticated-orcid":false,"given":"Jing-Yun","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry, National Chi Nan University, Nantou 545, Taiwan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,12,26]]},"reference":[{"key":"ref_1","first-page":"1","article-title":"Chromium (III) and chromium (VI) as important players in the induction of genotoxicity\u2212current view","volume":"28","author":"Sawicka","year":"2021","journal-title":"Ann. Agric. Environ. Med."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"575","DOI":"10.1016\/j.neuro.2010.05.009","article-title":"The neurotoxicity of environmental aluminum is still an issue","volume":"31","author":"Bondy","year":"2010","journal-title":"NeuroToxicology"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"140","DOI":"10.1016\/j.burns.2003.09.030","article-title":"In vitro cytotoxity of silver: Implication for clinical wound care","volume":"30","author":"Poon","year":"2004","journal-title":"Burns"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.cbpa.2012.01.016","article-title":"Metal-associated amyloid-\u03b2 species in Alzheimer\u2019s disease","volume":"16","author":"Pithadia","year":"2012","journal-title":"Curr. Opin. Chem. Biol."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1002\/etc.5620180112","article-title":"Bioaccumulation and toxicity of silver compounds: A review","volume":"18","author":"Ratte","year":"1999","journal-title":"Environ. Toxicol. Chem."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1016\/j.aquatox.2013.07.012","article-title":"Behavioural and physiological responses of Gammarus fossarum (Crustacea Amphipoda) exposed to silver","volume":"142\u2013143","author":"Funck","year":"2013","journal-title":"Aquat. Toxicol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1016\/S0361-9230(01)00459-2","article-title":"Aluminium as a risk factor in Alzheimer\u2019s disease, with emphasis on drinking water","volume":"55","author":"Flaten","year":"2001","journal-title":"Brain Res. Bull."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"3011","DOI":"10.1016\/S0045-6535(98)00342-7","article-title":"Tests of toxicity and teratogenicity in biphasic vertebrates treated with heavy metals (Cr3+, A13+, Cd2+)","volume":"37","author":"Calevro","year":"1998","journal-title":"Chemosphere"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"773","DOI":"10.1016\/j.bmc.2004.10.037","article-title":"Design, synthesis, and evaluation of novel bifunctional iron-chelators as potential agents for neuroprotection in Alzheimer\u2019s, Parkinson\u2019s, and other neurodegenerative diseases","volume":"13","author":"Zheng","year":"2005","journal-title":"Bioorg. Med. Chem."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"759","DOI":"10.1016\/j.etap.2014.01.025","article-title":"Biomonitorization of chromium, copper, iron, manganese and nickel in scalp hair from orthodontic patients by atomic absorption spectrometry","volume":"37","author":"Jos","year":"2014","journal-title":"Environ. Toxicol. Pharmacol."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"682","DOI":"10.1016\/j.talanta.2004.03.039","article-title":"Trace enrichment and determination of silver by immobilized DDTC microcolumn and flow injection atomic absorption spectrometry","volume":"64","author":"Dadfarnia","year":"2004","journal-title":"Talanta"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1016\/j.aca.2015.08.053","article-title":"Inductively coupled plasma\u2212Tandem mass spectrometry (ICP-MS\/MS): A powerful and universal tool for the interference-free determination of (ultra)trace elements\u2014A tutorial review","volume":"894","author":"Balcaen","year":"2015","journal-title":"Anal. Chim. Acta"},{"key":"ref_13","first-page":"1467631","article-title":"Determination of Metals in Natural Waters by Inductively Coupled Plasma Optical Emission Spectroscopy after Preconcentration on Silica Sequentially Coated with Layers of Polyhexamethylene Guanidinium and Sulphonated Nitrosonaphthols","volume":"2019","author":"Losev","year":"2019","journal-title":"Int. J. Anal. Chem."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"e13251","DOI":"10.1002\/ep.13251","article-title":"Solid phase extraction of trace level Ag(I) using coriolus versicolor immobilized magnetic nanoparticles and its determination by ICP-OES","volume":"38","author":"Yalcin","year":"2019","journal-title":"Environ. Prog. Sustain. Energy"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"933","DOI":"10.1039\/b917755h","article-title":"Atomic Fluorescence Spectrometry: A suitable detection technique in speciation studies for arsenic, selenium, antimony and mercury","volume":"25","author":"Corns","year":"2010","journal-title":"J. Anal. At. Spectrom."