{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:46:31Z","timestamp":1760147191380,"version":"build-2065373602"},"reference-count":72,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2023,1,16]],"date-time":"2023-01-16T00:00:00Z","timestamp":1673827200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>A new coordination compound of copper(II) with a tolfenamate ligand of the paddle-wheel-like structure [CuII2(Tolf)4(MeOH)2]\u22192MeOH was obtained and structurally characterized. Chemical bonds of Cu(II)\u2219\u2219\u2219Cu(II) and Cu(II)\u2013O were theoretically analyzed and compared with the results for selected similar structures from the CSD database. QTAIM analysis showed that the Cu(II)\u2219\u2219\u2219Cu(II) interaction has a strength comparable to a hydrogen bond, as indicated by the electron density at a critical point. The remaining QTAIM parameters indicate stability of the Cu(II)\u2219\u2219\u2219Cu(II) interaction. Other methods, such as NCI and NBO, also indicate a significant strength of this interaction. Thus, the Cu(II)\u2219\u2219\u2219Cu(II) interaction can be treated as one of the noncovalent interactions that affects the structure of the coordination compound, the packing of molecules in the crystal, and the general properties of the compound.<\/jats:p>","DOI":"10.3390\/ijms24021745","type":"journal-article","created":{"date-parts":[[2023,1,16]],"date-time":"2023-01-16T02:29:55Z","timestamp":1673836195000},"page":"1745","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Crystal Structure and Chemical Bonds in [CuII2(Tolf)4(MeOH)2]\u22192MeOH"],"prefix":"10.3390","volume":"24","author":[{"given":"Irena","family":"Majerz","sequence":"first","affiliation":[{"name":"Faculty of Pharmacy, Wroc\u0142aw Medical University, Borowska 211a, 50-556 Wroc\u0142aw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marta S.","family":"Krawczyk","sequence":"additional","affiliation":[{"name":"Faculty of Pharmacy, Wroc\u0142aw Medical University, Borowska 211a, 50-556 Wroc\u0142aw, Poland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2023,1,16]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1664","DOI":"10.1345\/aph.1C489","article-title":"Use of NSAIDs for the chemoprevention of colorectal cancer","volume":"37","author":"Herendeen","year":"2003","journal-title":"Ann. 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