{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T15:44:01Z","timestamp":1791906241621,"version":"4.3.4"},"reference-count":68,"publisher":"MDPI AG","issue":"4","license":[{"start":{"date-parts":[[2023,2,10]],"date-time":"2023-02-10T00:00:00Z","timestamp":1675987200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Beijing Natural Science Foundation","award":["8222046"],"award-info":[{"award-number":["8222046"]}]},{"name":"Beijing Natural Science Foundation","award":["cstc2020jcyj-msxmX0120"],"award-info":[{"award-number":["cstc2020jcyj-msxmX0120"]}]},{"name":"Natural Scientific Fund of Chongqing","award":["8222046"],"award-info":[{"award-number":["8222046"]}]},{"name":"Natural Scientific Fund of Chongqing","award":["cstc2020jcyj-msxmX0120"],"award-info":[{"award-number":["cstc2020jcyj-msxmX0120"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>In the present study, mulberry branch-derived biochar CuO (MBC\/CuO) composite was successfully synthesized and used as a catalyst to activate persulfate (PS) for the degradation of bisphenol A (BPA). The MBC\/CuO\/PS system exhibited a high degradation efficiency (93%) of BPA, under the conditions of 0.1 g\/L MBC\/CuO, 1.0 mM PS, 10 mg\/L BPA. Free radical quenching and electron spin-resonance spectroscopy (ESR) experiments confirmed that both free radicals \u2022OH, SO4\u2022\u2212 and O2\u2022\u2212 and non-radicals 1O2 were involved in the MBC\/CuO reaction system. Cl\u2212 and NOM displayed negligible influence on the degradation of BPA, while HCO3\u2212 promoted the removal of BPA. In addition, the toxicity tests of BPA, MBC\/CuO and the degraded BPA solution were conducted by the 5th instar silkworm larvae. The toxicity of BPA was reduced after the treatment in the MBC\/CuO\/PS system, and no obvious toxicity of the synthesized MBC\/CuO composite was found in the toxicity evaluation experiments. This work provides a new value-added utilization of mulberry branches as a cost-effective and environmentally friendly PS activator.<\/jats:p>","DOI":"10.3390\/ijms24043609","type":"journal-article","created":{"date-parts":[[2023,2,13]],"date-time":"2023-02-13T03:28:46Z","timestamp":1676258926000},"page":"3609","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Synthesis of an Environmentally Friendly Modified Mulberry Branch-Derived Biochar Composite: High Degradation Efficiency of BPA and Mitigation of Toxicity in Silkworm Larvae"],"prefix":"10.3390","volume":"24","author":[{"given":"Han","family":"Qu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Silkworm Genome Biology, Key Laboratory of Sericultural Biology and Genetic Breeding, Ministry of Agriculture and Rural Affairs, College of Sericulture, Textile and Biomass Sciences, Southwest University, Chongqing 400715, China"},{"name":"Key Laboratory of Eco-Environment of Three Gorges Region of Ministry of Education, Chongqing University, Chongqing 400045, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silkworm Genome Biology, Key Laboratory of Sericultural Biology and Genetic Breeding, Ministry of Agriculture and Rural Affairs, College of Sericulture, Textile and Biomass Sciences, Southwest University, Chongqing 400715, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fujian","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silkworm Genome Biology, Key Laboratory of Sericultural Biology and Genetic Breeding, Ministry of Agriculture and Rural Affairs, College of Sericulture, Textile and Biomass Sciences, Southwest University, Chongqing 400715, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiangwei","family":"Zhu","sequence":"additional","affiliation":[{"name":"Co-Innovation Center for Sustainable Forestry in Southern China, Nanjing Forestry University, Nanjing 210037, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7111-6543","authenticated-orcid":false,"given":"Chengdu","family":"Qi","sequence":"additional","affiliation":[{"name":"School of Environment, Nanjing Normal University, Nanjing 210023, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7905-5033","authenticated-orcid":false,"given":"Guilong","family":"Peng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silkworm Genome Biology, Key Laboratory of Sericultural Biology and Genetic Breeding, Ministry of Agriculture and Rural Affairs, College of Sericulture, Textile and Biomass Sciences, Southwest University, Chongqing 400715, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,2,10]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"405","DOI":"10.1016\/j.indcrop.2018.11.041","article-title":"The potential of lignocellulosic biomass precursors for biochar production: Performance, mechanism and wastewater application\u2014A review","volume":"128","author":"Rangabhashiyam","year":"2019","journal-title":"Ind. 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