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"829","DOI":"10.1016\/S0039-9140(01)00338-1","article-title":"Determination of metals in lubricating oils by X-ray fluorescence spectrometry","volume":"51","author":"Pouzar","year":"2001","journal-title":"Talanta"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"515","DOI":"10.1016\/j.snb.2015.02.122","article-title":"A review on detection of heavy metal ions in water\u2212An electrochemical approach","volume":"213","author":"Gumpu","year":"2015","journal-title":"Sens. Actuators B"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"461","DOI":"10.1021\/acssensors.0c02038","article-title":"Determination of Ag[I] and NADH using single-molecule conductance ratiometric probes","volume":"6","author":"Hu","year":"2021","journal-title":"ACS Sens."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"20550","DOI":"10.1021\/acsami.8b05041","article-title":"Metal\u2212Polydopamine Framework as an Effective Fluorescent Quencher for Highly Sensitive Detection of Hg(II) and Ag(I) Ions through Exonuclease III Activity","volume":"10","author":"Ravikumar","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"6810","DOI":"10.1021\/acsomega.0c05867","article-title":"Novel Multifunctional Samarium\u2212Organic Framework for Fluorescence Sensing of Ag+, MnO4\u2212, and Cimetidine and Electrochemical Sensing of o-Nitrophenol in Aqueous Solutions","volume":"6","author":"Zhang","year":"2021","journal-title":"ACS Omega"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"13834","DOI":"10.1039\/C9DT02962A","article-title":"Post-imparting Br\u00f8nsted acidity into an amino-functionalized MOF as a bifunctional luminescent turn-ON sensor for the detection of aluminum ions and lysine","volume":"48","author":"Liu","year":"2019","journal-title":"Dalton Trans."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"20035","DOI":"10.1039\/C7TA05896A","article-title":"An ultrastable zinc(II)\u2212organic framework as a recyclable multi-responsive luminescent sensor for Cr(III), Cr(VI) and 4-nitrophenol in the aqueous phase with high selectivity and sensitivity","volume":"5","author":"Guo","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"18018","DOI":"10.1039\/C4TA03990D","article-title":"Highly sensitive and selective fluorescent probe for Ag+ based on a Eu3+ post-functionalized metal\u2212organic framework in aqueous media","volume":"2","author":"Hao","year":"2014","journal-title":"J. Mater. Chem. A"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"2671","DOI":"10.1021\/acsenergylett.0c01148","article-title":"Functionalizing Luminescent Metal\u2212Organic Frameworks for Enhanced Photoluminescence","volume":"5","author":"Liu","year":"2020","journal-title":"ACS Energy Lett."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"485","DOI":"10.1021\/acs.accounts.9b00575","article-title":"Metal\u2212Organic Frameworks with Multiple Luminescence Emissions: Designs and Applications","volume":"53","author":"Yin","year":"2020","journal-title":"Acc. Chem. Res."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"3429","DOI":"10.1039\/D0DT04276E","article-title":"Luminescent metal\u2013organic frameworks as chemical sensors based on \u201cmechanism\u2212response\u201d: A review","volume":"50","author":"Huangfu","year":"2021","journal-title":"Dalton Trans."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"342","DOI":"10.1016\/j.poly.2018.11.016","article-title":"A new multifunctional two-dimensional cobalt(II) metal\u2212organic framework for electrochemical detection of hydrogen peroxide, luminescent sensing of metal ions, and photocatalysis","volume":"158","author":"Xiao","year":"2019","journal-title":"Polyhedron"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.jssc.2019.02.027","article-title":"Two new ternary Mn(II) coordination polymers by regulation of aromatic carboxylate ligands: Synthesis, structures, photocatalytic and selective ion-sensing properties","volume":"273","author":"Xiao","year":"2019","journal-title":"J. Solid State Chem."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"6373","DOI":"10.1021\/acs.inorgchem.5b00688","article-title":"Highly Selective and Sensitive Luminescence Turn-On-Based Sensing of Al3+ Ions in Aqueous Medium Using a MOF with Free Functional Sites","volume":"54","author":"Singha","year":"2015","journal-title":"Inorg. Chem."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"2285","DOI":"10.1039\/C9DT00005D","article-title":"An excellent example illustrating the fluorescence sensing property of cobalt\u2212organic frameworks","volume":"48","author":"Zhang","year":"2019","journal-title":"Dalton Trans."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"1888","DOI":"10.1039\/C7QI00549K","article-title":"A highly selective and sensitive Zn(II) coordination polymer luminescent sensor for Al3+ and NACs in the aqueous phase","volume":"4","author":"Zhang","year":"2017","journal-title":"Inorg. Chem. Front."