{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,4]],"date-time":"2026-04-04T15:48:28Z","timestamp":1775317708974,"version":"3.50.1"},"reference-count":52,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2023,4,13]],"date-time":"2023-04-13T00:00:00Z","timestamp":1681344000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["21-73-00192"],"award-info":[{"award-number":["21-73-00192"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["121031700313-8"],"award-info":[{"award-number":["121031700313-8"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Ministry of Education and Science of the Russian Federation","award":["21-73-00192"],"award-info":[{"award-number":["21-73-00192"]}]},{"name":"Ministry of Education and Science of the Russian Federation","award":["121031700313-8"],"award-info":[{"award-number":["121031700313-8"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>Nine heterometallic iodobismuthates with the general formula Cat2{[Bi2M2I10}] (M = Cu(I), Ag(I), Cat = organic cation) were synthesized. According to X-ray diffraction data, their crystal structures consisted of {Bi2I10} units interconnected with Cu(I) or Ag(I) atoms through I-bridging ligands, forming one-dimensional polymers. The compounds are thermally stable up to 200 \u00b0C. Optical band gaps (Eg), estimated at room temperature via diffuse reflectance measurements, range from 1.81 to 2.03 eV. Thermally induced changes in optical behavior (thermochromism) for compounds 1\u20139 were recorded, and general correlations were established. The thermal dependence of Eg appears to be close to linear for all studied compounds.<\/jats:p>","DOI":"10.3390\/ijms24087234","type":"journal-article","created":{"date-parts":[[2023,4,14]],"date-time":"2023-04-14T02:28:12Z","timestamp":1681439292000},"page":"7234","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Copper- and Silver-Containing Heterometallic Iodobismuthates: Features of Thermochromic Behavior"],"prefix":"10.3390","volume":"24","author":[{"given":"Irina A.","family":"Shentseva","sequence":"first","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Lavrentieva St. 3, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3980-5028","authenticated-orcid":false,"given":"Andrey N.","family":"Usoltsev","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Lavrentieva St. 3, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3399-5975","authenticated-orcid":false,"given":"Nikita A.","family":"Korobeynikov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Lavrentieva St. 3, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5269-9130","authenticated-orcid":false,"given":"Taisiya S.","family":"Sukhikh","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Lavrentieva St. 3, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vladimir R.","family":"Shayapov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Lavrentieva St. 3, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9361-4594","authenticated-orcid":false,"given":"Maxim N.","family":"Sokolov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Lavrentieva St. 3, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergey A.","family":"Adonin","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Lavrentieva St. 3, 630090 Novosibirsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2023,4,13]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2787","DOI":"10.1016\/j.ccr.2009.08.003","article-title":"Structural Overview and Structure-Property Relationships of Iodoplumbate and Iodobismuthate","volume":"253","author":"Wu","year":"2009","journal-title":"Coord. 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