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1021\/acs.cgd.1c00876","article-title":"A Thermally Stable Undulated Coordination Layer Showing a Sequentially Interweaving 2D \u2192 3D Net as a Turn-On Sensor for Luminescence Detection of Al3+ in Water","volume":"22","author":"Chen","year":"2022","journal-title":"Cryst. Growth Des."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"122564","DOI":"10.1016\/j.jssc.2021.122564","article-title":"A luminescent Cd(II) coordination polymer as a fluorescence-responsive sensor for enhancement sensing of Al3+ and Cr3+ ions and quenching detection of chromium(VI) oxyanions","volume":"304","author":"Tsai","year":"2021","journal-title":"J. Solid State Chem."},{"key":"ref_34","doi-asserted-by":"crossref","unstructured":"Liao, K.-S., Tsai, M.-J., Hsu, L.-J., Wang, C.-M., and Wu, J.-Y. (2021). A Cd(II) luminescent coordination grid as a multiresponsive fluorescence sensor for Cr(VI) oxyanions and Cr(III), Fe(III), and Al(III) in aqueous medium. Molecules, 26.","DOI":"10.3390\/molecules26237103"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"4391","DOI":"10.1021\/acs.inorgchem.6b00111","article-title":"Heterometallic Alkaline Earth\u2212Lanthanide BaII\u2212LaIII Microporous Metal\u2212Organic Framework as Bifunctional Luminescent Probes of Al3+ and MnO4\u2212","volume":"55","author":"Ding","year":"2016","journal-title":"Inorg. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.jssc.2017.12.033","article-title":"A Highly Selective and Fast-Response Fluorescent Probe Based on Cd-MOF for the Visual Detection of Al3+ Ion and Quantitative Detection of Fe3+ Ion","volume":"259","author":"Lv","year":"2018","journal-title":"J. Solid State Chem."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"14201","DOI":"10.1039\/D0DT02606A","article-title":"From lamellar net to bilayered-lamella and to porous pillared-bilayer: Reversible crystal-to-crystal transformation, CO2 adsorption, and fluorescence detection of Fe3+, Al3+, Cr3+, MnO4\u2212, and Cr2O72\u2212 in water","volume":"49","author":"Zhang","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"1786","DOI":"10.1039\/C8DT04653K","article-title":"A water-stable europium-MOF as a multifunctional luminescent sensor for some trivalent metal ions (Fe3+, Cr3+, Al3+), PO43\u2212 ions, and nitroaromatic explosives","volume":"48","author":"Zhan","year":"2019","journal-title":"Dalton Trans."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"5226","DOI":"10.1039\/D1CE00705J","article-title":"A highly stable Zn coordination polymer exhibiting pH-dependent fluorescence and as a visually ratiometric and on\u2212off fluorescence sensor","volume":"23","author":"Chuang","year":"2021","journal-title":"CrystEngComm"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"2222","DOI":"10.1039\/D0CE01825B","article-title":"Influence of linker substitution on fluorescence responsive sensing of isostructural coordination polymers: Visual turn-on, ratiometric, and turn-off sensing in water","volume":"23","author":"Chuang","year":"2021","journal-title":"CrystEngComm"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"20137","DOI":"10.1039\/C8NJ04956D","article-title":"3D water-stable europium metal organic frameworks as a multi-responsive luminescent sensor for high-efficiency detection of Cr2O72\u2212, MnO4\u2212, Cr3+ ions and SDBS in aqueous solution","volume":"42","author":"Yang","year":"2018","journal-title":"New J. Chem."},{"key":"ref_42","doi-asserted-by":"crossref","unstructured":"Tsai, M.-J., Liao, K.-S., and Wu, J.-Y. (2022). A Water-Stable 2-Fold Interpenetrating cds Net as a Bifunctional Fluorescence-Responsive Sensor for Selective Detection of Cr(III) and Cr(VI) Ions. Nanomaterials, 12.","DOI":"10.3390\/nano12010158"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"2686","DOI":"10.1021\/acs.inorgchem.8b03294","article-title":"Supramolecular Aggregate of Cadmium(II)-Based One-Dimensional Coordination Polymer for Device Fabrication and Sensor Application","volume":"58","author":"Dutta","year":"2019","journal-title":"Inorg. Chem."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"3828","DOI":"10.1021\/acs.inorgchem.9b03496","article-title":"Multiresponsive Luminescent Sensitivities of a 3D Cd-CP with Visual Turn-on and Ratiometric Sensing toward Al3+ and Cr3+ as Well as Turn-off Sensing toward Fe3+","volume":"59","author":"Yu","year":"2020","journal-title":"Inorg. Chem."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"11338","DOI":"10.1021\/acsami.8b20410","article-title":"Highly Selective and Sensitive Turn-Off\u2212On Fluorescent Probes for Sensing Al3+ Ions Designed by Regulating the Excited-State Intramolecular Proton Transfer Process in Metal\u2212Organic Frameworks","volume":"11","author":"Li","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"9095","DOI":"10.1021\/acs.inorgchem.0c00964","article-title":"Solvent-Induced Controllable Supramolecular Isomerism: Phase Transformation, CO2 Adsorption, and Fluorescence Sensing toward CrO42\u2212, Cr2O72\u2212, MnO4\u2212 and Fe3+","volume":"59","author":"Huang","year":"2020","journal-title":"Inorg. Chem."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"6529","DOI":"10.1002\/chem.202005373","article-title":"Engineering Tailored Bifunctional Luminescent Pillared-Layer Frameworks for Adsorption of CO2 and Sensitive Detection of Nitrobenzene in Water Media","volume":"27","author":"Su","year":"2021","journal-title":"Chem. Eur. J."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"131967","DOI":"10.1016\/j.snb.2022.131967","article-title":"A thiadiazole-functionalized Zn(II)-based luminescent coordination polymer with seven-fold interweaved herringbone nets showing solvent-responsive fluorescence properties and discriminative detection of ethylenediamine","volume":"366","author":"Chuang","year":"2022","journal-title":"Sens. Actuators B Chem."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1107\/S090744490804362X","article-title":"Structure validation in chemical crystallography","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Crystallogr. Sect. D"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"875","DOI":"10.1039\/C6DT04335F","article-title":"A reliable amplified fluorescence-enhanced chemosensor (Eu-MIL-61) for the directional detection of Ag+ in an aqueous solution","volume":"46","author":"Sun","year":"2017","journal-title":"Dalton Trans."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"9174","DOI":"10.1039\/C7CP00631D","article-title":"Ag+-induced photoluminescence enhancement in lanthanide post-functionalized MOFs and Ag+ sensing","volume":"19","author":"Sun","year":"2017","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"4788","DOI":"10.1039\/C4TA06462C","article-title":"Ag+-sensitized lanthanide luminescence in Ln3+ post-functionalized metal\u2212organic frameworks and Ag+ sensing","volume":"3","author":"Hao","year":"2015","journal-title":"J. Mater. Chem. A"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"129518","DOI":"10.1016\/j.molstruc.2020.129518","article-title":"A new fluorescent sensor constructed by Eu3+ post-functionalized metal\u2212organic framework for sensing Ag+ with high selectivity and sensitivity in aqueous solution","volume":"1227","author":"Luo","year":"2021","journal-title":"J. Mol. Struct."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"10153","DOI":"10.1039\/c2dt30689a","article-title":"Post-modification of a MOF through a fluorescent-labeling technology for the selective sensing and adsorption of Ag+ in aqueous solution","volume":"41","author":"Zhang","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1016\/j.dyepig.2015.01.014","article-title":"A highly sensitive fluorescent chemosensor for simultaneous determination of Ag(I), Hg(II), and Cu(II) ions: Design, synthesis, characterization and application","volume":"116","author":"Hien","year":"2015","journal-title":"Dyes Pigm."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"1150","DOI":"10.1039\/C3CP53907E","article-title":"Proton transfer and hydrogen bonding in the organic solid state: A combined XRD\/XPS\/ssNMR study of 17 organic acid\u2212base complexes","volume":"16","author":"Stevens","year":"2014","journal-title":"Phys. Chem. Chem. Phys."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"9681","DOI":"10.1039\/c1cc13312h","article-title":"Highly qualified reduced graphene oxides: The best chemical reduction","volume":"47","author":"Moon","year":"2011","journal-title":"Chem. Commun."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"515","DOI":"10.1016\/j.dyepig.2016.09.011","article-title":"Two stable 3D porous metal\u2212organic frameworks with high selectivity for detection of PA and metal ions","volume":"136","author":"Shen","year":"2017","journal-title":"Dyes Pigm."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A short history of SHELX","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr., Sect. A"},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","article-title":"Crystal structure refinement with SHELXL","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. Sect. C"},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","article-title":"WinGX and ORTEP for Windows: An update","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Crystallogr."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1107\/S2053229614024929","article-title":"PLATON SQUEEZE: A tool for the calculation of the disordered solvent contribution to the calculated structure factors","volume":"71","author":"Spek","year":"2015","journal-title":"Acta Crystallogr. Sect. 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